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131.
Biosorption of Chromium(III) by Biomass of Seaweed Sargassum sp. in a Fixed-Bed Column 总被引:2,自引:0,他引:2
Eneida Sala Cossich Edson Antonio da Silva Célia Regina Granhen Tavares Lúcio Cardozo Filho Teresa Massako Kakuta Ravagnani 《Adsorption》2004,10(2):129-138
This work aimed at modeling chromium biosorption using the biomass of seaweed Sargassum sp. in a fixed-bed column. The mathematical model used was obtained from the mass balance of the component in the liquid phase and in the biosorbent material. The effects of both axial dispersion in the column and the resistance to mass transfer in the solid were considered for the solution of the partial differential equations of the model, using the Galerkin method on finite elements. To represent the equilibrium data of the batch system the Langmuir isotherm were used. The chromium ion adsorption capacity of the seaweed Sargassum sp., at a temperature of 30°C and pH 3.5, was 2.61 mmol/g. The model performance was evaluated from experimental data obtained at 30°C for flow rates of 2, 6 and 8 mL/min. The parameters of the model, mass transfer and axial dispersion coefficients, were adjusted from these experimental data. The model proved adequate to describe chromium biosorption dynamics in fixed-bed columns. 相似文献
132.
Compared with linear polymers, more factors may affect the glass‐transition temperature (Tg) of a hyperbranched structure, for instance, the contents of end groups, the chemical properties of end groups, branching junctions, and the compactness of a hyperbranched structure. Tg's decrease with increasing content of end‐group free volumes, whereas they increase with increasing polarity of end groups, junction density, or compactness of a hyperbranched structure. However, end‐group free volumes are often a prevailing factor according to the literature. In this work, chain‐end, free‐volume theory was extended for predicting the relations of Tg to conversion (X) and molecular weight (M) in hyperbranched polymers obtained through one‐pot approaches of either polycondensation or self‐condensing vinyl polymerization. The theoretical relations of polymerization degrees to monomer conversions in developing processes of hyperbranched structures reported in the literature were applied in the extended model, and some interesting results were obtained. Tg's of hyperbranched polymers showed a nonlinear relation to reciprocal molecular weight, which differed from the linear relation observed in linear polymers. Tg values decreased with increasing molecular weight in the low‐molecular‐weight range; however, they increased with increasing molecular weight in the high‐molecular‐weight range. Tg values decreased with increasing log M and then turned to a constant value in the high‐molecular‐weight range. The plot of Tg versus 1/M or log M for hyperbranched polymers may exhibit intersecting straight‐line behaviors. The intersection or transition does not result from entanglements that account for such intersections in linear polymers but from a nonlinear feature in hyperbranched polymers according to chain‐end, free‐volume theory. However, the conclusions obtained in this work cannot be extended to dendrimers because after the third generation, the end‐group extents of a dendrimer decrease with molecular weight. Thus, it is very possible for a dendrimer that Tg increases with 1/M before the third generation; however, it decreases with 1/M after the third generation. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1235–1242, 2004 相似文献
133.
Jérôme Gualbert Patrick Shahgaldian Adina Lazar Anthony W. Coleman 《Journal of inclusion phenomena and macrocyclic chemistry》2004,48(1-2):37-44
Solid Lipid Nanoparticles (SLNs) have been prepared fromc-2,c-8,c-14,c-20-tetraundecyl-4,6,10,12,16,18,22,24-octahydroxyresorc[4]areneas colloidal suspensions. Photon Correlation Spectroscopy studies revealed aparticle hydrodynamic diameter of 150 nm. Non-contact mode Atomic ForceMicroscopy allows observation of the particles as slightly flattened sphericalobjects of 236 (±40) nm diameter and 145 (±40) nm height. Thestudy of the preparation parameters showed that shear force does not affectthe hydrodynamic size of the SLNs. In contrast, the viscosity and the pH ofthe aqueous phase, the amphiphile concentration in the organic phase and thevolume of organic phase used, all lead to variation in the size of the particles.In term of post preparation parameters only the ionic strength has been shownto affect significantly the particle size; while the pH of the storing solution,microwave, ultrasonic and thermal treatments do not. Short and long-termstability studies have been performed to measure the effect of the ionic strengthon the stability of the particles. The use of carbohydrate cryoprotectants does notallow re-dispersion of the colloidal suspension after freeze-drying. 相似文献
134.
135.
The exponential functional of simple, symmetric random walks with negative
drift is an infinite polynomial Y = 1 + ξ1 + ξ1ξ2 + ξ1ξ2ξ3 + ⋯ of independent
and identically distributed non-negative random variables. It has moments that are
rational functions of the variables μ
k
= E(ξ
k
) < 1 with universal coefficients. It
turns out that such a coefficient is equal to the number of permutations with descent
set defined by the multiindex of the coefficient. A recursion enumerates all numbers
of permutations with given descent sets in the form of a Pascal-type triangle.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
136.
Paramagnetic pyrroline and 1,2,3,6-tetrahydropyridine derivatives of BODIPY and their diamagnetic analogs have been synthesized and characterized as novel redox double sensor and cation sensitive reagents. 相似文献
137.
Parabolic Capacity and Soft Measures for Nonlinear Equations 总被引:2,自引:0,他引:2
We first introduce, using a functional approach, the notion of capacity related to the parabolic p-Laplace operator. Then we prove a decomposition theorem for measures (in space and time) that do not charge the sets of null capacity. We apply this result to prove existence and uniqueness of renormalized solutions for nonlinear parabolic initial boundary-value problems with such measures as right-hand side. 相似文献
138.
139.
Kinetic selection principles have been shown to be useful and physically reasonable in nonlinear hyperbolic problems with
large amplitude phase transitions. We refer to Abeyaratne and Knowles, [A-K], for discussion on the subject. They also have
been used for degenerate nonlinear problems, where the genuine nonlinearity property of Lax is violated. This is the framework
of Liu, [Li], in the kinetic situation of Hayes and Le Floch, [H-L], where their so-called non classical shocks may be seen
as small amplitude phase transitions. Here, we describe the local geometry generated by the generic non genuinely nonlinear
assumption. A geometric kinetic criterion can be used to select indeterminate simple waves and obtain the well-posedness of
the local Riemann problem. A particular case is the entropic kinetic criterion of Hayes and Le Floch.
Sunto Principi di selezione cinetica sono stati mostrati utili e fisicamente ragionevoli in problemi iperbolici con transizioni di fase di grande ampiezza. Ci riferiamo ad Abeyaratne e Knowles, [A-K], per discussioni sull'argomento. Detti principi sono stati usati per problemi nonlineari degeneri, dove la proprietà di genuina nonlinearità di Lax è violata. Questo è la prospettiva di Liu, [Li], nella situazione cinetica di Hayes e Le Floch, [H-L], dove i loro così detti urti non classici possono essere considerati come transizioni di fase di piccola ampiezza. Qui, descriviamo la geometria locale generata dall'ipotesi generica genuinamente nonlineare. Un criterio di geometria cinetica può essere usato per selezionare onde semplici indeterminate ed ottenere la buona posizione per il problema locale di Riemann. Un caso particolare è il criterio di entropia cinetico di Hayes e Le Floc.相似文献
140.
The function lattice, or generalized Boolean algebra, is the set of ℓ-tuples with the ith coordinate an integer between 0 and a bound ni. Two ℓ-tuples t-intersect if they have at least t common nonzero coordinates. We prove a Hilton–Milner type theorem for systems of t-intersecting ℓ-tuples.Received September 29, 2004 相似文献