Benzothiazole‐Pyimidine‐Based BF2 Complex for Selective Detection of Cysteine

Due to the similar structure and reactivity of cysteine (Cys), homocysteine (Hcy) and glutathione (GSH), the simultaneous discrimination of Cys over Hcy and GSH by a single fluorescent sensor is still a great challenge. In this work, a benzothiazole‐pyimidine‐based boron difluoride complex ( BPB ) was developed as a new fluorescent sensor for Cys. The sensor exhibits a highly selective “turn‐on” response to cysteine over Hcy, GSH and other amino acids in aqueous solution at physiological pH. The observed pseudo‐first‐order rate constant for the reaction of BPB with Cys was calculated to be about 0.062 min⁻¹. The detection limit of this sensor for Cys was determined to be 332 nm, and bioimaging of exogenous Cys by this sensor was successfully applied in living cells, thus indicating that this sensor holds great potential for biological applications.     

Spectrophotometric Method for the Determination of Oxidative IonsWith Decoloring Reaction Using HCPCF

HCPCF is a color reagent for the determination of vanadium, zinc and magnesium, etc. To the best of our knowledge, no work on the decoloring reaction for analytical use of HCPCF for the determination of oxidative anions has been report. In this work, we found that some oxidative anions can oxidize HCPCF in acid medium, forming a colorless product. In addition, surfactant was used in this work, because of the low solubility of HCPCF in aqueous solutions. The purpose of this work is to establish a new, rapid and simple spectrophotometric method for the determination of NO2-, BrO3-,IO3-, IO4-and Cr2O7-based on the reaction between HCPCF and analytes in the presence of emulsion OP.     

某些雄性和同化激素的吸附行为和电化学测定

某些雄性激素和同化激素能在不同条件下吸附在静汞电极上。具有１７－羟基的化合物仅在带负电的电极表面吸附；而具有１７－酯化基团的化合物则在开路下即可进行吸附。所吸附的激素在电位扫描时，于－１．３－１．５Ｖ之间可被还原。因此，采用吸附伏安法可以灵敏地测定不同类型的激素。本文拟定了分析条件并测定了药片中激素的含量，同时也探讨了检测尿样中同化激素的可能性。     

Synthesis,bioactivities, and X-ray structure analysis of 2-cyano-5-methylpyrazolo[1,5-a]pyrimidine

The title compound crystallizes in the monoclinic space group P2₁/c with unit cell parameters a = 3.8380(12), b = 11.994(4), and c = 16.245(5) Å, β = 90.743(5)^∘, V = 747.7(4) ų, and Z = 4. The final reliability index is 0.0409 for 1088 observed reflections. All the non-hydrogen atoms in the title compound are almost coplanar, the largest deviation from the mean plane being 0.030(2) Å for atom C5. The crystal cohesion is accentuated by C–H⋅sN hydrogen bond. The X-ray crystallography analysis indicates that the methyl group is at the 5-position of the compound 4 rather than at the 7-position of the isomer 4-1. The preliminary biological test shows that the title compound has moderate herbicidal activity.     

Dissection of the Multichannel Reaction O(3P) + C2H2: Differential Cross-Sections and Product Energy Distributions

The O(³P) + C₂H₂ reaction plays an important role in hydrocarbon combustion. It has two primary competing channels: H + HCCO (ketenyl) and CO + CH₂ (triplet methylene). To further understand the microscopic dynamic mechanism of this reaction, we report here a detailed quasi-classical trajectory study of the O(³P) + C₂H₂ reaction on the recently developed full-dimensional potential energy surface (PES). The entrance barrier TS1 is the rate-limiting barrier in the reaction. The translation of reactants can greatly promote reactivity, due to strong coupling with the reaction coordinate at TS1. The O(³P) + C₂H₂ reaction progress through a complex-forming mechanism, in which the intermediate HCCHO lives at least through the duration of a rotational period. The energy redistribution takes place during the creation of the long-lived high vibrationally (and rotationally) excited HCCHO in the reaction. The product energy partitioning of the two channels and CO vibrational distributions agree with experimental data, and the vibrational state distributions of all modes of products present a Boltzmann-like distribution.     

