High-performance liquid chromatographic determination of histamine N-methyltransferase activity

A method for the determination of histamine N-methyltransferase (HMT) activity by high-performance liquid chromatography based on post-column derivatization with omicron-phthalaldehyde is described. The determination involves the separation of the substrate, histamine, from its product. N tau-methylhistamine, using a weak cation exchanger, followed by on-line derivatization of these imidazoleamines with omicron-phthalaldehyde and their detection and quantitation with a fluorimetric detector. This assay method is suitable for the measurement of HMT activity during enzyme purification.     

A regioselective ω-epoxidation of polyisoprenoids by the sodium bromide promoted electrochemical oxidation

A regioselective ω-epoxidation of polyisoprenoids has been realized by the sodium bromide promoted electrochemical oxidation in a mixed solvent (MeCN-THF-H₂O).     

Preliminary test estimation for spectra

For a general non-Gaussian stationary linear process, quasi-maximum likelihood estimation of a subset of the parameters of the spectral density is considered when the complementary subset is suspected to be superfluous. A preliminary test quasi-maximum likelihood estimator (q-MLE) of parameters is introduced and, in the light of its mean square error, is compared with the restricted and unrestricted q-MLE.     

A novel synthesis of dl-marmelolactone and dl-rose oxide by electrochemical oxyselenenylation-deselenenylation sequence

One-step transformation of olefins $\text{1}$ into allylic alcohols and ethers $\text{3}$ has been accomplished by electrooxidative oxyselenenylation-deselenenylation sequence. The electrochemical process furnished efficient syntheses of dl-marmelolactone $\text{4}$ and dl-rose oxide $\text{5}$.     

Eigenspace manipulation in SCF theory

The procedure proposed by Silverstone and others to modify virtual levels in SCF theory is extended as a technique to be used in any type of generalized secular equations. Some useful results are obtained.     

Photophysical and Photochemical Properties of Ru(bpy)3 2+ in Si-Ti Mixed Oxides Xerogels Prepared by the Sol-Gel Process

The luminescence spectra and lifetime of tris(2,2-bipyridine)ruthenium(II), Ru(bpy)₃ ²⁺, were studied in sol-gel reaction systems of tetramethoxysilane (TMOS) and titanium(IV) isopropoxide (TTIP) with HCl. Luminescence lifetime in the TMOS system increased as the sol-gel reaction proceeded, because diffusion-controlled luminescence quenching such as oxygen and collisional quenching with solvent molecules were suppressed in the rigid matrices. On the other hand, luminescence lifetime in the TTIP system decreased during the sol-gel reaction. The decrease in lifetime was ascribed to electron transfer from photoexcited Ru(bpy)₃ ²⁺ to the conduction band of the TiO₂ xerogels. Extended X-ray absorption fine structure (EXAFS) measurements were done to associate lifetime in the Si-Ti xerogels with the structures of Ti⁴⁺ sites in the xerogels.     

A systematic preparation of new contracted Gaussian-type orbital sets. VI. Ab initio calculation on molecules containing Na through Cl

Compact contracted Gaussian basis sets introduced in the preceding article are tested for ab initio molecular calculations on molecules containing third-row atoms (Na through Cl). It is found that the effect of splitting valence orbitals is essential for these molecules and addition of polarization functions to split basis sets can yield computed geometries, spectroscopic constants, and atomization energies in close agreement with the result of near Hartree–Fock calculations.