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41.
This research was done while the last two authors were visitors at the University of Mainz. They are grateful to the Department of Mathematics for its excellent hospitality. 相似文献
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43.
Allodi MA Dunn ME Livada J Kirschner KN Shields GC 《The journal of physical chemistry. A》2006,110(49):13283-13289
It has been speculated that the presence of OH(H2O)n clusters in the troposphere could have significant effects on the solar absorption balance and the reactivity of the hydroxyl radical. We have used the G3 and G3B3 model chemistries to model the structures and predict the frequencies of hydroxyl radical/water clusters containing one to five water molecules. The reaction between hydroxyl radical clusters and methane was examined as a function of water cluster size to gain an understanding of how cluster size affects the hydroxyl radical reactivity. 相似文献
44.
Highly selective enzymatic reductions of aldehydes to the corresponding alcohols was performed using an E. coli JM109 whole cell biocatalyst. A selective enzymatic method for the reduction of aldehydes could provide an eco-compatible alternative to chemical methods. The simplicity, fairly wide scope and the very high observed chemoselectivity of this approach are its most unique features. 相似文献
45.
Gervásio A. Degrazia Otávio C. Acevedo Silvana Maldaner Umberto Rizza 《Physica A》2010,389(24):5808-5813
The classical statistical diffusion theory and the binomial autocorrelation function are used to obtain a new formulation for the turbulence dissipation rate ε. The approach employs the Maclaurin series expansion of a logarithm function contained in the dispersion parameter formulation. The numerical coefficient of this new relation for ε is 100% larger than the numerical coefficient of the classical relation derived from the exponential autocorrelation function. A similar approach shows that the dispersion parameter obtained from the even exponential autocorrelation function does not result in a relation for ε and, therefore, is not suitable for application in dispersion models. In addition, a statistical comparison to experimental ground-level concentration data demonstrates that this newly derived relation for ε as well as other formulations for the turbulence dissipation rate are suitable for application in Lagrangian stochastic dispersion models. Therefore, the analysis shows that there is an uncertainty regarding the turbulence dissipation rate function form and the autocorrelation function form. 相似文献
46.
The IR spectra have been recorded in the solid state for the parent molecule, 6-(N-pyrrolyl)purine (1) and its N-9-and N-7-substituted derivatives: 9-and 7-(2-hydroxyprop-1-yl)-6-(N-pyrrol-1-yl)purine (2 and 3), 9-and 7-(2-acetoxyprop-1-yl)-6-(N-pyrrol-1-yl)purine (4 and 5), 9-and 7-(2,3-dihydroxyprop-1-yl)-6-(N-pyrrol-1-yl)purine (6 and 7) as well as 9-and 7-(2,3-diacetoxyprop-1-yl)-6-(N-pyrrol-1-yl)purine (8 and 9). Analysis of the characteristic bands has proved to be useful in differentiating between N-9 and N-7 regioisomers. 相似文献
47.
Let K be a field of characteristic p > 0, let L be a restricted Lie algebra and let R be an associative K-algebra. It is shown that the various constructions in the literature of crossed product of R with u(L) are equivalent. We calculate explicit formulae relating the parameters involved and obtain a formula which hints at a noncommutative version of the Bell polynomials. 相似文献
48.
Molina FD Bertollo EM Assis CM Falleiros LR Campos SG Maniglia JV Taboga SR 《Micron (Oxford, England : 1993)》2008,39(7):910-914
Squamous cell carcinoma of the tongue is one of the most common head and neck cancer. Treatment in the early stages is still controversial. This study aims to correlate the apoptosis rate of primary tongue cancer with cervical node metastasis, found in the histopathological studies of specimens obtained from neck dissections or during clinical follow-up. Twenty patients, 65% males, mean age 64.5 years, without clinical evidence of cervical metastasis was included. Eighty-five percent were smokers and 40% were alcohol abusers. Mann-Whitney test was used for statistical analysis (p=0.05). Five patients with clinically occult cervical metastases had metastasis in the histopathological specimens (25%) occult metastasis. The mean apoptosis rate in patients without cervical metastasis was 9.43%. Twenty-five percent of the patients had occult cervical metastasis. High apoptosis rate in tongue cancer, even in the absence of palpable neck nodes, correlates with the presence of occult metastasis. 相似文献
49.
We consider the problem of sending a message from a sender to a receiver through an unreliable network by specifying in a protocol what each vertex is supposed to do if it receives the message from one of its neighbors. A protocol for routing a message in such a graph is finite if it never floods with an infinite number of copies of the message. The expected reliability of a given protocol is the probability that a message sent from reaches when the edges of the network fail independently with probability .We discuss, for given networks, the properties of finite protocols with maximum expected reliability in the case when is close to 0 or 1, and we describe networks for which no one protocol is optimal for all values of . In general, finding an optimal protocol for a given network and fixed probability is challenging and many open problems remain. 相似文献
50.