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71.
Polyamide 12 (PA12) is used in a variety of applications when low moisture absorption, good dimensional stability, and toughness are required. Polyamide 12 is one of the polymers most frequently employed to fabricate angioplasty balloon catheters; however, its high hydrophobicity and chemical inertness require the application of coatings to make its surface more hydrophilic and biocompatible. In this work, an alternative method, based on the photochemical reaction of PA12 with a hydrophilic aromatic azide, was developed. Static and dynamic contact angle measurements evidenced that the surface modification process was able to improve PA12 wettability and that the effects were retained even after 12 months from surface treatment. Polyamide 12 modification resulted in an increase of its surface free energy, as evaluated by the van Oss, Good, and Chaudhury method. X‐ray photoelectron spectroscopy confirmed the presence of the aromatic azide on PA12 surface. Finally, compliance tests showed that the modification process did not reduce the mechanical performance of balloons. 相似文献
72.
Dr. Luca Fornasari Dr. Anna Olejniczak Dr. Federica Rossi Dr. Simone d'Agostino Prof. Michele R. Chierotti Prof. Roberto Gobetto Prof. Andrzej Katrusiak Prof. Dario Braga 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(22):5061-5069
The structures and solid-state dynamics of the supramolecular salts of the general formula [(12-crown-4)2 ⋅ DABCOH2](X)2 (where DABCO=1,4-diazabicyclo[2.2.2]octane, X=BF4, ClO4) have been investigated as a function of temperature (from 100 to 360 K) and pressure (up to 3.4 GPa), through the combination of variable-temperature and variable-pressure XRD techniques and variable-temperature solid-state NMR spectroscopy. The two salts are isomorphous and crystallize in the enantiomeric space groups P3221 and P3121. All building blocks composing the supramolecular complex display dynamic processes at ambient temperature and pressure. It has been demonstrated that the motion of the crown ethers is maintained on lowering the temperature (down to 100 K) or on increasing the pressure (up to 1.5 GPa) thanks to the correlation between neighboring molecules, which mesh and rotate in a concerted manner similar to spiral gears. Above 1.55 GPa, a collapse-type transition to a lower-symmetry ordered structure, not attainable at a temperature of 100 K, takes place, proving, thus, that the pressure acts as the means to couple and decouple the gears. The relationship between temperature and pressure effects on molecular motion in the solid state has also been discussed. 相似文献
73.
Alessio Melli Simone Potenti Dr. Mattia Melosso Dr. Sven Herbers Dr. Lorenzo Spada Dr. Andrea Gualandi Kevin G. Lengsfeld Prof. Luca Dore Philipp Buschmann Prof. Pier Giorgio Cozzi Prof. Jens-Uwe Grabow Prof. Vincenzo Barone Prof. Cristina Puzzarini 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(65):15016-15022
Phenylmethanimine is an aromatic imine with a twofold relevance in chemistry: organic synthesis and astrochemistry. To tackle both aspects, a multidisciplinary strategy has been exploited and a new, easily accessible synthetic approach to generate stable imine-intermediates in the gas phase and in solution has been introduced. The combination of this formation pathway, based on the thermal decomposition of hydrobenzamide, with a state-of-the-art computational characterization of phenylmethanimine laid the foundation for its first laboratory observation by means of rotational electric resonance spectroscopy. Both E and Z isomers have been accurately characterized, thus providing a reliable basis to guide future astronomical observations. A further characterization has been carried out by nuclear magnetic resonance spectroscopy, showing the feasibility of this synthetic approach in solution. The temperature dependence as well as possible mechanisms of the thermolysis process have been examined. 相似文献
74.
The stable adsorption sites for both Ga and N ions on the ideal and on the reconstructed LiNbO3 (0 0 0 1) surface are determined by means of first-principle total energy calculations. A single N layer is found to be more strongly bound to the substrate than a single Ga layer. The adsorption of a GaN monolayer on the polar substrate within different orientations is then modeled. On the basis of our results, we propose a microscopic model for the GaN/LiNbO3 interface. The GaN and LiNbO3 (0 0 0 1) planes are parallel, but rotated by 30° each other, with in-plane epitaxial relationship [1 0 0]GaN‖ [1 1 0]LiNbO3. In this way the (0 0 0 1) plane lattice mismatch between GaN and LiNbO3 is minimal and equal to 6.9% of the GaN lattice constant. The adsorbed GaN and the underlying LiNbO3 substrate have parallel c-axes. 相似文献
75.
