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41.
Photopyroelectric spectroscopy of Sb<Subscript>2</Subscript>O<Subscript>3</Subscript> - ZnO ceramics
A. Zakaria Z. Rizwan M. Hashim A. Halim Shaari W. Mohmood Mat Yunus 《The European physical journal. Special topics》2008,153(1):33-35
Photopyroelectric spectroscopy is used to study the
band-gap energy of the ceramic (ZnO + xSb2O3), x = 0.1 - 1.5 mol%
and the ceramic (ZnO + 0.4 mol% Bi2O3 + xSb2O3), x = 0 - 1.5 mol% sintered at isothermal temperature, 1280 °C, for 1 and 2 hours. The wavelength of incident light, modulated
at 9 Hz, is kept in the visible range and the photopyroelectric spectrum with
reference to doping level is discussed. The band-gap energy is reduced from
3.2 eV, for pure ZnO, to 2.86, 2.83 eV for the samples without
Bi2O3at 0.1 mol% of Sb2O3 for 1 and 2 hours of
sintering time, respectively. It is reduced to 2.83, 2.80 eV for the samples
with Bi2O3 at 0 mol% of Sb2O3 for 1 and 2 hours of
sintering time, respectively. The steepness factor σA which
characterizes the slop of exponential optical absorption is discussed with
reference to the doping level. The phase constitution is determined by XRD
analysis; microstructure and compositional analysis of the selected areas
are analyzed using SEM and EDX. 相似文献
42.
Zagier constructed a cusp form for each weightk of the full modular group. We use this construction to estimate Fourier coefficients of cusp forms. In particular, we get
a non-trivial estimate, by elementary methods and indicate a relationship with the Lindelof hypothesis for classical Dirichlet
L-functions.
Dedicated to the memory of Professor K G Ramanathan 相似文献
43.
44.
Tarafder M. Tofazzal H. Asmadi A. Talib Siti M. S. Ali A. M. Crouse K. A. 《Transition Metal Chemistry》2001,26(1-2):170-174
Complexes of S-benzyldithiocarbazate (SBDTC) with lighter and heavier metals, viz., CrIII, FeIII, SbIII, ZrIV, ThIV and UVI have been prepared and characterized by elemental analyses, conductivity measurements, and spectral studies. The complexes: [Cr(SBDTCA)3],** [Fe(SBDTCA)3], [Sb(SBDTCA)3], [Sb(SBDTCA)2Cl · H2O], [Zr(O)(SBDTCA)2 · H2O], [Th(SBDTCA)(NO3)3 · H2O)], and [U(O)2(SBDTCA)2] were all prepared in alkaline media. They were all hexa-coordinated with bidentate, uninegative chelation of the ligand. [Fe(SBDTCA)3], [Sb(SBDTCA)3] and [Sb(SBDTCA)2Cl · H2O] were strongly effective against bacteria giving clear inhibition zones with Pseudomonas aeruginosa and Bacillus cereus. The compounds showed poor antifungal activity. The antimony complexes were strongly cytotoxic against leukemic cells with CD50 values of 3.2–6.7 g cm–3 as compared to the CD50 value of 14.5 g cm–3 of the free SbCl3 molecule. 相似文献
45.
Let (Xn,dn) be a sequence of finite metric spaces of uniformlybounded diameter. An equivalence relation D on the product defined by if and only if is a c0-equality.A systematic study is made of c0-equalities and Borel reductionsbetween them. Necessary and sufficient conditions, expressedin terms of combinatorial properties of metrics dn, are obtainedfor a c0-equality to be effectively reducible to the isomorphismrelation of countable structures. It is proved that every Borelequivalence relation E reducible to a c0-equality D either reducesa c0-equality D' additively reducible to D, or is Borel-reducibleto the equality relation on countable sets of reals. An appropriatelydefined sequence of metrics provides a c0-equality which isa turbulent orbit equivalence relation with no minimum turbulentequivalence relation reducible to it. This answers a questionof Hjorth. It is also shown that, whenever E is an F-equivalencerelation and D is a c0-equality, every Borel equivalence relationreducible to both D and to E has to be essentially countable.2000 Mathematics Subject Classification: 03E15. 相似文献
46.
Electrochemical impedance spectroscopy (EIS) was employed to study electrochemical behaviors during Li-ion insertion into
rice husk carbon. The impedance spectra consist of two depressed semicircles in the high and middle range frequency and an
incline line at low frequency. The impedance spectra, obtained in the potential range 2.0 to 0.005 V were analyzed with an
equivalent circuit model. Kinetic parameters such as the charge-transfer resistance and surface film resistance were evaluated
and discussed.
Paper presented at the International Conference on Solid State Science and Technology 2006, Kuala Terengganu, Malaysia, September
4–6, 2006. 相似文献
47.
Surface-confined telechelic poly(ε-caprolactone) macroligand with two distinct functional groups per polymeric chain has been synthesized and characterized. The molecular microstructure of the macroligand with regard to the properties of the end-capped functionalities and with those on surface substrate has been studied by solution and surface analytical methods (i.e., X-ray photoelectron spectroscopy (XPS), grazing angle reflectance-Fourier transform IR spectroscopy (GA-FTIR), water contact angle measurements, and atomic force microscopy (AFM)) to elucidate the structure and properties of such multifunctional polymer on gold (1 1 1) substrate. 相似文献
48.
Afaq Shagufta Khan Sadia Kazmi Mehdi Hassan Fatima Itrat Malik Abdul Inamullah Farah Farhad Zahid Abbas Tanveer Tareen Rasool Bakhsh 《Chemistry of Natural Compounds》2021,57(2):269-273
Chemistry of Natural Compounds - Armatans A (1) and B (2), new isoflavans, have been isolated from the EtOAc-soluble fraction of the MeOH extract of Colutea armata Hemsl. & Lace, along with... 相似文献
49.
Kirchberg asked in 2004 whether the commutant of L(H) in its (norm) ultrapower is trivial. Assuming the Continuum Hypothesis, we prove that the answer depends on the choice of
the ultrafilter. 相似文献
50.