Two kinds of cyclodextrin/peptide (CD/peptide) hybrids bearing ZnII‐cyclen or cyclen, dansyl and β‐cyclodextrin (β‐CD) units have been synthesized as chemosensors for organic anionic molecules. ZnII‐cyclen serves as a ligand site and β‐CD is a receptor site for guest molecules, while the dansyl unit acts as a fluorescent probe. Examination of the fluorescence behaviors of these CD/peptides suggest that the hybrid containing Zn2+ has larger binding constants with respect to anionic molecules than that without Zn2+.
In the title compound, pentacyclo[11.8.1.13,11.07,23.015,20]tricosa‐3,5,7,9,11(23),15,17,19‐octaen‐22‐one, C23H20O, the bicyclo[5.4.1]dodecan‐12‐one moiety takes a rigid conformation in which the seven‐ and eight‐membered rings take chair and boat–boat forms, respectively. The molecule has a non‐crystallographic mirror symmetry perpendicular to the benzene and naphthalene planes. 相似文献
The β-NMR spectra of 21F, 23Mg, 27Si and 39Ca which were produced in heavy ion collisions and implanted in various crystals have been observed. The magnetic moments
of 21F and 27Si were determined to be |μ(21F)| = 3.9194 ± 0.0012 μN and |μ(27Si)| = 0.8653 ± 0.0003 μN, respectively. The electric quadrupole coupling constants were determined for the first time to be |eqQ(21F in MgF2)/h|= 9.94 ± 0.09 MHz, |eqQ(23Mg in MgF2)/h|= 1.96 ± 0.06 MHz, |eqQ(27Si in Al2O3)/h|= 1.90 ± 0.12 MHz, |eqQ(39Ca in CaCO3)/h|= 0.60 ± 0.04 MHz. From the present eqQ/h, the Q moments were deduced as |Q(21F)|= 110 ± 22 mb, |Q(23Mg)|= 114 ± 3 mb, |Q(27Si)|= 60 ± 13 mb and |Q(39Ca)|= 36± 7 mb. The present data were compared with the theoretical values obtained by the OXBASH shell model code.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
Hyperfine interactions of 12,14N in BN(hexagonal) crystal were studied by detecting β-NQR(12N) and FT-NMR(14N). A β-NMR of 16N (Iπ=2−,T1/2=7.13 s) in MgO crystal was detected to determine the magnetic moment of 16N to be |μ(16N:2−)|=(1.986±0.001)μN. Also, the β-NQR of 12,16N in TiO2 crystal were detected to determine |Q(16N:2−)|=(17.9±1.7) mb. An abnormally small effective charge for neutrons is required to account for |Q(16N:2−)|.
This revised version was published online in September 2006 with corrections to the Cover Date. 相似文献
1 Introduction The production of nuclear spin polarization and the maintenance of the nuclear po-larization in a stopper are the essential requirement for the measurement of nuclear magnetic and electric quadrupole moments of the b-emitting nuclei by the ?NMR and b-NQR (b-ray detected Nuclear Magnetic Resonance and b-ray detected Nuclear Quad-rupole Resonance) technique. This requirement can be realized by the selection tech-nique of the incident particle energy of the nuclear reaction th… 相似文献
An emission excitation source comprising a high-frequency diode-pumped Q-switched Nd:YAG laser and a radio-frequency powered glow discharge lamp is proposed. In this system sample atoms ablated by the laser irradiation are introduced into the lamp chamber and subsequently excited by the helium glow discharge plasma. The pulsed operation of the laser can produce a cyclic variation in the emission intensities of the sample atoms whereas the plasma gas species emit the radiation continuously. The salient feature of the proposed technique is the selective detection of the laser modulation signal from the rest of the continuous background emissions, which can be achieved with the phase sensitive detection of the lock-in amplifier. The arrangement may be used to estimate the emission intensity of the laser ablated atom, free from the interference of other species present in the plasma. The experiments were conducted with a 13.56 MHz radio-frequency (rf) generator operated at 80 W power to produce plasma and the laser at a wavelength of 1064 nm (pulse duration:34 ns, repetition rate:7 kHz and average pulse energy of about 0.36 mJ) was employed for sample ablation. The measurements resulted in almost complete removal of nitrogen molecular bands (N2+ 391.44 nm). Considerable reduction (about 75%) in the emission intensity of a carbon atomic line (C I 193.03 nm) was also observed. 相似文献
Ring transformation of 3-hydroxy-1,2,5-thiadiazole ( 1 ), 3-hydroxy-1,2,4-thiadiazole ( 14 ), and 3-hydroxyiso-thiazole ( 18 ) by the reaction with acetic anhydride in the presence of DBU afforded isothiazoles 2-5 and 13 , thiazoles 15 and 16 and thiophenes 21-25 , respectively. The reaction of 1 with propionic anhydride gave isothiazole 13 . The formation pathway of the products is mentioned. 相似文献
This paper reports unique and unusual formations of columnar liquid crystals and organogels by self-assembling discotic molecules, which are composed of an aromatic hexaazatriphenylene (HAT) core and six flexible aromatic side chains. In HAT derivatives 3a, with 4'-(N,N-diphenylamino)biphenyl-4-yl chains, 3b, with 4'-[N-(2-naphthyl)-N-phenylamino]biphenyl-4-yl chains, and 3c, with 4'-phenoxybiphenyl-4-yl chains, the two-dimensional hexagonal packings can be created by their self-assembling in the liquid crystalline phase, which were characterized by polarizing optical microscopy, differential scanning calorimetry, and X-ray diffraction analysis. In certain solvents, HAT molecules 3a-c can form the viscoelastic fluid organogels, in which one-dimensional aggregates composed of the HAT molecules are self-assembled and entangled into three-dimensional network structures. The organogel structures were analyzed by scanning electron microscopy observation, (1)H NMR, UV-vis, and circular dichroism spectroscopy. In contrast to 3a-c, none of the liquid crystalline and organogel phases could be formed from 3d and 3e with short aromatic side chains including a phenylene spacer, and 3f (except a few specific solutions) and 3g without terminal diarylamino and phenoxy groups. In 3a-c, the aromatic side chains with terminal flexible groups make up soft regions that cooperatively stabilize the liquid crystalline and organogel supramolecular structures together with the hard regions of the hexaazatriphenylene core. 相似文献
Beta-ray angular distributions from aligned12B and12N have been observed in order to study the meson-exchange effect in a nucleus. Alignment-correlation coefficients for12B and12N were determined to be –=–(0.0174±0.0059)%/MeV and +=–(0.2774±0.0086)%/MeV, respectively. These values are fairly consistent with the previous values, while the reliability was greatly improved. From these coefficients, the nuclear parametery, i.e. the ratio of the time component of the axial vector currents of the Gamow-Teller matrix element, was determined to bey=4.13±0.15. The value is enhanced by 33% from that calculated by use of the impulse approximation, which clearly shows a considerable effect due to meson-exchange currents. 相似文献
The nuclear quadrupole moment of8B(I=2+,T1/2=769 ms) has been determined by use of a modified -NMR detection as |Q(8B)|=68.3±2.1 mb, which is twice the prediction of the Cohen-Kurath shell model calculation. The anomalous quadrupole moment which is carried mainly by the protons in the nucleus, has been accounted for by the proton halo effect. 相似文献