A 2-D bimetallic assembly with bridging cyanide ions

A novel cyanide-bridged bimetallic assembly, [Cu(1,3-Pn)₂]₂[Fe^III(CN)₆]ClO₄ · 2H₂O (1,3-Pn = 1,3-diaminopropane), derived from [Fe(CN)₆]^3– building blocks and four-coordinated bisdiamine metal(II) ions [Cu(1,3-Pn)₂]²⁺ is described and characterized by X-ray crystal analysis. The compound contains a two-dimensional network structure extended through Fe^III—CN—Cu linkages. Mössbauer experimental results indicate that the iron is ferric (Fe³⁺) in the complex. Cryomagnetic measurements reveal an antiferromagnetic exchange interaction between the nearest paramagnetic metal ions in the compound. The exchange mechanism was also discussed.     

Security of quantum key distribution using two-mode squeezed states against optimal beam splitter attack

For the beam splitter attack strategy against quantum key distribution using two-mode squeezed states, the analytical expression of the optimal beam splitter parameter is provided in this paper by applying the Shannon information theory. The theoretical secret information rate after error correction and privacy amplification is given in terms of the squeezed parameter and channel parameters. The results show that the two-mode squeezed state quantum key distribution is secure against an optimal beam splitter attack.     

Tunable nanogap devices for ultra-sensitive electrochemical impedance biosensing

A wealth of research has been available discussing nanogap devices for detecting very small quantities of biomolecules by observing their electrical behavior generally performed in dry conditions. We report that a gold nanogapped electrode with tunable gap length for ultra-sensitive detection of streptavidin based on electrochemical impedance technique. The gold nanogap is fabricated using simple monolayer film deposition and in-situ growth of gold nanoparticles in a traditional interdigitated array (IDA) microelectrode. The electrochemical impedance biosensor with a 25-nm nanogap is found to be ultra-sensitive to the specific binding of streptavidin to biotin. The binding of the streptavidin hinder the electron transfer between two electrodes, resulting in a large increase in electron-transfer resistance (R_et) for operating the impedance. A linear relation between the relative R_et and the logarithmic value of streptavidin concentration is observed in the concentration range from 1 pM (picomolar) to 100 nM (nanomolar). The lowest detectable concentration actually measured reaches 1 pM. We believe that such an electrochemical impedance nanogap biosensor provides a useful approach towards biomolecular detection that could be extended to a number of other systems.     

(Cl-nacnac)Pt(H)与端炔的反应机理

在Templeton实验(West, N. M.; et al. Organometallics 2008, 27, 5252)的基础上, 利用密度泛函理论研究了(Cl-nacnac)Pt(H)(Cl-nacnac: bis(N-aryl)-β-diiminate)与端炔的主、副反应机理. 结果表明: 叔丁基乙炔以1,2-方式插入到Pt―H键之间生成主产物, C―C键生成为决速步骤; 以2,1-方式插入到Pt―H键之间生成副产物, 炔烃插入为决速步骤. 基于主、副反应机理, 合理地解释了主、副产物生成的原因. 分析表明, 主产物是热力学控制的产物, 而副产物是动力学控制的产物.     

一种聚焦型X射线探测器在轨性能标定方法

X射线探测器是X射线天文观测及脉冲星导航的核心器件,受发射振动、高能粒子辐射损伤及元器件老化等影响,X射线探测器空间观测性能会逐渐变化,X射线探测器在轨标定有利于观测天体X射线辐射信息的准确获取及精确建模.研究利用了脉冲星辐射能谱标定X射线探测器性能的方法,能较好地消除探测器本底及空间环境噪声的影响,通过处理脉冲星导航试验卫星(XPNAV-1卫星)的Crab脉冲星观测数据,评估了我国首款聚焦型X射线探测器的在轨性能.计算结果表明,XPNAV-1卫星上聚焦型X射线探测器的有效面积在0.6-1.9 keV能段内优于2 cm~2,其中在0.7 keV能量处取得最大值3.06 cm~2,探测效率约10%;有效面积随着探测能量增大而减小,在2—3.5 keV能段内有效面积约为1 cm~2,而大于5 keV能段的有效面积约为0.1 cm~2,且此能段估计精度明显受光子统计误差影响.同时研究了考虑能量响应矩阵的探测器有效面积标定新方法,利用地面性能测试中五个特征能谱处的能量分辨率重构其能量响应矩阵,重新标定了聚焦型X射线探测器有效面积,发现该能量响应矩阵对结果影响较小.最后建议观测某些超新星遗迹监测能量分辨率及能量线性等指标的变化.     

