Quantitative analysis of sulphated glycosaminoglycans content of Malaysian sea cucumber Stichopus hermanni and Stichopus vastus

Stichopus hermanni and Stichopus vastus are sea cucumber species from the Stichopodidae family within the coastal waters of Malaysia. The integument of these invertebrates is hypothesised to contain abundant glycosaminoglycans (GAGs). GAGs are divided into non-sulphated and sulphated GAGs. Sulphated GAGs have various chemico-biological functions that are beneficial to humans. This study quantitatively analysed N-, O-sulphated and total sulphated GAG content from three different anatomical regions (integument, internal organs and coelomic fluid) of S. hermanni and S. vastus. The integument revealed the highest content of total, O- and N-sulphated GAGs, followed by the internal organs and the coelomic fluid for both species of sea cucumbers. The percentage division of O- and N-sulphated GAGs suggested that anatomical parts of both species showed higher levels of O-sulphated GAGs compared to N-sulphated GAGs. In conclusion, these findings indicate that the integument body wall of S. hermanni and S. vastus is a rich source of sulphated GAGs.     

Optimized synthesis and photovoltaic performance of TiO2 nanoparticles for dye-sensitized solar cell

This paper presents response surface methodology （RSM） as an efficient approach for modeling and optimizing TiO2 nanoparticles preparation via co-precipitation for dye-sensitized solar cell （DSSC） perfor- mance. Titanium （IV） bis-（acetylacetonate） di-isopropoxide （DIPBAT）, isopropanol and water were used as precursor, solvent and co-solvent, respectively. Molar ratio of water, aging temperature and calcina- tion temperature as preparation factors with main and interaction effects on particle characteristics and performances were investigated, Particle characteristics in terms of primary and secondary sizes, crys- tal orientation and morphology were determined by X-ray diffractometry （XRD） and scanning electron microscopy （SEM）. Band gap energy and power conversion efficiency of DSSCs were used for perfor- mance studies. According to analysis of variance （ANOVA） in response surface methodology （RSM）, all three independent parameters were statistically significant and the final model was accurate. The model predicted maximum power conversion efficiency （0.14%） under the optimal condition of molar ratio of DIPBAT-to-isopropanol-to-water of 1 ： 10：500, aging temperature of 36 C and calcination temperature of 400 ℃. A second set of data was adopted to validate the model at optimal conditions and was found to be 0.14 ± 0.015%, which was very close to the predicted value. This study proves the reliability of the model in identi（ving the optimal condition for maximum performance.     

Riemann–Hilbert-type Boundary Value Problems on a Half Hexagon

In this article we discuss the explicit solvability of both Schwarz boundary value problem and Riemann–Hilbert boundary value problem on a half hexagon in the complex plane. Schwarz-type and Pompeiu-type integrals are obtained. The boundary behavior of these operators is discussed.Finally, we investigate the Schwarz problem and the Riemann–Hilbert problem for inhomogeneous Cauchy–Riemann equations.     

Early detection of diseases in plant tissue using spectroscopy – applications and limitations

Plant diseases can greatly affect the total production of food and agricultural materials, which may lead to high amount of losses in terms of quality, quantity and also in economic sense. To reduce the losses due to plant diseases, early diseases detection either based on a visual inspection or laboratory tests are widely employed. However, these techniques are labor-intensive and time consuming. In a view to overcome the shortcoming of these conventional approaches, several researchers have developed non-invasive techniques. Recently, spectroscopy technique has become one of the most available non-invasive methods utilized in detecting plant diseases. However, most of the studies on the application of this novel technology are still in the experimental stages, and are carried out in isolation with no comprehensive information on the most suitable approach. This problem could affect the advancement and commercialization of spectroscopy technology in early plant disease detection. Here, we review the applications and limitations of spectroscopy techniques (visible/infrared, electrical impedance and fluorescence spectroscopy) in early detection of plant disease. Particular emphasis was given to different spectral level, challenges and future outlook.     

