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31.
Linear {NiII–LnIII–NiII} Complexes Containing Twisted Planar Ni(μ‐phenolate)2Ln Fragments: Synthesis,Structure, and Magnetothermal Properties
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Sourav Das Atanu Dey Subrata Kundu Sourav Biswas Prof. Dr. A. J. Mota Prof. Dr. Enrique Colacio Prof. Dr. Vadapalli Chandrasekhar 《化学:亚洲杂志》2014,9(7):1876-1887
Sequential reaction of a multisite LH4 ligand {2‐[2‐hydroxy‐3‐(hydroxymethyl)‐5‐methylbenzylideneamino]‐2‐methylpropane‐1,3‐diol} with appropriate lanthanide salts followed by the addition of Ni(NO3)2 ? 6 H2O in a 4:1:2 stoichiometric ratio in the presence of triethylamine afforded four heterobimetallic trinuclear complexes [Ni2Gd(LH3)4] ? 3 NO3 ? 3 MeOH ? H2O ? CH3CN ( 1 ), [Ni2Tb(LH3)4] ? 3 NO3 ? 3 MeOH ? CH3CN ( 2 ), [Ni2Dy(LH3)4] ? 3 NO3 ? 3 MeOH ? H2O ? CH3CN ( 3 ), and [Ni2Ho(LH3)4] ? 3 NO3 ? 3 MeOH ? H2O ? CH3CN ( 4 ). Complexes 1 – 4 possess linear trimetallic cores with a central lanthanide ion. Magnetic studies revealed a predominant ferromagnetic interaction between the Ni and Ln centers. Alternating current susceptibility measurements of complex 3 showed a small frequency dependence of the out‐of‐phase signal, χ′′M , under zero direct current field, but without achieving a net maximum above 2 K. Magnetic studies on 1 revealed that it has a significant magnetocaloric effect. 相似文献
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Banerjee Sangeeta Kundu Atreyee Dhak Prasanta 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(6):2409-2435
Journal of Radioanalytical and Nuclear Chemistry - Several treatments for the removal of toxic heavy metals like uranium from wastewater have been developed, but none of them are sufficiently... 相似文献
34.
Kundu Sumana Kraytsberg Alexander Ein-Eli Yair 《Journal of Solid State Electrochemistry》2022,26(9):1809-1838
Journal of Solid State Electrochemistry - Many elements in the periodic table form ionic compounds; the crystal lattices of such compounds contain cations and anions, which are arranged in the way... 相似文献
35.
Conformational Control of Oligo(p‐phenyleneethynylene)s with Intrinsic Substituent Electronic Effects: Origin of the Twist in Pentiptycene‐Containing Systems
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Che‐Jen Lin Dr. Sandip Kumar Kundu Dr. Cheng‐Kai Lin Prof. Jye‐Shane Yang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(45):14826-14833
Dependence of the backbone planarity of oligo(p‐phenyleneethynylene)s (OPEs) on the intrinsic electronic character of substituents and on the nature of the solvent has been experimentally demonstrated with a series of center‐symmetrical five‐ring systems, pentiptycene‐pentiptycene‐arene‐pentiptycene‐pentiptycene, differing in the substituents on the central arene. In frozen 2‐methyltetrahydrofuran (MTHF), the adjacent pentiptycene units prefer to be in a mutually twisted orientation when the substituents are electron‐withdrawing (F and amido), resulting in a TPPT or TTTT conformation, whereas a planarized PPPP backbone is favored in the case of electron‐donating substituents (alkyl and alkoxy). The propensity to adopt the PPPP form is generally enhanced by replacing MTHF with either methylcyclohexane or mixed ethanol/methanol as solvent. These observations reveal that the twist between adjacent pentiptycene units in OPEs is a consequence of the electronic rather than steric effects of iptycenyl substituents. The electronic effect of iptycenyl substituents is manifested in decreased phenylene π polarizability as the net effect of both electron‐donating hyperconjugation and an electron‐withdrawing inductive effect. Variable‐temperature electronic absorption and emission spectroscopies are the critical tools for this work. Our findings provide important guidelines for conformational and electronic engineering of OPEs and for the design of novel iptycene‐based organic electronic materials. 相似文献
36.
Amongst various carbon sources, xylan was found to be the sole inducer of endoxylanase production by Penicillium janthinellum MTCC 10889 in submerged cultivation. Endoxylanase synthesis by a xylan induced culture was initially repressed after a simultaneous addition of xylose, probably by the inducer exclusion mechanism, but it was resumed and achieved its highest level at a much later stage of growth (at 120 h). Xylose added after 30 h of growth cannot exert its full repressive effect. Although glucose was proved to be a more potent repressor than xylose, supplementation of salicin, an alcoholic β-glycoside containing d-glucose, with pure xylan resulted in an about 3.22 fold increase in the enzyme synthesis at 72 h followed by constant high production of the enzyme at least until the 144th h of growth. Inducing capacity of salicin in a xylan induced culture was significantly reduced when it was added after 30 h of growth. Addition of salicin and xylan help to partially overcome the repressive effect of xylose and glucose. Failure of salicin in recovering the endoxylanase synthesis in actinomycin D and cyclohexamide inhibited the xylan induced culture indicating that salicin cannot initiate the de novo synthesis of the enzyme. 相似文献
37.
Soujan Ghosh Swati Chowdhury Subrata Kundu Sudipta Sasmal Dimitrios Z. Politis Stelios M. Potirakis Masashi Hayakawa Suman Chakraborty Sandip K. Chakrabarti 《Entropy (Basel, Switzerland)》2022,24(1)
We focus on the possible thermal channel of the well-known Lithosphere–Atmosphere–Ionosphere Coupling (LAIC) mechanism to identify the behavior of thermal anomalies during and prior to strong seismic events. For this, we investigate the variation of Surface Latent Heat Flux (SLHF) as resulting from satellite observables. We demonstrate a spatio-temporal variation in the SLHF before and after a set of strong seismic events occurred in Kathmandu, Nepal, and Kumamoto, Japan, having magnitudes of 7.8, 7.3, and 7.0, respectively. Before the studied earthquake cases, significant enhancements in the SLHF were identified near the epicenters. Additionally, in order to check whether critical dynamics, as the signature of a complex phenomenon such as earthquake preparation, are reflected in the SLHF data, we performed a criticality analysis using the natural time analysis method. The approach to criticality was detected within one week before each mainshock. 相似文献
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39.
A cellulose derivative/liquid crystal composite‐type electro‐optical cell using a commercial cholesteric liquid crystal (CLC) was investigated. The electro‐optical properties of the system were examined, i.e. the dependence on applied voltage of the reflected wavelength and the minimum and maximum transmissions. A thin film of the CLC was dispersed with a cross‐linked cellulose film of 25 µm thickness. In the voltage dependence of the reflected wavelength it was verified that there is a hysteresis in the reflected wavelength. The variation of the reflected wavelength with temperature was also determined. The results are analysed in the framework of similar systems described in the literature for CLC dispersed in a polymer matrix. 相似文献
40.
Pintu K. Kundu 《Tetrahedron》2010,66(44):8562-8568
The β-aryl-β-silyl and β,β-disilyl propionates have been synthesized from cinnamates and β-silyl acrylates by a regiospecific reductive C-silylation using Mg/silyl chloride/DMF system at room temperature. These reductive C-silylation conditions have also been applied to δ-aryl substituted dienoates wherein silylation took place at the δ-position leading to the synthesis of single regioisomeric allylsilanes with very high stereoselectivity. 相似文献