Analysis of a Tessiet type food chain chemostat with k-times’ periodically pulsed input

In this paper, we introduce and study a Tessiet type food chain chemostat, which contains with predator, prey and k-times’ periodically pulsed substrate. We investigate the subsystem with substrate and prey and study the stability of the periodic solutions, which are the boundary periodic solutions of the system. The stability analysis of the boundary periodic solution yields an invasion threshold. By use of standard techniques of bifurcation theory, we prove that above this threshold there are periodic oscillations in substrate, prey, and predator. Simple cycles may give way to chaos in a cascade of period-doubling bifurcations. Furthermore, by comparing bifurcation diagrams with different bifurcation parameters, we can see that the impulsive system shows two kinds of bifurcations, whose are period-doubling and period-halfing. When impulsive period is small, there exists quasiperiodic oscillation in the impulsive system.     

Microwave-assisted combinatorial synthesis of hexa-substituted 1,4-dihydropyridines scaffolds using one-pot two-step multicomponent reaction followed by a S-alkylation

A sequential one-pot two-step protocol for microwave-assisted synthesis of Hantzsch-type hexa-substituted 1,4-dihydropyridines has been developed. The three-component reactions of beta-aroylthioamides with aldehydes and acetonitrile derivatives produce the intermediates in situ followed by a S-alkylation to afford hexa-substituted 1,4-dihydropyridines. The reaction presumably proceeds via a Knoevenagel condensation-Michael addition-cyclocondensation-rearrangement-S N2 reaction sequence. Target compounds were obtained in high yields and simply purified by recrystallization. The novel method is complementary to the classical Hantzsch synthesis in that it is well-suited to the preparation of hexa-substituted 1,4-dihydropyridines.     

Benzothiazole‐Pyimidine‐Based BF2 Complex for Selective Detection of Cysteine

Due to the similar structure and reactivity of cysteine (Cys), homocysteine (Hcy) and glutathione (GSH), the simultaneous discrimination of Cys over Hcy and GSH by a single fluorescent sensor is still a great challenge. In this work, a benzothiazole‐pyimidine‐based boron difluoride complex ( BPB ) was developed as a new fluorescent sensor for Cys. The sensor exhibits a highly selective “turn‐on” response to cysteine over Hcy, GSH and other amino acids in aqueous solution at physiological pH. The observed pseudo‐first‐order rate constant for the reaction of BPB with Cys was calculated to be about 0.062 min⁻¹. The detection limit of this sensor for Cys was determined to be 332 nm, and bioimaging of exogenous Cys by this sensor was successfully applied in living cells, thus indicating that this sensor holds great potential for biological applications.     

Catalytic asymmetric hydrogenation to access spiroindane dimethyl acetic acid

Asymmetric hydrogenation of achiral spiroindene dimethyl acetic acid 2 with 4% of Ru(II)-Mandyphos in acetone produced (S)-spiroindane dimethyl acetic acid 1 in 86% isolated yield and 96.8:3.2 enantiomeric ratio.     

Formation of CO(x)-free H2 and cup-stacked carbon nanotubes over nano-Ni dispersed single wall carbon nanohorns

Transitional metals (M) were dispersed on single-wall carbon nanohorns (M/SWCNHs, M = Fe, Co, Ni, Cu) by simple thermal treatment of the deposited metal nitrate without H(2) reduction. Nanometallic Ni particles on SWCNH were evidenced by high-resolution transmission electron microscopic observation and X-ray photoelectron spectroscopy. The nano-Ni dispersed on SWCNH showed the highest CH(4) decomposition activity; the activity of used transitional metals decreases in the order Ni ? Co > Fe ? Cu. On the other hand, the reaction rate over Ni/SWCNH was much larger than that over Ni/Al(2)O(3), and the former provided CO(x)-free H(2) and cup-stacked carbon nanotubes, while Ni/Al(2)O(3) produced CO(x) in addition to H(2). SWCNH was superior to Al(2)O(3) as the catalyst support of Ni for the CH(4) decomposition reaction.     

一种混合WDMA-OCDMA系统归一化吞吐量性能研究

理论分析了一种混合WDMA-OCDMA系统的归一化吞吐量性能.研究了光差拍噪声对系统归一化吞吐量性能的影响.提出了BCH信道编码的方案来改善系统性能.结果表明,当系统负载较轻时,归一化吞吐量略微下降;但当系统负载中等或较重时,归一化吞吐量明显提高.同时,BCH信道编码提高了WDMA-OCDMA系统的归一化吞吐量峰值.     