HIRFL-CSR ETF多层CsI(Tl)望远镜探测器能量刻度方法

在兰州重离子加速器冷却储存环（HIRFL-CSR）的外靶终端（ETF）,设计建造了一套多层CsI（Tl）望远镜探测器,用于对轻质量带电粒子的鉴别。这套探测器由7层CsI（Tl）晶体组成,每一层晶体光输出信号由4个光电倍增管分别在晶体4角读出。由于CsI（Tl）晶体对于重离子的响应是非线性的,且与入射离子的种类有关,这些因素使得对这台探测器的能量刻度需要做专门的研究。利用RIBLL2提供的能量在200 s~300 MeV/u的次级束流对探测器进行了测试,并针对第一片CsI（Tl）晶体的光输出以及所有CsI（Tl）晶体光输出的和的刻度方法分别进行了探索。在此能区下,第一片CsI（Tl）晶体猝灭现象可以近似忽略,即光输出与能量沉积近似呈线性。对于所有晶体光输出的和,利用一个经验公式对其进行刻度,利用这种刻度方法计算得到的光输出的值与实验测量值之间的差别小于5%。A multi-layer CsI(Tl) telescope has been designed and constructed at External Target in Facility (ETF) terminal of the Cooling Storage Ring of Heavy Ion Research Facility in Lanzhou(HIRFL-CSR), and is used for identifying light charged particles. The detector consists of seven layers of CsI(Tl) crystals, and the signals of each crystal are read out by four photomultipliers at the corners. Since the response of the CsI(Tl) crystal to the heavy ions is non-linear and also depends on the species of the incident ions, the energy calibration method of the telescope must be carefully studied. With the help of the secondary beams selected by RIBLL2 in the energy ranges from 200 to 300 MeV/u, the telescope has been tested and the energy calibration method for the first-layer crystal together with the whole telescope has been investigated. In this energy region, the quench effect in the first-layer crystal can be neglected and a linear expression can be used to represent the relation between the light output and the energy deposition in the crystal. To the total light output of the telescope, an empirical formula is used for the energy calibration. The difference between the calculated results and the experiment data is globally less than 5%.     

Effect of microstructure of MgO buffer layer on BaTiO3 grown on silicon substrates

MgO ultrathin films were grown on Si(1 0 0) substrates as buffer layers for the growth of ferroelectric BaTiO₃ thin films by laser molecular beam epitaxy (L-MBE). The deposition process of MgO buffer layers grown on silicon was in situ monitored by reflection high-energy electron diffraction (RHEED). The structure of BaTiO₃ films fabricated on MgO buffers was investigated by X-ray diffraction. Biaxially textured MgO was obtained at high laser energy density, but when the laser energy was lowered, MgO buffer was transformed to the form of texture with angular dispersion with the increase of the film thickness. BaTiO₃ films grown on the former buffer were completely (0 0 1) textured, while those on the latter were (0 0 1) preferred orientated. Furthermore, the fabricated MgO buffers and BaTiO₃ films had atomically smooth surface and interface. All these can reveal that the quality of textured MgO buffer is a key factor for the growth of BaTiO₃ films on silicon.     

球面的快速测量与非球面的快速拼接

利用立式车间用球面干涉仪实现比较法球面面形测量，一次调整好以后可以达到多片快速测量，避免复杂的调整，通过监示器看到光圈；并可以通过条纹扫描技术实现光圈数Ｎ及局部光圈数ΔＮ的自动客观判读；对于低陡度非球面的多块拼接，可以籍助“非球面特征干涉图”实现快速初步拼接，然后再用每个子孔径的相位探测实现整个孔径的拼接，并可以通过数字的测量与波面相减自动获得非球面的面形误差。     

一种混合WDMA-OCDMA系统归一化吞吐量性能研究

理论分析了一种混合WDMA-OCDMA系统的归一化吞吐量性能.研究了光差拍噪声对系统归一化吞吐量性能的影响.提出了BCH信道编码的方案来改善系统性能.结果表明,当系统负载较轻时,归一化吞吐量略微下降;但当系统负载中等或较重时,归一化吞吐量明显提高.同时,BCH信道编码提高了WDMA-OCDMA系统的归一化吞吐量峰值.     

Catalytic asymmetric hydrogenation to access spiroindane dimethyl acetic acid

Asymmetric hydrogenation of achiral spiroindene dimethyl acetic acid 2 with 4% of Ru(II)-Mandyphos in acetone produced (S)-spiroindane dimethyl acetic acid 1 in 86% isolated yield and 96.8:3.2 enantiomeric ratio.