全文获取类型
收费全文 | 2945篇 |
免费 | 301篇 |
国内免费 | 200篇 |
专业分类
化学 | 2148篇 |
晶体学 | 29篇 |
力学 | 131篇 |
综合类 | 15篇 |
数学 | 317篇 |
物理学 | 806篇 |
出版年
2024年 | 7篇 |
2023年 | 57篇 |
2022年 | 72篇 |
2021年 | 89篇 |
2020年 | 129篇 |
2019年 | 113篇 |
2018年 | 85篇 |
2017年 | 77篇 |
2016年 | 140篇 |
2015年 | 118篇 |
2014年 | 142篇 |
2013年 | 213篇 |
2012年 | 251篇 |
2011年 | 278篇 |
2010年 | 158篇 |
2009年 | 139篇 |
2008年 | 192篇 |
2007年 | 181篇 |
2006年 | 126篇 |
2005年 | 128篇 |
2004年 | 98篇 |
2003年 | 96篇 |
2002年 | 100篇 |
2001年 | 77篇 |
2000年 | 65篇 |
1999年 | 54篇 |
1998年 | 30篇 |
1997年 | 32篇 |
1996年 | 27篇 |
1995年 | 23篇 |
1994年 | 25篇 |
1993年 | 19篇 |
1992年 | 17篇 |
1991年 | 9篇 |
1990年 | 17篇 |
1989年 | 8篇 |
1988年 | 10篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1975年 | 2篇 |
1957年 | 2篇 |
排序方式: 共有3446条查询结果,搜索用时 39 毫秒
101.
以3-异丙基苯乙酮(1)为原料,经3步反应合成了花青醛[3-(3-异丙基苯基)丁醛(4)],并优化了反应条件。确定合成3-(3-异丙基苯基)-2-丁烯酸乙酯(2)的最优条件为:n(1)/n(磷酰基乙酸三乙酯)/n(氢化钠)=5/6/6,于室温反应12 h,收率84.5%;合成3-(3-异丙基苯基)-1-丁醇(3)的最佳条件为:n(2)/n(硼氢化钠)/n(六水合二氯化钴)/n(二异丙基胺)=10/20/1/2,于55 ℃反应24 h,收率87.8%;合成4的最优条件为: n(3)/n(乙酸酐)/n(亚硝酸钠)=5/4/15,投料顺序为:乙酸酐、3、亚硝酸钠,反应时间为2 min,收率91.0%。产物结构经1H NMR, 13C NMR和MS(ESI)确证。 相似文献
102.
Yuxiang Chen Ke Gong Feng Jiao Xiulian Pan Guangjin Hou Rui Si Xinhe Bao 《Angewandte Chemie (International ed. in English)》2020,59(16):6529-6534
Despite significant progress achieved in Fischer–Tropsch synthesis (FTS) technology, control of product selectivity remains a challenge in syngas conversion. Herein, we demonstrate that Zn2+‐ion exchanged ZSM‐5 zeolite steers syngas conversion selectively to ethane with its selectivity reaching as high as 86 % among hydrocarbons (excluding CO2) at 20 % CO conversion. NMR spectroscopy, X‐ray absorption spectroscopy, and X‐ray fluorescence indicate that this is likely attributed to the highly dispersed Zn sites grafted on ZSM‐5. Quasi‐in‐situ solid‐state NMR, obtained by quenching the reaction in liquid N2, detects C2 species such as acetyl (‐COCH3) bonding with an oxygen, ethyl (‐CH2CH3) bonding with a Zn site, and epoxyethane molecules adsorbing on a Zn site and a Brønsted acid site of the catalyst, respectively. These species could provide insight into C?C bond formation during ethane formation. Interestingly, this selective reaction pathway toward ethane appears to be general because a series of other Zn2+‐ion exchanged aluminosilicate zeolites with different topologies (for example, SSZ‐13, MCM‐22, and ZSM‐12) all give ethane predominantly. By contrast, a physical mixture of ZnO‐ZSM‐5 favors formation of hydrocarbons beyond C3+. These results provide an important guide for tuning the product selectivity in syngas conversion. 相似文献
103.
Kai Wu Kang Li Sha Chen Ya‐Jun Hou Yu‐Lin Lu Jing‐Si Wang Mei‐Juan Wei Mei Pan Cheng‐Yong Su 《Angewandte Chemie (International ed. in English)》2020,59(7):2639-2643
A nanocage coupling effect from a redox RuII‐PdII metal–organic cage (MOC‐16) is demonstrated for efficient photochemical H2 production by virtue of redox–guest modulation of the photo‐induced electron transfer (PET) process. Through coupling with photoredox cycle of MOC‐16, tetrathiafulvalene (TTF) guests act as electron relay mediator to improve the overall electron transfer efficiency in the host–guest system in a long‐time scale, leading to significant promotion of visible‐light driven H2 evolution. By contrast, the presence of larger TTF‐derivatives in bulk solution without host–guest interactions results in interference with PET process of MOC‐16, leading to inefficient H2 evolution. Such interaction provides an example to understand the interplay between the redox‐active nanocage and guest for optimization of redox events and photocatalytic activities in a confined chemical nanoenvironment. 相似文献
104.
