全文获取类型
收费全文 | 341篇 |
免费 | 13篇 |
国内免费 | 1篇 |
专业分类
化学 | 216篇 |
晶体学 | 4篇 |
力学 | 18篇 |
数学 | 19篇 |
物理学 | 98篇 |
出版年
2024年 | 2篇 |
2023年 | 2篇 |
2022年 | 6篇 |
2021年 | 13篇 |
2020年 | 14篇 |
2019年 | 19篇 |
2018年 | 9篇 |
2017年 | 4篇 |
2016年 | 13篇 |
2015年 | 10篇 |
2014年 | 14篇 |
2013年 | 26篇 |
2012年 | 24篇 |
2011年 | 16篇 |
2010年 | 10篇 |
2009年 | 9篇 |
2008年 | 15篇 |
2007年 | 14篇 |
2006年 | 6篇 |
2005年 | 6篇 |
2004年 | 4篇 |
2003年 | 10篇 |
2002年 | 6篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1995年 | 3篇 |
1992年 | 2篇 |
1991年 | 5篇 |
1990年 | 1篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 7篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1976年 | 1篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1971年 | 1篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有355条查询结果,搜索用时 46 毫秒
31.
[reaction: see text] A library of nine-membered, biaryl-containing rings has been synthesized in parallel on polystyrene macrobeads. Dimeric medium rings were shown to be accessible via a regio- and stereoselective double cyclization. 相似文献
32.
Kasyutich V.L. Bale C.S.E. Canosa-Mas C.E. Pfrang C. Vaughan S. Wayne R.P. 《Applied physics. B, Lasers and optics》2003,76(6):691-697
We present an application of cavity-enhanced absorption spectroscopy with an off-axis alignment of the cavity formed by two
spherical mirrors and with time integration of the cavity-output intensity for detection of nitrogen dioxide (NO2) and iodine monoxide (IO) radicals using a violet laser diode at λ=404.278 nm. A noise-equivalent (1σ≡ root-mean-square variation
of the signal) fractional absorption for one optical pass of 4.5×10-8 was demonstrated with a mirror reflectivity of ∼0.99925, a cavity length of 0.22 m and a lock-in-amplifier time constant
of 3 s. Noise-equivalent detection sensitivities towards nitrogen dioxide of 1.8×1010 molecule cm-3 and towards the IO radical of 3.3×109 molecule cm-3 were achieved in flow tubes with an inner diameter of 4 cm for a lock-in-amplifier time constant of 3 s. Alkyl peroxy radicals
were detected using chemical titration with excess nitric oxide (RO2+NO→RO+NO2). Measurement of oxygen-atom concentrations was accomplished by determining the depletion of NO2 in the reaction NO2+O→NO+O2. Noise-equivalent concentrations of alkyl peroxy radicals and oxygen atoms were 3×1010 molecule cm-3 in the discharge-flow-tube experiments.
Received: 4 February 2003 / Revised version: 10 March 2003 / Published online: 12 May 2003
RID="*"
ID="*"Corresponding author. Fax: +44-1865/275-410, E-mail: vlk@physchem.ox.ac.uk 相似文献
33.
Energetics of an ohmically heated deuterium-tritium high densityZ-pinch has been computed taking into account the energy deposited by the alpha particles produced by fusion. As a result,
at higher plasma densities (>1027/m3) and temperatures (>4keV), the pinch current can cross Pease limit and the plasma can get ignited, yielding higher energy
gain and neutron yield in a shorter confinement time. 相似文献
34.
Yi ZHU Kumar Shyam Chenlu HU Zixuan CHEN Yapeng ZHANG Fengyi ZHAO Xianglun WEI Limin DUAN Nu XU Hao QIU 《原子核物理评论》2021,38(4):416-422
低温高密核物质测量谱仪(CEE)是研究高重子数密度区核物质性质的重离子碰撞实验谱仪。使用了先进的 SAMPA 电子学读出芯片的时间投影室(TPC)是 CEE 最核心的探测器。在集团重建的过程中,同一排读出板的信号被首先重建成 2 维集团,然后根据 2 维集团的 ADC 加权平均位置重建击中点。当信号 ADC 随漂移时间变化呈峰-谷-峰结构时,一个集团可能被重建成两个或更多击中点,从而提高双径迹分辨能力。使用模拟信号的测试显示,该重建算法在$x/ y$ 方向可以达到0.100/0.043 cm的位置分辨能力和1.1/2.8 cm的双径迹分辨能力。 相似文献
35.
