Online-Analysis on Acoustically Levitated Droplets

Summary: Aqueous solutions of acrylic acid were levitated in a 40 kHz acoustic levitator. The monomer amount in the levitated droplets was monitored by Raman spectroscopy relating to an internal standard. Thus evaporation of the monomer as well as polymerization reactions initiated by a redox system were investigated by Raman spectroscopy and resultant data were compared to HPLC data. Decreases in monomer amount due to evaporation can be clearly distinguished from polymerization reactions. Additionally, temperature measurement within the droplet throughout a polymerization reaction shows the typical temperature course originating from the heat of polymerization.     

New Poly(arylene ethynylene)s Consisting of Electron‐Deficient Aryleneimide Units

Summary: A new class of poly(arylene ethynylene)s (PAEs) containing an electron‐deficient N‐alkylphthalimide unit was prepared by means of a Sonogashira reaction. Complete solubility of the PAEs was observed by utilizing a 2,6‐diisopropylphenyl side chain. The chemical structure of the novel soluble polymer 3c was confirmed by NMR spectra, whereas the insoluble polymers were characterized by elemental analysis and IR spectra. Fluorescence measurements of 3c indicate a rigid structure and high symmetry in the excited state.

     

Implication for Lie group symmetries for RANS modeling

Since the symmetries of fluid motion are admitted by all statistical quantities of turbulent flows as can be taken from the multipoint equations, we can derive conditions for turbulence models so that they capture the proper flow physics. Concerning these constraints we will exemplary investigate the k – ϵ – model for its capability to reproduce new scaling laws derived from symmetry methods. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Separation of Dihydro-Isocoumarins and Dihydro-Stilbenoids from Hydrangea macrophylla ssp. serrata by Use of Counter-Current Chromatography

Previously, different Hydrangea macrophylla ssp. serrata cultivars were investigated by untargeted LC-MS analysis. From this, a list of tentatively identified and unknown compounds that differ significantly between these cultivars was obtained. Due to the lack of reference compounds, especially for dihydro-isocoumarins, we aimed to isolate and structurally characterise these compounds from the cultivar ‘Yae-no-amacha’ using NMR and LC-MS methods. For purification and isolation, counter-current chromatography was used in combination with reversed-phase preparative HPLC as an orthogonal and enhanced purification workflow. Thirteen dihydro-isocoumarins in combination with other metabolites could be isolated and structurally identified. Particularly interesting was the clarification of dihydrostilbenoid glycosides, which were described for the first time in H. macrophylla ssp. serrata. These results will help us in further studies on the biological interpretation of our data.     

Rado Numbers fora(x+y)=bz

In the case of existence the smallest numberN=Ra_kis called a Rado number if it is guaranteed that anyk-coloring of the numbers 1, 2, …, Ncontains a monochromatic solution of a given system of linear equations. We will determine Ra_k(a, b) for the equationa(x+y)=bzifb=2 andb=a+1. Also, the case of monochromatic sequences {x_n} generated bya(x_n+x_n+1)=bx_n+2 is discussed.     

Band-mapping of InP (100) along the ΓX-line

We have prepared InP (100) surfaces from wafer-material by cycles of argon ion sputtering and gentle annealing. From these samples normal-emission photoelectron spectra were recorded using photons in the energy range 10eV<h<75eV. From the results we derive the initial-state band disperison along the X-line of the 3-dimensional Brillouin zone. Our results are fully consistent with initial-state bands mapped by other authors along the KX-line. From the good agreement we conclude that the quality of the (100)-surfaces as used in our work is at least adequate for bulk band investigations.     

High Electromagnetic Field Enhancement of TiO2 Nanotube Electrodes

We present the fabrication of TiO₂ nanotube electrodes with high biocompatibility and extraordinary spectroscopic properties. Intense surface‐enhanced resonance Raman signals of the heme unit of the redox enzyme Cytochrome b₅ were observed upon covalent immobilization of the protein matrix on the TiO₂ surface, revealing overall preserved structural integrity and redox behavior. The enhancement factor could be rationally controlled by varying the electrode annealing temperature, reaching a record maximum value of over 70 at 475 °C. For the first time, such high values are reported for non‐directly surface‐interacting probes, for which the involvement of charge‐transfer processes in signal amplification can be excluded. The origin of the surface enhancement is exclusively attributed to enhanced localized electric fields resulting from the specific optical properties of the nanotubular geometry of the electrode.     

Structure of star-burst dendrimers: a comparison between small angle x-ray scattering and computer simulation results

We investigated the generation dependent shape and internal structure of star-burst dendrimers under good solvent conditions using small angle x-ray scattering and molecular modeling. Measurements have been performed on poly(amidoamine) dendrimers with generations ranging from g=0 up to g=8 at low concentrations in methanol. We described the static form factor P(q) by a model taking into account the compact, globular shape as well as the loose, polymeric character of dendrimers. Monomer distributions within dendrimers are of special interest for potential applications and have been characterized by the pair correlation function gamma(r), as well as by the monomer and end-group density profile, rho(r) and rho(e)(r), respectively. Monomer density profiles and gamma(r) can be derived from P(q) by modeling and via a model independent approach using the inverse Fourier transformation algorithm first introduced by Glatter. Experimental results are compared with computer simulations performed for single dendrimers of various generations using the cooperative motion algorithm. The simulation gives direct access to gamma(r) and rho(r), allows an independent determination of P(q), and yields in addition to the scattering experiment information about the distribution of the end groups. Excellent qualitative agreement between experiment and simulation has been found.