Aging effect of diethanolamine derived precursor sol on TiO<Subscript>2</Subscript> films deposited at different annealing temperatures

A diethanolamine stabilized precursor sol has been utilized for studying the effect of sol aging and annealing temperature on key properties of TiO₂ films. X-ray diffraction investigations have shown increased crystallite size in the films as a function of both sol aging and the thermal treatment. Fourier transform infrared studies have elucidated that cleavage of the bond involving diethanolamine and the alkoxide in the films requires high temperature annealing treatment upon the use of aged sol for the deposition of the films. Multiple step chronoamperometry has shown the ion storage capacity of the films increases as a function of sol aging, with the highest extent of Li ion insertion being obtained for films produced from as-prepared and aged sols and subsequently annealed at, 300 and 350 °C, respectively. Films with excellent optical quality were obtained. Ellipsometry revealed that the refractive indices of the films vary from 1.67 to 2.02. The highest thickness obtained in these films was nearly 900 nm. The bandgaps of the films for both direct and indirect transitions decreased as a function of precursor sol’s aging. In addition, although the indirect bandgap values have shown a decrease with increasing annealing temperature, the direct bandgap values reveal a slight increase as a function of annealing temperature.     

Reactivity studies of carbon,phosphorus and sulfur‐based acyl sites with tertiary oximes in gemini surfactants

Kinetic studies of the reactions of tertiary oximes (monoisonitroso acetone; MINA and butane 2,3 dione monooxime; BDMO) with some carboxylate (p‐nitrophenyl acetate and p‐nitrophenyl benzoate), phosphate (p‐nitrophenyl diphenyl phosphate and bis (2,4‐dinitrophenyl) phosphate) and sulfonate (p‐nitrophenyl p‐toluene sulphonate) esters in gemini surfactants have been conducted. The observed first‐order rate constant versus surfactant profiles show micelle‐assisted bimolecular reactions involving interfacial ion exchange between bulk aqueous media and micellar pseudophase. Experimental results showed that MINA exhibited better nucleophilic activity towards ester cleavage than BDMO. Pseudophase model has been applied in order to determine micellar second‐order rate constants and binding constants. Copyright © 2013 John Wiley & Sons, Ltd.     

A Convenient Synthesis of Novel Pentacyclo [5.4. 0.02,6 .03,10 .05,9] Undecane-8,11-dione-4-spiro-1-cyclopropane

An efficient synthesis of the title compound by Diels-Alder cycloaddition of spiro(4.2) heptadiene with p-benzoquinone followed by photochemical ring closure is described.     

Perturbed angular correlation study of radiation-induced defects in Rh metal

Radiation-induced defects are studied in cubic rhodium metal, using the local probe technique ‘Time differential perturbed angular correlation’ (TDPAC) at liquid N₂ temperature. Isochronal annealing was done at 300, 1073 and 1473 K temperatures. The irradiated sample showed two quadrupole interaction frequencies at 1150 and 93 MHz. The low frequency disappeared at room-temperature annealing, which was assigned to In trapped at a vacancy, whereas the higher frequency remained up to high temperatures and was attributed to In trapped at Rh–C complexes in the Rh matrix.     

Implementation of anti-reflection coating to enhance light out-coupling in organic light-emitting devices

We report significant enhancement of light out-coupling in organic light-emitting devices (OLEDs) by means of anti-reflection coating of magnesium fluoride (MgF₂) on the backside of glass substrate. OLEDs were fabricated by employing the green electrophosphorescent material fac tris-(2-phenylpyridine) iridium [Ir(ppy)₃] doped in 4,4′,8-N,N-8-dicarbazole-biphenyl (CBP) and 0.4 wt% tetrafluorotetracyano-quinodimethane (F4-TCNQ)-doped naphthylphenylbiphenyl diamine (α-NPD) as hole transport layer (HTL). Single-layer MgF₂ with the thickness of λ/4 was then vacuum deposited on the backside of glass substrate of OLED. About two-fold enhancement in luminance with anti-reflection coating of MgF₂ has been observed.     

Total attenuation cross-sections of fluorescent X-rays of Zr,Sn, Ba,Au, Pb,Th and U in elements 6⩽Z⩽82

The total attenuation cross-sections in elements 6?Z?82 forK _α andK _β groups of lines of elements Zr, Sn and Ba andL _l ,L _α,L _β andL _γ groups of lines of the elements Au, Pb, Th and U have been measured. The experimentally measured attenuation cross-sections have been found in good agreement with the theoretical estimates.