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排序方式: 共有192条查询结果,搜索用时 31 毫秒
121.
S. Momota M. Mihara D. Nishimura M. Fukuda Y. Kamisho M. Wakabayashi K. Matsuta S. Suzuki M. Nagashima Shengyun Zhu Daqing Yuan Yongnan Zheng Zuo Yi Ping Fan T. Izumikawa A. Kitagawa S. Sato M. Kanazawa M. Torikoshi T. Minamisono Y. Nakamura K. Tashiro A. Honma N. Yoshida H. Shirai T. Ohtsubo T. Nagatomo H. Uenishi K. Iwamoto M. Yaguchi T. Ogura T. Ito K. Yamamura Y. Ichikawa Y. Nojiri J. R. Alonso T. J. M. Symons 《Hyperfine Interactions》2013,218(1-3):53-58
Hyperfine interactions were studied in the intermetallic compound GdRh2Si2 by perturbed angular correlation (PAC) technique using 181Hf(181Ta) probe nuclei. The measurements were performed in the temperature range 15–285 K. The PAC spectra above the antiferromagnetic ordering temperature of the GdRh2Si2 compound (T N ~ 106 K), were analyzed using a model that included only electric quadrupole interactions. The observed major fraction was assigned to the 181Hf(181Ta) probe substituting the Gd atoms. The PAC spectra below Néel temperature were analyzed using combined electric quadrupole and magnetic dipole interactions. The Bhf value at Gd, measured at 15 K was found to be 1.4(1) T which, is smaller, when compared with the values obtained in this compound using other nuclear probes, 155Gd (Bhf ~ 30 T) and 140Ce (Bhf ~ 26 T). The present result using 181Hf(181Ta) probe is quite interesting since it shows that the contribution to Bhf at Gd due the host is smaller than other components which contribute to the hyperfine field. The temperature dependence of Bhf shows an anomalous behavior. 相似文献
122.
Dr. Shuntaro Takahashi Hidemi Isobe Prof. Takuya Ueda Prof. Yoshio Okahata 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(21):6807-6816
Translation initiation is a dynamic and complicated process requiring the building a 70S initiation complex (70S‐IC) composed of a ribosome, mRNA, and an initiator tRNA. During the formation of the 70S‐IC, initiation factors (IFs: IF1, IF2, and IF3) interact with a ribosome to form a 30S initiation complex (30S‐IC) and a 70S‐IC. Although some spectroscopic analyses have been performed, the mechanism of binding and dissociation of IFs remains unclear. Here, we employed a 27 MHz quartz crystal microbalance (QCM) to evaluate the process of bacterial IC formation in translation initiation by following frequency changes (mass changes). IFs (IF1, IF2, and IF3), N‐terminally fused to biotin carboxyl carrier protein (bio‐BCCP), were immobilized on a Neutravidin‐covered QCM plate. By using bio‐BCCP‐IF2 immobilized to the QCM, three steps of the formation of ribosomal initiation complex could be sequentially observed as simple mass changes in real time: binding of a 30S complex to the immobilized IF2, a recruitment of 50S to the 30S‐IC, and formation of the 70S‐IC. The kinetic parameters implied that the release of IF2 from the 70S‐IC could be the rate‐limiting step in translation initiation. The IF3‐immobilized QCM revealed that the affinity of IF3 for the 30S complex decreased upon the addition of mRNA and fMet‐tRNAfMet but did not lead to complete dissociation from the 30S‐IC. These results suggest that IF3 binds and stays bound to ICs, and its interaction mode is altered during the formation of 30S‐IC and 70S‐IC and is finally induced to dissociate from ICs by 50S binding. This methodology demonstrated here is applicable to investigate the role of IFs in translation initiation driven by other pathways. 相似文献
123.
