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排序方式: 共有188条查询结果,搜索用时 31 毫秒
91.
Siddhartha Sahi 《Combinatorica》2008,28(2):209-227
We prove a correlation inequality for n increasing functions on a distributive lattice, which for n = 2 reduces to a special case of the FKG inequality. The key new idea is to reformulate the inequalities for all n into a single positivity statement in the ring of formal power series. We also conjecture that our results hold in greater
generality. 相似文献
92.
Synthesis of β‐enaminones from β‐dicarbonyl compounds has been achieved in high yields within a minute using primary and aromatic amines and catalytic amounts of iodine under solvent‐free conditions at room temperature. 相似文献
93.
Shyamaprosad Goswami Sibaprasad Maity Avijit Kumar Das Annada C. Maity Tarun Kanti Mandal Siddhartha Samanta 《Tetrahedron letters》2013
A new dibenzimidazolo diimine sensor (DDS) has been designed and synthesized for selective detection of acetate ion. Significant naked eye recognized color change of DDS solution from light yellow to pink upon addition of only acetate ion is accompanied with near infra red (NIR) emission exploiting excited state intramolecular proton transfer (ESIPT). 相似文献
94.
Siddhartha Sahi 《Journal of Theoretical Probability》2008,21(2):449-458
The FKG inequality asserts that for a distributive lattice with log-supermodular probability measure, any two increasing functions
are positively correlated. In this paper we extend this result to functions with values in partially ordered algebras, such
as algebras of matrices and polynomials.
This research was supported by an NSF grant. 相似文献
95.
We present a streamline diffusion shock capturing spacetime discontinuous Galerkin (DG) method to approximate nonlinear systems of conservation laws in several space dimensions. The degrees of freedom are in terms of the entropy variables and the numerical flux functions are the entropy stable finite volume fluxes. We show entropy stability of the (formally) arbitrarily high order accurate method for a general system of conservation laws. Furthermore, we prove that the approximate solutions converge to the entropy measure valued solutions for nonlinear systems of conservation laws. Convergence to entropy solutions for scalar conservation laws and for linear symmetrizable systems is also shown. Numerical experiments are presented to illustrate the robustness of the proposed schemes. 相似文献
96.
Ujjwal Koley Siddhartha Mishra Nils Henrik Risebro Magnus Svärd 《BIT Numerical Mathematics》2009,49(2):375-395
We describe high order accurate and stable finite difference schemes for the initial-boundary value problem associated with
the magnetic induction equations. These equations model the evolution of a magnetic field due to a given velocity field. The
finite difference schemes are based on Summation by Parts (SBP) operators for spatial derivatives and a Simultaneous Approximation
Term (SAT) technique for imposing boundary conditions. We present various numerical experiments that demonstrate both the
stability as well as high order of accuracy of the schemes.
相似文献
97.
A new azido derivative of a NNO donor tridentate Schiff-base copper(II) complex, [CuL(μ1,1-N3)]n (1) (HL = 1-(N-ortho-hydroxyacetophenimine)-2-(N-ethyl)aminoethane), containing a single end-on μ1,1-azido bridged 1D infinite chain has been synthesized and characterized. X-ray single crystal structure analysis reveals that the complex [CuL(μ1,1-N3)]n (1) is a 1D chain in which neighboring Cu(II) chromophores are related by glide planes and linked by single azido bridges in the EO mode. No measurable magnetic interaction was evidenced in the complex [CuL(μ1,1-N3)]n (1) through variable temperature magnetic susceptibility measurements (10–300 K). The complex was used as an active catalyst for the epoxidation of cyclooctene using tert-butyl-hydroperoxide as an oxidant. The catalytic activity of the complex has been compared in a series of solvents. The results show that in acetonitrile medium, the epoxide was produced in high yield with high selectivity. 相似文献
98.
Ulrik S. Fjordholm Siddhartha Mishra Eitan Tadmor 《Foundations of Computational Mathematics》2013,13(2):139-159
We prove that the ENO reconstruction and ENO interpolation procedures are stable in the sense that the jump of the reconstructed ENO point values at each cell interface has the same sign as the jump of the underlying cell averages across that interface. Moreover, we prove that the size of these jumps after reconstruction relative to the jump of the underlying cell averages is bounded. Similar sign properties and the boundedness of the jumps hold for the ENO interpolation procedure. These estimates, which are shown to hold for ENO reconstruction and interpolation of arbitrary order of accuracy and on nonuniform meshes, indicate a remarkable rigidity of the piecewise polynomial ENO procedure. 相似文献
99.
100.
Samaddar S Mandal AK Mondal SK Sahu K Bhattacharyya K Roy S 《The journal of physical chemistry. B》2006,110(42):21210-21215
The nature of solvent molecules around proteins in native and different non-native states is crucial for understanding the protein folding problem. We have characterized two compact denatured states of glutaminyl-tRNA synthetase (GlnRS) under equilibrium conditions in the presence of a naturally occurring osmolyte, l-glutamate. The solvation dynamics of the compact denatured states and the fully unfolded state has been studied using a covalently attached probe, acrylodan, near the active site. The solvation dynamics progressively becomes faster as the protein goes from the native to the molten globule to the pre molten globule to the fully unfolded state. Anisotropy decay measurements suggest that the pre-molten-globule intermediate is more flexible than the molten globule although the secondary structure is largely similar. Dynamic light scattering studies reveal that both the compact denatured states are aggregated under the measurement conditions. The implications of solvation dynamics in aggregated compact denatured states have been discussed. 相似文献