Oxidation‐induced the Formation of Vesicles from Ferrocene Derivative Superamphiphiles

The stimuli‐responsive vesicles were prepared via electrochemical oxidation on the mixture solution of ferrocenylmethyl‐trimethylammonium iodide (FcMI) and sodium deoxycholate (NaDC). The vesicle structure and morphology are characterized respectively by transmission electron microscopy (TEM), dynamic light scattering (DLS) and atomic force microscopy (AFM). The vesicle shells can be clearly observed by TEM with the thickness ranging from several to several tens of nanometers and their outer diameters at the range of 50‐200 nm. The formation of vesicular structures is also supported via AFM measurements, and the ratio of the diameter and height of the nanospheres was estimated to be ca. 10, indicating the shell collapse. The obtained results are significant for the preparation of smart supramolecular aggregates.     

Amperometric biosensor based on hemoglobin immobilized on Cu2S nanorods/nafion nanocomposite film for the determination of polyphenols

A novel biosensor was fabricated based on hemoglobin (Hb) immobilized onto cuprous sulfide (Cu₂S) nanorods/nafion nanocomposite film for the detection of polyphenols in the presence of hydrogen peroxide (H₂O₂). The nanostructured inorganic–organic hybrid material formed by Cu₂S nanorods and nafion provided a biocompatible microenvironment for Hb and increased the sensitivity for polyphenols detection. The modified electrodes were characterized by electrochemical impedance spectroscopy and linear sweep voltammetry. Parameters such as pH, H₂O₂ concentration, and the applied potential were optimized. Under optimum conditions, the biosensor gave linear response ranges of 7.0–110, 0.6–10, and 8–100 μM for catechol, hydroquinone, and resorcin, with the detection limits of 0.5, 0.03, and 0.6 μM (S/N?=?3), respectively. The developed biosensor exhibited a short response time within only 8 s with good stability and reproducibility. Such a novel biosensor showed great promise for rapid, simple analysis of polyphenols contents in real samples.     

Selective removal of nitrate by using a novel macroporous acrylic anion exchange resin

An anion exchange resin NDP-5 has been prepared successfully and applied on the selective removal of nitrate from SO₄^2-/ NO₃^- binary co-existence system.The composition and morphology of NDP-5 were confirmed by FT-IR and SEM.The NDP-5 resin exhibits the completely different behavior on the adsorption capacity,adsorption kinetic and the effect of the completing anion in the absence or presence of sulfate,compared to D213.And,the resultants of kinetic are well fitted by the pseudo-first-order and pseudo-second-order models.These results are very important to develop novel resins with great features.     

二极管激光器垂直阵列光束精密准直

 为实现二极管激光器垂直阵列输出光束具有小发散角、高指向精度的特点,简述了快轴准直（FAC）微透镜的光束准直原理,分析了调节装置的精度要求及透镜选择等问题。通过光学成像方法实时监测二极管激光bar条的近场像和远场像,对FAC透镜分别进行粗调节和细调节,获得了20个bar条连续输出2 kW,垂直阵列二极管激光快轴准直光束远场发散角4.4 mrad,bar条间准直光束指向精度不大于±1.7 mrad的准直效果,并对监测精度进行了简要分析。对影响光束准直效果的因素进行了分析,指出了工艺优化的重点。     

基于亮度衰减模型的硅基OLED微显示器寿命研究

为了研究硅基OLED(Organic Light Emitting Diodes)微显示器的使用寿命,通过老化实验提出一种基于恢复模型的OLED亮度衰减模型,该亮度衰减模型融合传统延伸型指数衰减模型与OLED亮度恢复模型.使用亮度退化数据拟合衰减模型中的待定参数,得到初始亮度和占空比与OLED寿命之间的定性和定量关系,...     

Mapping properties of certain oscillatory integrals on modulation spaces

Suppose β1 α1 ≥0,β2 α2 ≥ 0 and(k,j) ∈R2. In this paper, we mainly investigate the mapping properties of the operator T_αβf(x,y,z)=∫_Q~2f(x-t,y-s,z-t~ks~j)e~(-2πit-β1_s-β2)t~(-1-α1)s~(-1-α2)dtds on modulation spaces, where Q~2 = [0,1] x [0,1] is the unit square in two dimensions.     

ASP技术在《大学物理实验》课件中的应用

介绍了ASP技术的特点、现状，较为详细的讨论了ASP技术在《大学物理实验》课件中的应用。     

活性炭-水杨基荧光酮吸附富集光度法测定痕量钼

本工作研究了活性炭-水杨基荧光酮(SAF)对水中痕量钼(Ⅵ)的吸附和解吸条件,以及SAF在吸附过程中所起的作用,并采用分光光度法测定了天然水中痕量钼。     

α型硅钼蓝法测铝中硅的研讨

实验考察了影响硅钼蓝法结果重现性及准确性的因素；比较了α型硅钼蓝及β型硅钼蓝的异同、特点；提出了利用α型硅钼蓝法线性范围宽、稳定性好的优点，同时测定铸铝中高含量硅和铝合金中低含量硅的分析方法。