Effects of particle size of silica aerogel on its nano-porous structure and thermal behaviors under both ambient and high temperatures

Silica aerogel as the most commonly used aerogel has attracted increasing attention from both academia and industries due to its extraordinary performances and potentials. Through this study, influences of the particle size (38–880 μm) on its nano-porous structure and thermal behaviors were addressed based on a series of experimental tests under both ambient and high temperatures (i.e., 1000 °C). It was known from the experimental results that the fractional densities of samples with particle sizes of 270–880 μm were similar, which were about 40% of the sample with a particle size of 38 μm. The ratio of densification was found decrease to about 10–40% when heating time increased from 10 to 90 min. For those samples with 150 μm or finer particles, SiC crystal with 70.8 nm particles was generated, and the pore shape was slit in the silica aerogel. The Brunauer–Emmett–Teller (BET) surface area, cumulative pore volume, and average pore diameter of those heated samples with over 75 μm diameter were about 40%, 20%, and 50% of those unheated (virgin) samples, respectively. Virgin samples showed 18% lower thermal conductivity for 75 μm particles compared to that of 38 μm, while for the heated samples, 38 μm particles showed a 28% lower thermal conductivity than that with 880 μm. Mixture of silica aerogel and other inorganic material particles are recommended for high-temperature applications, while the silica aerogel with different-sized particles are observed better for applications under ambient temperature.     

HIRFL-CSR ETF多层CsI(Tl)望远镜探测器能量刻度方法

在兰州重离子加速器冷却储存环（HIRFL-CSR）的外靶终端（ETF）,设计建造了一套多层CsI（Tl）望远镜探测器,用于对轻质量带电粒子的鉴别。这套探测器由7层CsI（Tl）晶体组成,每一层晶体光输出信号由4个光电倍增管分别在晶体4角读出。由于CsI（Tl）晶体对于重离子的响应是非线性的,且与入射离子的种类有关,这些因素使得对这台探测器的能量刻度需要做专门的研究。利用RIBLL2提供的能量在200 s~300 MeV/u的次级束流对探测器进行了测试,并针对第一片CsI（Tl）晶体的光输出以及所有CsI（Tl）晶体光输出的和的刻度方法分别进行了探索。在此能区下,第一片CsI（Tl）晶体猝灭现象可以近似忽略,即光输出与能量沉积近似呈线性。对于所有晶体光输出的和,利用一个经验公式对其进行刻度,利用这种刻度方法计算得到的光输出的值与实验测量值之间的差别小于5%。A multi-layer CsI(Tl) telescope has been designed and constructed at External Target in Facility (ETF) terminal of the Cooling Storage Ring of Heavy Ion Research Facility in Lanzhou(HIRFL-CSR), and is used for identifying light charged particles. The detector consists of seven layers of CsI(Tl) crystals, and the signals of each crystal are read out by four photomultipliers at the corners. Since the response of the CsI(Tl) crystal to the heavy ions is non-linear and also depends on the species of the incident ions, the energy calibration method of the telescope must be carefully studied. With the help of the secondary beams selected by RIBLL2 in the energy ranges from 200 to 300 MeV/u, the telescope has been tested and the energy calibration method for the first-layer crystal together with the whole telescope has been investigated. In this energy region, the quench effect in the first-layer crystal can be neglected and a linear expression can be used to represent the relation between the light output and the energy deposition in the crystal. To the total light output of the telescope, an empirical formula is used for the energy calibration. The difference between the calculated results and the experiment data is globally less than 5%.     

Dissection of the Multichannel Reaction O(3P) + C2H2: Differential Cross-Sections and Product Energy Distributions

The O(³P) + C₂H₂ reaction plays an important role in hydrocarbon combustion. It has two primary competing channels: H + HCCO (ketenyl) and CO + CH₂ (triplet methylene). To further understand the microscopic dynamic mechanism of this reaction, we report here a detailed quasi-classical trajectory study of the O(³P) + C₂H₂ reaction on the recently developed full-dimensional potential energy surface (PES). The entrance barrier TS1 is the rate-limiting barrier in the reaction. The translation of reactants can greatly promote reactivity, due to strong coupling with the reaction coordinate at TS1. The O(³P) + C₂H₂ reaction progress through a complex-forming mechanism, in which the intermediate HCCHO lives at least through the duration of a rotational period. The energy redistribution takes place during the creation of the long-lived high vibrationally (and rotationally) excited HCCHO in the reaction. The product energy partitioning of the two channels and CO vibrational distributions agree with experimental data, and the vibrational state distributions of all modes of products present a Boltzmann-like distribution.