Feruloyl,caffeoyl, and flavonol glucosides from <Emphasis Type="Italic">Equisetum hyemale</Emphasis>
Feruloyl, caffeoyl, and flavonol glucosides were isolated from the stems of Equisetum hyemale L. The structures of the compounds were elucidated as trans-feruloyl-4-β-glucoside (1), cis-feruloyl-4-β-glucoside (2), trans-caffeoyl-3-β-glucoside (3), kaempferol-3-sophoroside (4), kaempferol-3-sophoroside-7-β-glucoside (5), and herbacetin-3-sophoroside-8-β-glucoside (6) based on the spectral evidence. 相似文献
124.
Emisson spectra and time-resolved two-dimensional (2D) emission images of the electron-ion dielectronic recombination (i.e. a reversal process of auto-ionization) line of neutral Cu atoms, the selectively excited Cu ionic line, and normal Cu atomic line were observed for understanding the excitation mechanisms of Cu neutral and ionic lines in a low-pressure laser-induced plasma (LP-LIP) of Ar. From the observations, the number of charged particles around the emitting species seems to increase with increasing Ar pressure. Different time-resolved 2D emission images were observed among the selectively excited Cu ionic line and other Cu emission lines resulting from the different excitation mechanisms of the respective emission lines. Collisions of the second kind and electron-ion recombinations were found to be one of the major excitation mechanisms of Cu in Ar LP-LIP. 相似文献
125.
A novel emission excitation source comprising a high repetition rate diode-pumped Q-switched Nd:YAG laser and a Grimm-style glow-discharge lamp is described. Laser-ablated atoms are introduced into the He glow discharge plasma, which then give emission signals. By using phase-sensitive detection with a lock-in amplifier, the emission signal modulated by the pulsed laser can be detected selectively. It is possible to estimate only the emission intensity of sample atoms ablated by laser irradiation with little interference from the other species in the plasma. 相似文献
126.
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128.
Masaoki Oku Toetsu ShishidoHideyuki Matsuta Kazuaki Wagatsuma 《Journal of Electron Spectroscopy and Related Phenomena》2006
The background corrected valence band XPS spectra and the electronic structures of FeAl, FeSi, CoAl and CoSi were studied. Clean surfaces of the polycrystalline samples were obtained by in situ fracturing of the samples in an XPS spectrometer. The energy loss parts of the Fe 2p, Co 2p and valence band spectra were removed by the deconvolution method using Al 2s or Si 2s spectra as response functions. CoAl exhibited a satellite peak in the Co 2p region, but the other compounds had no clear satellite peaks in the Co 2p and Fe 2p regions. The experimentally background corrected valence band spectra were compared with the calculated spectra using the first-principle band calculation. There were large discrepancies between the spectra above the binding energy of 5 eV. These indicated that the experimental spectra could not be explained by the electronic structures of the ground states alone. 相似文献
129.
Taisuke Matsumoto Masataka Watanabe Tomohiro Matsumoto Shuntaro Mataka Thies Thiemann 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(11):o813-o814
In the title compound, C33H35NO2, the five‐membered ring adopts a half‐chair conformation. The N‐methyl‐N‐phenyl‐substituted keto–enamine moiety shows a comparatively long Csp2—N bond. 相似文献
130.
K. Minamisono K. Matsuta T. Minamisono C. D. P. Levy T. Nagatomo M. Ogura T. Sumikama J. A. Behr K. P. Jackson H. Fujiwara M. Mihara M. Fukuda 《Hyperfine Interactions》2004,159(1-4):261-264
Hyperfine interactions of Na isotopes in single crystals have been studied using highly nuclear polarized 20,21,26,27,28Na beams provided by ISAC/TRIUMF. The degree of polarization kept in the crystals, the spin-lattice relaxation times, the
electric quadrupole coupling constants and the initial distribution of the populations were measured. Such knowledge is indispensable
for the application of the hyperfine interactions in the study of precision measurements such as the nuclear structure through
nuclear moments and the fundamental symmetries. 相似文献