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31.
R. Menges U. Dinger N. Boos G. Huber S. Schröder S. Dutta R. Kirchner O. Klepper T. Kühl D. Marx G. D. Sprouse 《Zeitschrift für Physik A Hadrons and Nuclei》1992,341(4):475-479
The hyperfine structure, isotope and isomeric shifts in the atomic transition 6p
2
P
3/2–7s
2
S
1/2, =535 nm have been measured for theI=7 andI=2 states of190, 192, 194, 196Tl; theI=1/2 andI=9/2 states of191Tl and the I=7 isomer of188Tl. The thallium isotopes were prepared as fast atomic beams at the GSI on-line mass separator following fusion reactions and — in some cases — subsequent-decay. The nuclear dipole moments, electric quadrupole moments and the change in the nuclear mean square charge radius are evaluated. Theuu-isotopes show an isomeric shift which changes sign between192Tl and194Tl.Dedicated to P. Armbruster on the occasion of his 60th birthday 相似文献
32.
Lee CM Hsieh CH Dutta A Lee GH Liaw WF 《Journal of the American Chemical Society》2003,125(38):11492-11493
Iron-nitrosyl complex containing S-bonded monosulfinate [PPN][(NO)Fe(S,SO2-C6H4)(S,S-C6H4)] (3) has been isolated from sulfur oxygenation of complex [PPN][(NO)Fe(S,S-C6H4)2] (2) which is obtained from addition of NO molecule to [PPN][(C4H8O)Fe(S,S-C6H4)2] (1) in organic solvents. This result reveals that binding of NO to the iron center promotes sulfur oxygenation of iron dithiolates by dioxygen and stabilizes the S-bonded sulfinate iron species. Analysis of the bond angles for complexes 2 and 3 reveals that iron is best described as existing in a distorted trigonal bipyramidal coordination environment surrounded by one NO, three thiolates, and one sulfinate in complex 3, whereas the distorted square pyramidal geometry is adopted in complex 2. Complex 3 further reacts in organic solvents with molecular oxygen in the presence of [PPN][NO2] to produce the dinuclear bis(sulfinate) complex [PPN]2[(NO)Fe(SO2,SO2-C6H4)(S,S-C6H4)]2 (4). Complex 3 showed reaction with PPh3 in THF/CH2Cl2 to yield complex 2 and Ph3PO. Upon photolysis of CH2Cl2 solution of complex 3 under N2 purge at ambient temperature, the UV-vis and IR spectra consistent with the formation of complex 2 demonstrate that complex 2 and 3 are photochemically interconvertible. Obviously, complex 3 is thermally quite stable but is photochemically active toward [O] release. Also described are the X-ray crystal structures of 3 and 4. 相似文献
33.
ZnO nanoparticles were synthesized by the continuous spray pyrolysis technique (CoSP) and the effect of applied voltage across the spray nozzle and an annular ground electrode during spray has been studied. X-ray diffraction and transmission electron microscopy studies showed that the product has (hexagonal) wurtzite structure with the average particle size decreasing from 18.5?nm to 12.9?nm in the presence of a high DC voltage (1?kV). The higher value of the absorption peak for the nanoparticles synthesized without voltage is supportive of this behavior. The films deposited by spin coating using these nanoparticles can be used for a variety of applications, particularly as photoelectrodes for dye-sensitized solar cells. 相似文献
34.
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36.
When states of the world are normally distributed, the sequential exchange and revision of beliefs converges to agreement in finitely many rounds of communication. Public information may reduce the information shared by individuals after the revision of beliefs. 相似文献
37.
Sandip Dutta Ritabrata Biswas 《The European Physical Journal C - Particles and Fields》2017,77(10):717
This paper deals with the viscous accretion flow of a modified Chaplygin gas towards a black hole as the central gravitating object. A modified Chaplygin gas is a particular type of dark energy model which mimics of radiation era to phantom era depending on the different values of its parameters. We compare the dark energy accretion with the flow of adiabatic gas. An accretion disc flowing around a black hole is an example of a transonic flow. To construct the model, we consider three components of the Navier–Stokes equation, the equation of continuity and the modified Chaplygin gas equation of state. As a transonic flow passes through the sonic point, the velocity gradient being apparently singular there, it gives rise to two flow branches: one in-falling, the accretion and the other outgoing, the wind. We show that the wind curve is stronger and the wind speed reaches that of light at a finite distance from the black hole when dark energy is considered. Besides, if we increase the viscosity, the accretion disc is shortened in radius. These two processes acting together make the system deviate much from the adiabatic accretion case. It shows a weakening process for the accretion procedure by the work of the viscous system influencing both the angular momentum transport and the repulsive force of the modified Chaplygin gas. 相似文献
38.
An expeditious synthesis of aryl substituted E‐homoallylic bromides has been accomplished by the cleavage of cyclopropylcarbinols with phosphorus tribromide. 相似文献
39.
Gakhyun Kim Dr. Ranjan Dutta Dr. Won-Young Cha Dr. Seong-Jin Hong Dr. Juwon Oh Dr. Dikhi Firmansyah Hongil Jo Prof. Dr. Kang Min Ok Prof. Dr. Chang-Hee Lee Prof. Dr. Dongho Kim 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(69):16434-16440
π–π Stacking is omnipresent not only in nature but in a wide variety of practical fields applied to our lives. Because of its importance in a performance of natural and artificial systems, such as light harvesting system and working layer in device, many researchers have put intensive effort into identifying its underlying nature. However, for the case of π–π stacked systems composed of antiaromatic units, the understanding of the fundamental mechanisms is still unclear. Herein, we synthesized a new type of planar β,β’-phenylene-bridged hexaphyrin (1.0.1.0.1.0), referred as naphthorosarin which possesses the 24π-electron conjugated pathway. Especially, the corresponding antiaromatic porphyrinoid shows the unique property to form dimeric species adopting the face-to-face geometry which is unprecedented in cases of known annulated naphthorosarins. In order to elucidate the intriguing properties derived from the stacked dimer, the current study focuses on the experimental support to rationalize the observed π–π interactions between the two subunits. 相似文献
40.
Dr. Siddhartha De Dr. Alexandrine Flambard Dr. Delphine Garnier Patrick Herson Dr. Frank H. Köhler Dr. Abhishake Mondal Dr. Karine Costuas Dr. Béatrice Gillon Prof. Rodrigue Lescouëzec Dr. Boris Le Guennic Dr. Frédéric Gendron 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(52):12120-12136
The local magnetic structure in the [FeIII(Tp)(CN)3]− building block was investigated by combining paramagnetic Nuclear Magnetic Resonance (pNMR) spectroscopy and polarized neutron diffraction (PND) with first-principle calculations. The use of the pNMR and PND experimental techniques revealed the extension of spin-density from the metal to the ligands, as well as the different spin mechanisms that take place in the cyanido ligands: Spin-polarization on the carbon atoms and spin-delocalization on the nitrogen atoms. The results of our combined density functional theory (DFT) and multireference calculations were found in good agreement with the PND results and the experimental NMR chemical shifts. Moreover, the ab-initio calculations allowed us to connect the experimental spin-density map characterized by PND and the suggested distribution of the spin-density on the ligands observed by NMR spectroscopy. Interestingly, significant differences were observed between the pseudo-contact contributions of the chemical shifts obtained by theoretical calculations and the values derived from NMR spectroscopy using a simple point-dipole model. These discrepancies underline the limitation of the point-dipole model and the need for more elaborate approaches to break down the experimental pNMR chemical shifts into contact and pseudo-contact contributions. 相似文献