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171.
172.
The mechanism of nucleophilic substitution in cyclobutane derivatives has been studied by means of ab initio molecular orbital computations on a model system. The results are in favour of a reaction which proceeds with inversion of configuration, in agreement with experimental data. 相似文献
173.
Results from LEED dynamical calculations performed on the Ni(100) c(2 × 2)C2H2 structure, produced by adsorption of C2H2 at about 273 K and 1.5 L exposure, are reported. Among the several model geometries tried, the most favoured one appears to be a distorted acetylene molecule with the midpoint of the CC bond (1.20 Å long) placed above the fourfold hollow site at a vertical distance 2.02 Å from the topmost Ni layer and with the CC axis itself tilted by 50° with respect to the surface normal in the [011] direction. In this geometry the NiC distance is 2.2 Å. 相似文献
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175.
Massimo Di Vaira Simonetta Moneti Maurizio Peruzzini Piero Stoppioni 《Journal of organometallic chemistry》1984,266(1):c8-c10
Reaction of the [(triphos)Co(E2S)]BF4 complexes (triphos = 1,1,1-tris(di-phenylphosphinomethyl)ethane, E = P or As) containing the P2S or As2S cyclic units trihapto(η3-bonded to the metal, with (C2H4)Pt(PPh3)2 involves insertion of the Pt(PPh3)2 moiety into a bond of the inorganic ring, yielding the compounds [(triphos)Co(E2S)Pt(PPh3)2]BPh4 (E = P or As), whose structures have been determined by X-ray diffraction studies. 相似文献
176.
Gian Franco Tantardini Mario Raimondi Massimo Simonetta 《International journal of quantum chemistry》1973,7(5):893-903
An ab initio valence bond (VB ) method for calculating energies and wave functions for simple electronic systems is described and the results of its application to methylene are given together with extensive comparisons with previous theoretical results. 相似文献
177.
H. Beissler G. A. Petrucci K. Bächmann U. Panne P. Cavalli N. Omenetto 《Fresenius' Journal of Analytical Chemistry》1996,355(3-4):345-347
A method is described for measuring the gold content of integral and size-segregated samples of atmospheric particulate matter. After acid digestion and a liquid/ liquid extraction, the sample are analysed by Two-Colour Laser Induced Fluorescence in a graphite furnace. An absolute instrumental detection limit of 1 fg is achieved. Assuming a sampled volume of 1 m3, this corresponds to an atmospheric concentration of 50 fg m–3. Due to blank limited noise, the above limits increase to 20 fg and 1 pg m–3, respectively. Results of the analysis of filter samples as well as of size-segregated impactor samples are presented. 相似文献
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