Archana Vibhute Shyam Mokle Khushal Karamunge Vasant Gurav Yeshwant Vibhute 《中国化学快报》2010,21(8):914-918
<正>Green,mild and efficient iodination of hydroxylated aromatic aldehydes and ketones using iodine and iodic acid in the solidstate by grinding under solvent-free conditions at room temperature.This method provides several advantages such as environmentally friendly,short reaction times,high yields,non-hazardous and simple work-up procedure. 相似文献
36.
Swades De Priyatosh Mandal Shyam S. Chakraborty 《Mathematical and Computer Modelling》2011,53(11-12):2093-2107
Standard analyses of wireless random access protocols that are available in the literature assume negligible propagation delay between any two nodes. This assumption holds good in reasonably short-range terrestrial RF (radio frequency) wireless networks. On the contrary, in wireless communications involving acoustic wave propagation, as in underwater wireless networks, even short distance propagation has appreciably large propagation delay. This observation has led to several recent simulation and experimental studies on underwater Aloha and slotted-Aloha (S-Aloha) protocols and also a few new proposals on random access protocols for underwater wireless ad hoc networks (UWN). To study the efficiency of more advanced multiaccess communication protocols for UWN, it is important to benchmark their performances with respect to the two basic random access protocols, Aloha and S-Aloha. This paper provides an analytic framework to capture the performance of Aloha and S-Aloha protocols in an underwater environment with high and random internodal signal propagation delay. The performance of underwater Aloha and S-Aloha are contrasted with those in short-range terrestrial RF wireless networks. The analysis shows that random internodal propagation delay has no effect on the underwater Aloha performance. It also sheds light on the throughput degradation of underwater S-Aloha with a slotting concept that achieves RF S-Aloha equivalent one-slot vulnerability. Additionally, a modified slotting concept is introduced where the slot size is judiciously reduced such that even by allowing some collisions the overall system throughput can be increased. Our calculations show that, with the modified slotting approach up to 17% throughput performance gain can be achieved over the naive (RF S-Aloha equivalent) slotting approach in UWN. Our analytic results are supported by discrete event simulations. 相似文献
37.
Shyam Krishnan 《Tetrahedron letters》2007,48(43):7571-7573
A method for the synthesis of 3,3-disubstituted oxindole derivatives is described. This involves the base-mediated addition of malonate esters to 3-halo-3-alkyloxindoles. The addition is tolerant of a range of alkyl substituents at position 3 of the oxindole. Addition to an aryl chloro-oxindole is also described. 相似文献
38.
The thioridazine metabolites 7-hydroxythioridazine (2a) and 7-hydroxysulforidazine (2b) were synthesized. Commercial 4-chloro-3-nitrophenylmethylsulfone was converted to the corresponding 4-thiol through an intermediate xanthate ester. Subsequent zinc metal reduction provided the 3-amino thiolate. This salt was condensed with chloroquinone to yield 7-hydroxy-2-methylsulfonylphenothiazine which was then protected as the isopropyl ether. N-Alkylation with 2-(2-chloroethyl)-1-methylpiperidine using sodium hydroxide, then ether cleavage, afforded 2b . The N-alkylation followed by reduction with diisobutylaluminum hydride and deblocking yielded 2a . These reference standards will assist in an exploration of the potential role of meta-bolically formed 2a and 2b in the neuroleptic response to thioridazine. 相似文献
39.
The growth equation for weak discontinuities headed by wave fronts of arbitrary shape in a relaxing gas flow is derived along the orthogonal trajectories of the wave fronts. An explicit criteria for the growth and decay of weak discontinuities along their orthogonal trajectories is given. It is concluded that the internal relaxation processes in the flow as well as the wave front curvature both have a stabilizing effect on the tendency of the wave surface to grow into a shock in the sense that they cause the shock formation time to increase. 相似文献
40.
In the present investigation, thermophilic fungus Rhizomucor pusillus was used to study biotransformation of antihelmintic drug albendazole to produce its active metabolite, albendazole sulfoxide and novel metabolites of commercial interest. A two-stage fermentation procedure was followed for biotransformation of albendazole. The transformation was identified and structures were confirmed by high-performance liquid chromatography and liquid chromatography-tandem mass spectrometry analysis. Four metabolites albendazole sulfoxide, the active metabolite, albendazole sulfone, N-methyl metabolite of albendazole sulfoxide, and a novel metabolite were produced. The study demonstrates the biotransformation ability of thermophilic fungus R. pusillus NRRL28626 in the production of, the active metabolite of albendazole which has industrial and economic importance, other metabolites and a novel metabolite in an ecofriendly way. 相似文献