Structure and temperature controlled synthesis of novel thiazolidin-4-one derivatives bearing an azasugar

Novel thiazolidin-4-one linked pseudo-aza-disaccharides and thiazolidin-4-ones containing C-pseudo-aza-nucleosides were synthesized via a one-pot three component reaction. The former was synthesized stereoselectively by the tandem Staudinger/aza-Wittig/cyclization reaction of azasugar aldehyde 1, an azidosugar, and mercaptoacetic acid. The reaction was structure and temperature controlled, and could be performed stereospecifically under 40 °C. It was the first report of a stereospecific synthesis of thiazolidin-4-one linked derivatives. However, these derivatives were synthesized with low stereoselectivity by involving the condensation reaction of azasugar aldehyde 1, aniline, and mercaptoacetic acid.     

Study of asymmetric aldol and Mannich reactions catalyzed by proline–thiourea host–guest complexes in nonpolar solvents

A proline–thiourea host–guest complex has been described as a good catalyst for asymmetric reactions such as aldol and Mannich reactions. High stereoselectivities were obtained under optimal conditions. Thiourea was observed to have an important effect on the reactivity and selectivity, even in an unconventional nonpolar reaction medium and without the need to utilize low temperatures. This proline–thiourea host–guest system has the ability to participate in a hydrogen bonding network.     

N-3烷基取代嘧啶及其衍生物的合成

在室温条件下,经过三步反应,合成了一系列N-3烷基取代的嘧啶类化合物.该方法具有条件温和、操作简便、反应时间短、产率高等特点.目标产物经过了1HNMR,13C NMR和MS确证表征.     

The <Emphasis Type="Italic">p</Emphasis>-Cockcroft Property of Central Extensions of Groups II

In [6], ?evik defined necessary and sufficient conditions for the presentation of a central extension of a cyclic group by an ordinary group to be p-Cockcroft, where p is a prime or 0. In this paper, as a next step of this above result, we will define the p-Cockcroft property for the presentation of a central extension of an abelian group by any group. Finally, as an application of the main result, we will present an example.     

Zur Reaktion von Phenazon und lithiiertem Phenazon mit Aryl-Carbonyl-Derivaten

Some new experimental results are described on the acid catalysed reaction of the 4-Pyrazoline-3-on (1a) with aromatic aldehydes leading to the cationic derivatives4 and5.4-Pyrazoline-3-on-lithium (1b), synthesised for the first time, gives in good yield with 4-dimethylaminobenzaldehyde under mild condition the cyanine2b and with benzophenone the pyrazolyl-diphenylmethane dye8.

Zur Struktur von2a und4a siehe Lit.².     

Quantum wave packet study of the insertion reaction S+H2

S(¹D)+H₂→SH+H reaction at zero total angular momentum has been studied by using a time-dependent quantum real wave packet method. State-to-state and state-to-all reactive scattering probabilities for a broad range of energy are calculated. The probabilities show many sharp peaks that ascribed to reactive scattering resonances. The density plots of the wave function shows that the reaction presents a pure insertion pathway.     

Perspectives of aerosol-photopolymerization: organic-inorganic hybrid nanoparticles

The technique of aerosol-photopolymerization is employed for the generation of organic-inorganic spherical polymer-matrix nanocomposites (PMNCs). The loading amount of well-distributed ZnO nanoparticles in polymer networks is varied in a broad range up to 40 wt.%. Similar hybrid particles are produced without the addition of a conventional photoinitiator by making use of the UV absorptivity of ZnO nanoparticles only. Highlights of the process are the continuous, aerosol-based setup with a flow-through photoreactor operated at ambient temperature and atmospheric pressure. Aerosol-photopolymerization possesses great potential of incorporating various materials in situ into a polymer matrix, resulting in hybrid materials for diverse applications. Furthermore, the process can be integrated with further unit operations for the design of smart materials.     

Reinforcing thermosets with crystallizable solvents

This study demonstrates an approach to generate reinforcement in thermosetting polymers through crystal growth of crystallizable solvents. Emphasis is to identify the reaction conditions, which lead to suitable reinforcement in selected compounds. Crystallization behavior and miscibility of dimethylsulfone (DMS) in diglycidylether of bisphenol‐A epoxy monomer was investigated. Small angle laser scattering and optical microscopy were utilized to monitor phase separation and crystallization of DMS at different isothermal conditions during the cure process. It is shown that DMS crystals grow anisotropically to form faceted geometries and demonstrate possible structures to anchor into the epoxy matrix. The growth mechanism and the agility of crystals are shown to be affected by the cure reaction as well as depth of supercooling. A completely cured sample with 15 wt % DMS shows a broad map of rich morphologies from nanoscale particles to uniformly distributed macroscale, discontinuous fiber‐like crystals generated only by altering the curing conditions. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 840–849, 2010     

On the purely irregular fundamental group

Based on the (not yet fully understood analogy) between irregular connections and wild ramification, we define a purely irregular fundamental group for complex algebraic varieties and prove some results about this fundamental group which are analogous to the p‐adic étale fundamental group of algebraic varieties over fields of characteristic p (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Solutions of fractional gas dynamics equation by a new technique

In this paper, a novel technique is formed to obtain the solution of a fractional gas dynamics equation. Some reproducing kernel Hilbert spaces are defined. Reproducing kernel functions of these spaces have been found. Some numerical examples are shown to confirm the efficiency of the reproducing kernel Hilbert space method. The accurate pulchritude of the paper is arisen in its strong implementation of Caputo fractional order time derivative on the classical equations with the success of the highly accurate solutions by the series solutions. Reproducing kernel Hilbert space method is actually capable of reducing the size of the numerical work. Numerical results for different particular cases of the equations are given in the numerical section.