W-S中含Fermi圈的光子链传播子及其 截面

研究电弱统一标准模型(W-S)里的电磁相互作用,传递相互作用的是 光子传播子,并对光子传播子里的“树图”以及出现轻子与夸克混合圈中的“链圈图”及其“链图”作了考察与分析,获得光子重整化链图传播子函数 “精确”解析计算结果. 利用这一结果,又对高能物理中备受关注的一类轻子反应： 作了有关研究,计算出在光子链图传播下的反应截面,并获得“精确”理论计算结果,同时还与实验结果作了对比分析,发现本文理论计算结果与实验吻合较好,获得了有关“辐射修正”的许多重要分析结果。     

Novel dioximato-bridged chromium(III)-copper(II)-chromium(III) trinuclear complexes with ferromagnetic exchange interactions

Summary Two new dioximato-bridged trinuclear Cr^II-Cu^II-Cr^III complexes, [Cr(salen)-Cu(-BD)₂-Cr(salen)] (1) and [Cr(salen)-Cu(-FD)₂-Cr(salen)]-H₂O (2), have been prepared and characterized [salen^2– = N,N-ethylene- bis (salicylideneiminate), (-BD)^2– = -benzyldioximato and (-FD)^2– = -furildioximato]. Magnetic susceptibility measurements in the 4.2–300 K range demonstrated the operation of a ferromagnetic interaction between the adjacent Cr^III and Cu^II ions through oximato bridges in both (1) and (2). Based on spin Hamiltonians =–2J(₁₂+₂₃)(S₁=S₃=3/2,S₂=1/2) the exchange integrals (J) were evaluated as 3.19 and 5.38 cm^–1 for (1) and (2), respectively.     

三维异双金属混合桥氰化物的合成和结构

高Tc分子磁体的研究近年来受到重视，其中尤以双过渡金属氰化物的研究发展异常迅猛．继Verdaguer[1]报道了Tc=90K的CsNi[Cr（CN）6]2·H2O配合物后，Verdaguer[2]和Girlami等[3]又分别报道了一系列TC=240、230、190K的同或异双过渡金属含CN配合物．Fujishima等[4]报道的具有磁光效应的K0.2Co1.4[Fe（CN）6]·6.9H2O配合物使分子磁性应用于分子电子学领域成为可能．但上述化合物均为粉末，未能获得其晶体结构，因此无法阐明其磁交换机理，亦难以发展成为晶须及其它异型磁性材料．为弄清混合金属氰化物成键性质、CN桥中介磁交换机…     

Study on the Vortex of the Qinghai-Xizang (Tibet) Plateau in Summer

In this paper an ideal model for the formation and development of the Qinghai-Xizang Plateau vortex is presented by a large number of statistical data and typical case studies. It points out that the Plateau vortex is shallow and thermal originated from a strong heat source near the surface of the west of the Plateau. Then moving eastward , it develops and becomes stronger and thicker with larger upward vertical velocity, and causes great precipitation in the middle Plateau. But at this time the heat source in the vortex becomes weaker, and even the heat sink occurs near the surface. Consequently, it disappears in a cold trough with a strong heat sink in the east of the Plateau. The heat source (sink) is mainly determined by the vertical eddy flux convergence (divergence) of the sensible heat caused by the cumulus convection and turbu-lance. Both the nonuniform heating (cooling) at the surface and the convergence (divergence) of the eddy kinetic energy coact and play an important role in the genesis (di     

关于费曼传播子在位形空间的解析式

We correct an inaccurate result of previous work on the Feynman propagator in position space of a free Dirac field in （3 ＋ 1）-dimensional spacetime; we derive the generalized analytic formulas of both the scalar Feynman propagator and the spinor Feynman propagator in position space in arbitrary （D ＋ 1）- dimensional spacetime; and we further find a recurrence relation among the spinor Feynman propagator in （D＋1）-dimensional spacetime and the scalar Feynman propagators in （D＋1）-, （D-1）- and （D＋3）-dimensional spacetimes.