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991.
Jyotsna Galgale Nupinder Kaur Preeti Singh Manik Manake N. K. Gaur R. K. Singh 《Pramana》2004,63(2):413-417
An extended three-body force shell model (ETSM) has been applied to investigate the static and dynamic properties of KCN
x
Cl1−x
for the compositionx = 0.56 and 1.0 at 300 K. The phonon dispersion curves computed by us are compared with the single crystal neutron diffraction
data. The unusual features of these curves are the upward curvature seen in some of the acoustic branches. This is a result
ofK-dependent softening of the phonon due to translation-rotation coupling. The transverse acoustic branch is more soft near
the zone centre. 相似文献
992.
Fluorescence spectrum of Dy3+, Dy3+-Ho3+, Tb3+ and Tb3+-Er3+ doped in calibo glass have been studied using Ar+ and excimer lasers. Non-radiative energy transfer from trivalent dysprosium and terbium (donors) to holmium and erbium (acceptors)
respectively has been observed on the basis of decrease in the life time of the levels and reduction in fluorescence intensity
of Dy3+ and Tb3+ on increasing Ho and Er concentrations. The interaction mechanism of donor and acceptor ions is found to be dipole-dipole
in both cases. Various parameters such as donor-acceptor distances, non-radiative energy transfer efficiency (η) and energy transfer probability (P
da) have been computed. Stark splitting have also been marked in several intense transition of the two. 相似文献
993.
It is found from Maxwell's equations that the magnetic field lines are good analogues of relativistic strings. It is shown that the superconducting current in the neutron star's interior causes local rotation of magnetic flux tubes carrying quantized flux. 相似文献
994.
A system consisting of two interacting particles, one of which has the angular momentum 1/2 and the other of which has an arbitrary angular momentum (a muonium-like system) is considered. The possibility of reconstruction of all the elements of the spin density matrix with the help of the μSR method is shown. For entangled states (Einstein-Podolsky-Rosen and Schrödinger cat states), the time dependence of components of the polarization vector (μSR photographs) is demonstrated. It is shown that, to identify these states, two μSR photographs suffice. 相似文献
995.
New series of phenylantimony chloride and antimony chloride with Schiff base ligands, L1H and L2H having N∩S and N∩O donor systems were synthesized under microwave irradiation using a domestic microwave oven. The reaction time was brought down from hours to a few seconds with improved yield as compared with conventional heating. All the ligands and their antimony(III) derivatives were characterized on the basis of microanalysis, elemental analyses, molecular weight determinations and spectral studies including IR, NMR (1H and 13C) and electronic spectral studies. A distorted trigonal bipyramidal and pseudo‐octahedral geometry around the antimony atom was tentatively proposed for these derivatives. The compounds were screened in vitro against bacteria and fungi to test their antimicrobial property and in vivo in male albino rats to test their antifertility properties. The treatment with the ligands and their phenylantimony derivatives at dose levels of 20 mg per rat per day did not cause any significant change in body weight, but a significant reduction in the weights of reproductive organs was observed. Arrest of spermatogenesis was noted at various stages with production of primary spermatocytes (preleptotene and pachytene), secondary spermatocytes and step‐19 spermatids found to be decreased. Biochemical parameters of tissues, i.e. protein, sialic acid, cholesterol content of testes and seminal vesicular fructose also showed significant reduction. Further, the serum testosterone concentrations were also decreased after treatment with ligands and their antimony(III) derivatives. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
996.
K. Singh S.M. Pande S.W. Anwane S.S. Bhoga 《Applied Physics A: Materials Science & Processing》1998,66(2):205-215
2 SO4. The solid solubility limits up to x≤3 mole% for monovalent, x≤5.27 mole% for divalent and x≤3.63 mole% for trivalent cation
doped Ag2SO4 are set with XRD, SEM, IR and DSC techniques. A predominant dependence of conductivity on the ionic size of iso- and alio-valent
cations is observed. In particular, the conductivity enhances in both α and β phases, despite having a lower ionic-size dopant
cation (relative to that of Ag+) in the transition element cation doped Ag2SO4. Ca2+, Ba2+, Y3+ and Dy3+ doped samples show depature from the regular behaviour in the β-phase. The conductivity behaviour is discussed considering
ionic size, valence and electronic structure of the guest cations.
Received: 3 February 1997/Accepted: 27 May 1997 相似文献
997.
Manganese(III) acetate mediated oxidation of aporphines to oxoaporphines is described. The developed methodology was conveniently applied for the synthesis of naturally occurring oxoaporphine alkaloids, oxoglaucine, and atheroline, starting from commercially available boldine. 相似文献
998.
The influence of analyte mass concentration on determination of detection limits in X-ray fluorescence spectrometry has been investigated experimentally. Both the total reflection X-ray fluorescence (TXRF) and the conventional energy-dispersive X-ray fluorescence techniques have been used to derive the dependence of analyte mass concentration on the values of detection limits. Results obtained indicate that values of detection limits are optimum, or in other words, they are closer to the true detection limit of the technique, when analyte concentrations are in the range of 10 times of the detection limit. 相似文献
999.
The LR-115 type-II plastic track detector has been used for measuring the indoor radon levels in the dwellings of some villages of Punjab and Himachal Pradesh. In Punjab, the villages surveyed are Rampura Phul, Lehra Mahabat and Pitho (villages in Bathinda district), and Amritsar city. The average indoor radon levels in these areas are found to vary from 64 to 152 Bq/m3, which are quite within the safe limits recommended by International Commission on Radiological Protection (Ann. ICRP 23(2)). The indoor radon levels have also been measured in the dwellings of Hamirpur district of Himachal Pradesh. The villages surveyed in this area are Nukhel, Badarn, Galore-Khas, Har-Upper, Tikker Brahamana and Awah-Lower where radon concentration has been found to vary from 261 to 724 Bq/m3. These values are higher than the recommended limit. 相似文献
1000.