Griffith–Kelly–Sherman Correlation Inequalities for Generalized Potts Model

Inspired by the work of D.G.Kelly and S.Sherman on general Griffiths inequalities on correlations in Ising ferromagnets, we formulate and prove Griffith–Kelly–Sherman-type inequalities for the ferromagnetic Potts model with a general number q of local states. We take as local state space for the q-state Potts model the set F ^c  = { − l, − l + 1, ⋯ ,l − 1,l},where l=fracq-12l=frac{q-1}{2}. The important properties of F ^c for what follows are that |F ^c | = q and F ^c  = − F ^c .     

MHD flow and heat transfer over a radially stretching/shrinking disk

A steady magnetohydrodynamic (MHD) flow past a radially stretching or shrinking disk is investigated. The governing partial differential equations are transformed into a set of ordinary (similarity) differential equations by a similarity transformation. These equations along with the corresponding boundary conditions are solved numerically using the boundary value problem solver (bvp4c) in Matlab. The effects of magnetic field and suction on the shear stress and the heat transfer are analyzed and discussed. It is found that both parameters affect more in the shrinking region. The increase in the magnetic parameter results in the increase of the skin friction coefficient but decrease in the local Nusselt number.The skin friction coefficient and the local Nusselt number increase as suction increases.     

Silver nanoparticles generated by pulsed laser ablation in supercritical CO2 medium

Pulsed laser ablation (PLA) has been widely employed in industrial and biological applications and in other fields. The environmental conditions in which PLA is conducted are important parameters that affect both the solid particle cloud and the deposition produced by the plume. In this work, the generation of nanoparticles (NPs) has been developed by performing PLA of silver (Ag) plates in a supercritical CO₂ medium. Ag NPs were successfully generated by allowing the selective generation of clusters. Laser ablation was performed with an excitation wavelength of 532 nm under various pressures and temperatures of CO₂ medium. On the basis of the experimental result, both surface of the irradiated Ag plate and structure of Ag NPs were significantly affected by the changes in supercritical CO₂ pressure and temperature. With increasing irradiation pressure, plume deposited in the surrounding crater created by the ablation was clearly observed. In Field Emission Scanning Electron Microscopy (FE-SEM) the image of the generated Ag NPs on the silicon wafer and the morphology of Ag particles were basically a sphere-like structure. Ag particles contain NPs with large-varied diameter ranging from 5 nm to 1.2 μm. The bigger Ag NPs melted during the ablation process and then ejected smaller spherical Ag NPs, which formed nanoclusters attached on the molten Ag NPs. The smaller Ag NPs were also formed around the bigger Ag NPs. Based on the results, this new method can also be used to obtain advanced nano-structured materials.     

Structural,electrochemical, and adsorption studies of Ni and Zn benzylimidazole coordination polymers with terephthalate linkers

Two coordination polymers, [Ni(bim)₂(L1)(H₂O)₂] _n (CP-1) and [Zn(bim)(L1)(Cl)] _n (CP-2) (bim = 1-benzylimidazole, L1 = terephthalic acid), were synthesized and characterized by physicochemical and spectroscopic methods. The Ni(II) center in CP-1 is octahedral, while the Zn(II) center in CP-2 is tetrahedral. CP-1 and CP-2 were used to modify carbon paste electrodes to assess their effect on the electrochemical behavior of ferricyanide. The redox reactions of ferricyanide on both electrodes proved to be reversible and diffusion controlled, with ferricyanide diffusion coefficients for CP-1 and CP-2 of 1.88 × 10⁵ and 3.44 × 10⁵ cm² s^?1, respectively. These coordination polymers were also investigated for their adsorption behavior toward two dyes: Chicago sky blue and methylene blue. CP-1 and CP-2 both rapidly adsorbed the anionic Chicago sky blue dye by different intermolecular interactions; in contrast, the cationic methylene blue dye was adsorbed to a lesser extent. The adsorption of these CPs depends on the charge but not the size of the dye. Addition of methanolic potassium nitrate solution caused the release of the adsorbed dyes.