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71.
Ana?Maria?Gonzalez Wendy?E?Leadbeater Michael?Burg Karen?Sims Tetsuya?Terasaki Conrad?E?Johanson Edward?G?Stopa Brian?P?Eliceiri Andrew?BairdEmail author 《BMC neuroscience》2011,12(1):4
Background
Because the choroid plexus (CP) is uniquely suited to control the composition of cerebrospinal fluid (CSF), there may be therapeutic benefits to increasing the levels of biologically active proteins in CSF to modulate central nervous system (CNS) functions. To this end, we sought to identify peptides capable of ligand-mediated targeting to CP epithelial cells reasoning that they could be exploited to deliver drugs, biotherapeutics and genes to the CNS. 相似文献72.
Michael Aizenman Robert Sims Simone Warzel 《Communications in Mathematical Physics》2006,264(2):371-389
We consider the Laplacian on a rooted metric tree graph with branching number K≥2 and random edge lengths given by independent and identically distributed bounded variables. Our main result is the stability of the absolutely continuous spectrum for weak disorder. A useful tool in the discussion is a function which expresses a directional transmission amplitude to infinity and forms a generalization of the Weyl-Titchmarsh function to trees. The proof of the main result rests on upper bounds on the range of fluctuations of this quantity in the limit of weak disorder. 相似文献
73.
A metal-insulator crossover appears in the experimental data for in-plane resistivity of underdoped cuprates and a range of
superconducting cuprates in the presence of a strong magnetic field suppressing superconductivity. We propose an explanation
for this phenomenon based on a gauge field theory approach to the t-J model. In this approach, based on a formal spin-charge
separation, the low energy effective action describes gapful spinons (with a theoretically derived doping dependence of the
gap m
s
2
∼ δ| ln δ|) and holons with finite Fermi surface (ɛF ∼ tδ) interacting via a gauge field whose basic effect on the spinons is to bind them into overdamped spin waves, shifting their
gap by a damping term linear in T, which causes the metal-insulator crossover. The presence of a magnetic field perpendicular to the plane acts by increasing
the damping, in turn producing a big positive transverse in-plane magnetoresistance at low T, as experimentally observed. 相似文献
74.
The furanosesquiterpene, pallescensin-E has been prepared by a route involving reaction of a dimethyl 3-furylmethyl phosphonate anion with 2,3-dimethylbenzaldehyde in the presence of 15-crown-5; this reaction has been shown to have general applicability. 相似文献
75.
Examination of the red alga Plocamium cartilagineum (L.) Dixon collected along the Antarctic Peninsula yielded several new cyclic halogenated monoterpenes. The structures of a 2,4-dichloro-trans-1-chloro-vinyl-1-methyl-5-methylene-cyclohexane, a 2-chloro-4-bromo-trans-1-chlorovinyl-1-methyl-5-methylene-cyclohexane, a 2-chloro-trans-1-chlorovinyl-1-methyl-5-chloromethyl-4-cyclohexene, and a 2,5-dichloro-4-bromo-trans-1-chlorovinyl-1-methyl-5-bromomethyl-cyclohexane are described. The structures were determined by spectroscopic methods and chemically related to the halogenated monoterpene violacene. 相似文献
76.
Houssam Abdul-Rahman Bruno Nachtergaele Robert Sims Günter Stolz 《Letters in Mathematical Physics》2016,106(5):649-674
We consider the dynamics of the quantum XY chain with disorder under the general assumption that the expectation of the eigenfunction correlator of the associated one-particle Hamiltonian satisfies a decay estimate typical of Anderson localization. We show that, starting from a broad class of product initial states, entanglement remains bounded for all times. For the XX chain, we also derive bounds on the particle transport which, in particular, show that the density profile of initial states that consist of fully occupied and empty intervals only have significant dynamics near the edges of those intervals, uniformly for all times. 相似文献
77.