Si‐Hua Hou Adriana Y. Prichina Mengxi Zhang Guangbin Dong 《Angewandte Chemie (International ed. in English)》2020,59(20):7848-7856
To show the synthetic utility of the catalytic C?C activation of less strained substrates, described here are the collective and concise syntheses of the natural products (?)‐microthecaline A, (?)‐leubehanol, (+)‐pseudopteroxazole, (+)‐seco‐pseudopteroxazole, pseudopterosin A–F and G—J aglycones, and (+)‐heritonin. The key step in these syntheses involve a Rh‐catalyzed C?C/C?H activation cascade of 3‐arylcyclopentanones, which provides a rapid and enantioselective route to access the polysubstituted tetrahydronaphthalene cores presented in these natural products. Other important features include 1) the direct C?H amination of the tetralone substrate in the synthesis of (?)‐microthecaline A, 2) the use of phosphoric acid to enhance efficiency and regioselectivity for problematic cyclopentanone substrates in the C?C activation reactions, and 3) the direct conversion of serrulatane into amphilectane diterpenes by an allylic cyclodehydrogenation coupling. 相似文献
105.
Nonlinear Dynamics - Intelligent fault diagnosis provides great convenience for the prognostic and health management of the rotating machinery. Recently, the multiscale diversity entropy has been... 相似文献
106.
Polymer electrolytes based on poly(ethylene oxide) and lithium salts have been widely studied in recent years. In order to enhance the room temperature ionic conductivity of PEO-LiX complexes, various techniques, such as addition of plasticizers and crown ether, and also irradiation by γ and electron beams have been investigated. The enhancement of the conductivity by irradiation has been accounted for the decreasing of the crystallinity of PEO-LiX. We reviewed these results and have investigated the degradation processes of PEO using Tb3+ fluorescence probes. We have also studied on the effects of irradiation of polymers such as poly(acrylic acid) (PAA), poly(methacrylic acid) (PMA) and PEO using Tb+3 fluorescence probe. Various monomers containing SO3H and COOH have been grafted on poly(ethylene oxide) using irradiation technique. The structures and ionic conductivities of Li and Na salts of irradiated products were investigated in detail. 相似文献
107.
108.
QiuHong Wang Abdusalam Abdukerim Wei Chen Xun Chen YunHua Chen XiangYi Cui YingJie Fan DeQing Fang ChangBo Fu LiSheng Geng Karl Giboni Franco Giuliani LinHui Gu XuYuan Guo Ke Han ChangDa He Di Huang Yan Huang YanLin Huang Zhou Huang Peng Ji XiangDong Ji YongLin Ju YiHui Lai Kun Liang HuaXuan Liu JiangLai Liu WenBo Ma YuGang Ma YaJun Mao Yue Meng Parinya Namwongsa KaiXiang Ni JinHua Ning XuYang Ning XiangXiang Ren ChangSong Shang Lin Si AnDi Tan AnQing Wang HongWei Wang Meng Wang SiGuang Wang XiuLi Wang Zhou Wang MengMeng Wu ShiYong Wu JingKai Xia MengJiao Xiao PengWei Xie BinBin Yan JiJun Yang Yong Yang ChunXu Yu Jumin Yuan Dan Zhang HongGuang Zhang Tao Zhang Li Zhao QiBin Zheng JiFang Zhou Ning Zhou XiaoPeng Zhou 《中国科学:物理学 力学 天文学(英文版)》2020,(3):54-63
In dark matter direct detection experiments,neutron is a serious source of background,which can mimic the dark matter-nucleus scattering signals.In this paper,we present an improved evaluation of the neutron background in the PandaX-II dark matter experiment by a novel approach.Instead of fully relying on the Monte Carlo simulation,the overall neutron background is determined from the neutron-induced high energy signals in the data.In addition,the probability of producing a dark-matter-like background per neutron is evaluated with a complete Monte Carlo generator,where the correlated emission of neutron(s)andγ(s)in the(α,n)reactions and spontaneous fissions is taken into consideration.With this method,the neutron backgrounds in the Run 9(26-ton-day)and Run 10(28-ton-day)data sets of PandaX-II are estimated to be(0.66±0.24)and(0.47±0.25)events,respectively. 相似文献
109.
Dark sector may couple to the Standard Model via one or more mediator particles.We discuss two types of mediators:the dark photon A’and the dark scalar mediatorΦ.The total cross-sections and various differential distributions of the processes e+e-→qqA’and e+e→qqφ(q=u,d,c,s and b quarks)are discussed.We focus on the study of the invisible due to the cleaner background at future e+e-colliders.It is found that the kinematic distributions of the two-jet system could be used to identify(or exclude)the dark photon and the dark scalar mediator,as well as to distinguish between them.We further study the possibility of a search for dark photons at a future CEPC experiment with s1/2=91.2 GeV and 240 GeV.With CEPC running at s1/2=91.2 GeV,it would be possible to perform a decisive measurement of the dark photon(20 GeV相似文献
110.
Transport in Porous Media - Permeability, one of the most significant parameters for CBM, is affected by many influencing factors. In this paper, an improved fully coupled permeability model was... 相似文献