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31.
We deal with the scattering of an acoustic medium modeled by an index of refraction n varying in a bounded region Ω of and equal to unity outside Ω. This region is perforated with an extremely large number of small holes Dm's of maximum radius a, a << 1, modeled by surface impedance functions. Precisely, we are in the regime described by the number of holes of the order M:=O(aβ ? 2), the minimum distance between the holes is dat, and the surface impedance functions of the form λmλm,0a?β with β > 0 and λm,0 being constants and eventually complex numbers. Under some natural conditions on the parameters β,t, and λm,0, we characterize the equivalent medium generating approximately the same scattered waves as the original perforated acoustic medium. We give an explicit error estimate between the scattered waves generated by the perforated medium and the equivalent one, respectively, as a→0. As applications of these results, we discuss the following findings:
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The alpha-alkylation of amide enolates by using a pseudo-C(2) symmetry trans 4-phenyl-2-trifluoromethyloxazolidine (trans-Fox) as a chiral auxiliary occurs with an extremely high diastereoselectivity (>99 % de). The origin of this excellent stereocontrol was investigated by an experimental and theoretical (DFT) study. With this trans chiral auxiliary, both F...metal and pi...metal interactions compete to give the same diastereomer through Re face alkylation of the enolate. A 5.5 kcal mol(-1) energy difference found between the Re face and the Si face attack transition states is consistent with the complete diastereoselectivity that has been experimentally achieved. On the other hand, in the case of the cis chiral auxiliary (cis-Fox) the competition between the F...metal and pi...metal interactions is unfavourable to the diastereoselectivity. In this case, the Re face and the Si face attack transition states were found to be nearly isoenergetic (0.3 kcal mol(-1) difference), which is in good agreement with the very low diastereoselectivity observed.  相似文献   
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A multicomplexM is a collection of monomials closed under divisibility. For suchM we construct a cell complex M whosei-dimensional cells are in bijection with thef i monomials ofM of degreei+1. The bijection is such that the inclusion relation of cells corresponds to divisibility of monomials. We then study relations between the numbersf i and the Betti numbers of M. For squarefree monomials the construction specializes to the standard geometric realization of a simplicial complex.This work was supported by the Mittag-Leffler Institute during the Combinatorial Year program 1991–92. The second author also acknowledges support from the Serbian Science Foundation, Grant No. 0401D.  相似文献   
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This work is concerned with the inverse problem for ocean acoustics modeled by a multilayered waveguide with a finite depth. We provide explicit formulae to locate the layers, including the seabed, and reconstruct the speed of sound and the densities in each layer from measurements collected on the surface of the waveguide. We proceed in two steps. First, we use Gaussian type excitations on the upper surface of the waveguide and then from the corresponding scattered fields, collected on the same surface, we recover the boundary spectral data of the related 1D spectral problem. Second, from these spectral data, we reconstruct the values of the normal derivatives of the singular solutions, of the original waveguide problem, on that upper surface. Finally, we derive formulae to reconstruct the layers from these values based on the asymptotic expansion of these singular solutions in terms of the source points.  相似文献   
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In this paper we present numerical simulations for the dam-break flood wave propagation from Tribalj accumulation to the town of Crikvenica (Croatia). The mathematical models we used were the one-dimensional open channel flow and the two-dimensional shallow water equations. They were solved with the well-balanced finite volume numerical schemes which additionally include special numerical treatment of the wetting/drying front boundary. These schemes were tested on CADAM test problems. The aim of this study was to assess potential damage in the village of Tribalj and the town of Crikvenica. Results of these simulations were used as the basis for urban planning and micro-zoning of the flood-risk areas. Several different dam-break scenarios were considered, ranging from sudden dam disappearance to partial and dynamic breach formation.   相似文献   
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A numerical study using improved delayed detached eddy simulation (IDDES) was used to investigate the influence of the embankment height on the aerodynamic performance of a high-speed train travelling under the influence of a crosswind. The results of the flow predictions were used to explore both the instantaneous and the time-averaged flows and the resulting aerodynamic forces, moments and slipstreams. An increase of the aerodynamic drag and side forces as well as the lift force of the head and middle cars were observed with rising embankment height. While the lift force of the tail car decreased with the increasing embankment height. Furthermore, the height of the embankment was found to have a strong influence on the slipstream on the leeward side of the train. The correlation between the embankment height and the slipstream velocity on the windward side, was rather small. The flow structures in the near-wake of the leeward side of the train, responsible for the aerodynamic properties of the train were analyzed, showing strong dependency on the embankment height.

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