Fungal reduced polyketides possess diverse structures exploring a broad region of chemical space despite their synthesis by very similar enzymes. Many fungal polyketides are capped by diverse amino acid-derived five-membered rings, the tetramic acids and related pyrrolidine-2-ones. The known tetramic acid synthetase enzymes in fungi contain C-terminal reductive (R) domains that were proposed to release reduced pyrrolidine-2-one intermediates en route to the tetramic acids. To determine the enzymatic basis of pyrrolidine-2-one diversity, we overexpressed equisetin synthetase (EqiS) R domains and analyzed their reactivity with synthetic substrate analogs. We show that the EqiS R domain does not perform a reducing function and does not bind reducing cofactors. Instead, the EqiS R catalyzes a Dieckmann condensation, with an estimated kcat approximately 15 s(-1). This role differs from the redox reactions normally catalyzed by short chain dehydrogenase/reductase superfamily enzymes. 相似文献
78.
The kinetics of reactions of C2(a(3)Pi(u)) and C2(X(1)Sigma(g)(+)) with various hydrocarbons (CH4, C2H2, C2H4, C2H6, and C3H8) have been studied in a uniform supersonic flow expansion over the temperature range 24-300 K. Rate coefficients have been obtained by using the pulsed laser photolysis-laser induced fluorescence technique, where both radicals were produced at the same time but detected separately. The reactivity of the triplet state was found to be significantly lower than that of the singlet ground state for all reactants over the whole temperature range of the study. Whereas C2(X(1)Sigma(g)(+)) reacts with a rate coefficient close to the gas kinetic limit with all hydrocarbons studied apart from CH4, C2(a(3)Pi(u)) appears to be more sensitive to the molecular and electronic structure of the reactant partners. The latter reacts at least one order of magnitude faster with unsaturated hydrocarbons than with alkanes, and the rate coefficients increase very significantly with the size of the alkane. Results are briefly discussed in terms of their potential astrophysical impact. 相似文献
79.
Dyes in Liquid Crystals: Experimental and Computational Studies of a Guest–Host System Based on a Combined DFT and MD Approach
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Mark T. Sims Dr. Laurence C. Abbott Dr. Stephen J. Cowling Prof. Dr. John W. Goodby Dr. John N. Moore 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(28):10123-10130
Practical applications of guest–host liquid crystal systems are critically dependent on the alignment of the guest species within the liquid crystal host. UV/Vis absorption spectroscopy shows that the 1,5‐dihydroxy‐2,6‐bis‐(4‐propylphenyl)‐9,10‐anthraquinone dye aligns within the E7 nematic host, giving an experimental dichroic ratio of 9.40 and dye order parameter of 0.74. This alignment was modelled by using a combination of density functional theory (DFT) and molecular dynamics (MD) computational approaches that do not require the input of experimental data. Time‐dependent DFT calculations show that the electronic transition dipole moment is highly aligned with the long molecular axis of the dye. Fully atomistic MD simulations show that the long axis of the dye is less highly aligned within the E7 host, indicating that this contribution limits the overall dye alignment and, thereby, the potential practical applications of this particular system. Importantly, this study demonstrates an experimental and combined DFT and MD computational approach that may be applied generally to guest–host systems, providing a potential route to their rational design. 相似文献
80.
Modsching N Kadwani P Sims RA Leick L Broeng J Shah L Richardson M 《Optics letters》2011,36(19):3873-3875
We describe lasing of a thulium-doped polarizing photonic crystal fiber. A 4 m long fiber with 50 μm diameter core, 250 μm diameter cladding, and d/Λ ratio of 0.18 was pumped with a 793 nm diode and produced a polarized output with a polarization extinction ratio (PER) of 15 dB and an M(2) of <1.15. An intracavity polarizer and half-wave plate minimally increased the PER to 16 dB. The output power had 35% slope efficiency relative to the absorbed pump power. The maximum cw output power was limited to 4 W due to the quantum defect heating of the fiber. 相似文献