Discussed here are criteria for the existence of continuous components in the spectra of operators with random potential. First, the essential condition for the Simon‐Wolff criterion is shown to be measurable at infinity. By implication, for the i.i.d. case and more generally potentials with the K‐property, the criterion is boosted by a zero‐one law. The boosted criterion, combined with tunneling estimates, is then applied for sufficiency conditions for the presence of continuous spectrum for random Schrödinger operators. The general proof strategy that this yields is modeled on the resonant delocalization arguments by which continuous spectrum in the presence of disorder was previously established for random operators on tree graphs. In another application of the Simon‐Wolff rank‐one analysis we prove the almost sure simplicity of the pure point spectrum for operators with random potentials of conditionally continuous distribution.© 2015 Wiley Periodicals, Inc. 相似文献
76.
E. S. Freitas Neto A. C. A. Silva S. W. da Silva P. C. Morais J. A. Gmez O. Baffa N. O. Dantas 《Journal of Raman spectroscopy : JRS》2013,44(7):1022-1032
Glass‐embedded Cd1−xCoxS quantum dots (QDs) with mean radius of R ≈ 1.70 nm were successfully synthesized by a novel protocol on the basis of the melting‐nucleation synthesis route and herein investigated by several experimental techniques. Incorporation of Co2+ ions into the QD lattice was evidenced by X‐ray diffraction and magnetic force microscopy results. Optical absorption features with irregular spacing in the ligand field region confirmed that the majority of the incorporated Co2+ ions are under influence of a low‐symmetry crystal field located near to the Cd1−xCoxS QD surface. Electron paramagnetic resonance data confirmed the presence of Co2+ ions in a highly inhomogeneous crystal field environment identified at the interface between the hosting glass matrix (amorphous) and the crystalline QD. The acoustic‐optical phonon coupling in the Cd1−xCoxS QDs (x ≠ 0.000) was directly observed by Raman measurements, which have shown a high‐frequency shoulder of the longitudinal optical phonon peak. This effect is tuned by the size‐dependent sp‐d exchange interaction due to the magnetic doping, causing variations in the coupling between electrons and longitudinal optical phonon. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
77.
Let P(G,λ) be the chromatic polynomial of a graph G with n vertices, independence number α and clique number ω. We show that for every λ≥n, ()α≤≤ ()
n
−ω. We characterize the graphs that yield the lower bound or the upper bound.?These results give new bounds on the mean colour
number μ(G) of G: n− (n−ω)()
n
−ω≤μ(G)≤n−α() α.
Received: December 12, 2000 / Accepted: October 18, 2001?Published online February 14, 2002 相似文献
78.
Given a settled reduction in the present level of tax revenue, and by exploring a very large combinatorial space of tax structures, in this paper we employ a genetic algorithm in order to determine the ‘best’ structure of a real world personal income tax that allows for the maximisation of the redistributive effect of the tax, while preventing all taxpayers being worse off than with the present tax structure. We take Italy as a case study. 相似文献
79.
Ceccherini S 《Optics letters》2005,30(19):2554-2556
In the retrieval of vertical profiles of atmospheric constituents, regularization methods are frequently used to improve the conditioning of the solution. The regularization reduces the retrieval errors and causes the vertical resolution to deteriorate. One obtains a trade-off by tuning the strength of the regularization by way of a regularization parameter. A new analytical method for determining the regularization parameter is presented. This method is suitable for operational retrievals, for which an unattended procedure is required. The performance of the new method is compared with that of the L-curve method, and the results show that a better trade-off between retrieval errors and vertical resolution is obtained. 相似文献
80.
We present a compact optical design for a multireference Shack-Hartmann-based wavefront sensor (WFS) for multiconjugate adaptive optical systems. The key component of this WFS design is a field lenslet array that separates the exit pupil images in the sensing plane for all reference sources. An analytical method for WFS optical design is presented, and the optimal strategy for selecting optical components from a discrete set is outlined. The feasibility of the WFS design has been demonstrated for a prototype WFS system in a laboratory setup with five reference sources and two deformable mirrors representing a wavefront-distorting medium. 相似文献