Deposition of copper oxide (Cu2O,CuO) thin films at high temperatures by plasma-enhanced CVD

Copper-oxide films are deposited by plasma-enhanced CVD using copper acetylacetonate as a precursor. The influence of various experimental parameters on deposition rate, film composition and resistivity have been studied. The substrate temperature and the bias are the parameters which affect these properties the most. An increase of the substrate temperature changes the phases of the deposit from Cu₂O-CuO over Cu₂O to Cu. At temperatures 500° C the deposition rates are high but the films consist mainly of metallic Cu. A negative bias enhances the deposition rate only slightly but has a strong effect on the film composition and can completely balance the oxygen deficiency. At a bias of –120 V the films consist of pure CuO even at temperatures 500° C.     

Projections of Gibbs measures may be non-Gibbsian

Consider the + phase of the two dimensional nearest neighbor ferromagnetic Ising model at a temperature belowT _c . Let ₊ be the restriction of this measure to a coordinate axis. We prove that there is no one dimensional translation invariant summable interaction for which ₊ is a Gibbs measure. This is proven by showing that if such an interaction existed, ₊ would have large deviation properties different from those it actually has. Percolation methods are used in the proof.Work supported by the U.S. Army Research Office through the Mathematical Sciences Institute at Cornell and by a NSF grant to Cornell. This work was finished while the author was visiting Rutgers University, being supported by the NSF grant 86-12369     

Preparation of papers

General Information

Preparation of papers     

The evaluation of Cauchy principal value integrals involving unknown poles

A method is described for the evaluation of a Cauchy principal value integral of the formf ₀ ^p f(t)dt, wheref is analytic in the interval [0,p] except at a simple pole at an unknown point in (0,p), with an unknown residue. The method is based on the trapezoidal rule.     

Algorithms for non-linear huber estimation

The Huber criterion for data fitting is a combination of thel ₁ and thel ₂ criteria which is robust in the sense that the influence of wild data points can be reduced. We present a trust region and a Marquardt algorithm for Huber estimation in the case where the functions used in the fit are non-linear. It is demonstrated that the algorithms converge under the usual conditions.     

Continued fractions associated with the Newton-Padé table

Summary We discuss first the block structure of the Newton-Padé table (or, rational interpolation table) corresponding to the double sequence of rational interpolants for the data{(z _k, h(z_k)} _k =0. (The (m, n)-entry of this table is the rational function of type (m,n) solving the linearized rational interpolation problem on the firstm+n+1 data.) We then construct continued fractions that are associated with either a diagonal or two adjacent diagonals of this Newton-Padé table in such a way that the convergents of the continued fractions are equal to the distinct entries on this diagonal or this pair of diagonals, respectively. The resulting continued fractions are generalizations of Thiele fractions and of Magnus'sP-fractions. A discussion of an some new results on related algorithms of Werner and Graves-Morris and Hopkins are also given.Dedicated to the memory of Helmut Werner (1931–1985)     

Hot electron transport in semiconductors

A recently derived model for stationary flow of energy and charge carriers in semiconductors—consisting of a coupled system of nonlinear elliptic equations—is analysed by the methods of singular perturbation theory. This analysis reveals the solution structure and justifies a modified version of the standard drift-diffusion approximation for charge carrier flow.

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Zusammenfassung Ein kürzlich hergeleitetes Modell für stationären Energie- und Ladungsträgerfluß in Halbleitern—bestehend aus einem gekoppelten System von nichtlinearen elliptischen Gleichungen—wird mit Methoden der singulären Störungstheorie analysiert. Daraus ergeben sich Aussagen über die Lösungsstruktur und eine Rechtfertigung einer modifizierten Version der klassischen Konvektions-Diffusions-Approximation für den Ladungsträgerfluß.

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The work of the second author was supported by Österreichischer Fonds zur Förderung der wissenschaftlichen Forschung.     

Circles through two points that always enclose many points

This paper proves that any set of n points in the plane contains two points such that any circle through those two points encloses at least points of the set. The main ingredients used in the proof of this result are edge counting formulas for k-order Voronoi diagrams and a lower bound on the minimum number of semispaces of size at most k.Work on this paper by the first author has been supported by Amoco Fnd. Fac. Dev. Comput. Sci. 1-6-44862 and by the National Science Foundation under Grant CCR-8714565, by the second author has been partially supported by the Digital Equipment Corporation, by the fourth author has been partially supported by the Office of Naval Research under Grant N00014-86K-0416.     

Algorithms for flows with parametric capacities

We consider the problem of finding maximal flows with respect to capacities which are linear functions of a parametert [0,T]. Since this problem is a special case of a parametric linear program the classichorizontal approach can be applied in which optimal solutions are computed for successive subintervals of [0,T]. We discuss an alternative algorithm which approximates in each iteration the optimal solution for allt [0,T]. Thisvertical algorithm is a labeling type algorithm where the flow variables are piecewise linear functions. Flow augmentations are done alongconditional flow augmenting paths which can be found by modified path algorithms. The vertical algorithm can be used to solve the parametric flow problem optimally as well as to compute a good approximation for allt if the computation of the optimal solution turns out to be too time consuming.Partially supported by NSF Grants ECS-8412926 and INT-8521433, and NATO Grant RG 85/0240.     

Disorder arising from the location of enantiomers in a twist-boat structure: 2,6-trans-2,4,6-tris(trichloromethyl)-1-oxa-3,5-dithian

Crystals of the title compound are orthorhombic, Pca2₁;a=27.586(4),b=10.509(3),c=11.080(2) Å,V=3212(1) ų,Z=8. The structure was solved by direct methods, from data collected at room temperature on an Enraf-Nonius CAD4 diffractometer, and refined by full-matrix least squares to a finalR value of 0.055 using 2043 reflections. One of the two independent molecules in the asymmetric unit is disordered. The disorder is manifested mainly between the oxygen atom and one sulfur atom and is caused by opposite enantiomers occupying corresponding positions in different unit cells. The endocyclic torsion angles in both independent molecules are very similar but the disposition of the heteroatoms on the twist-boat framework is different in the two molecules. Site occupancy of the two models on this framework in the disordered molecule is in the ratio 2179 with the smaller proportion being very similar to the ordered molecule and the remainder similar to that found in the normal molecule oftrans-4-chloro-2,4,6-tris(trichloromethyl)-1-oxa-3,5-dithian (Irving and Irving, 1988).