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801.
802.
A phenomenological theory is presented to extend the method of reduced variables for the effects of both temperature and changing degree of crystallinity on the linear viscoelastic properties of solutions of crystalline polymers. The vertical and the horizontal shift factors, which are both obtainable in the course of analysis of the experimental data, are correlated with the concentration of the solution and the volume fraction of the crystalline phase, and the fractional free volume of the system, respectively. Dynamic mechanical properties of a gel of cellulose nitrate (nitrogen content, 12.6%) in diethyl phthalate with a nominal concentration of 18% by weight were obtained in the transition region from glasslike to rubberlike consistency and also in the rubbery plateau region by employing the Fitzgerald apparatus and a freely oscillating torsion pendulum over the temperature range from ?49 to 65°C. Application of the new reduction method to the experimental data was found to be quite successful, and it was shown that in general the degree of crystallinity in the system (and hence also the concentration of polymer in the amorphous phase) can depend on both temperature and thermal history. The dynamic mechanical data of a gel of different nominal concentration (23% by weight) previously obtained by Plazek were reanalyzed in terms of the method herein given. 相似文献
803.
Nobukimi Ohashi Masao Kakimoto Shuji Saito Eizi Hirota 《Journal of Molecular Spectroscopy》1980,84(1):204-224
The vibronic transition (16 370 to 16 425 cm?1) of the DSO radical in studied by Doppler-limited dye laser excitation spectroscopy. DSO is produced in a flow system by reacting the products of a microwave discharge in O2 with D2S. About 637 observed lines are assigned to 987 transitions of the 19 subbands: K′a ← K″a = 6 ← 5, 5 ← 4, 4 ← 3, 3 ← 2, 2 ← 1, 1 ← 0, 0 ← 1, 1 ← 2, 2 ← 3, 3 ← 4, 0 ← 0, 1 ← 1, 2 ← 2, 3 ← 3, 4 ← 4, 3 ← 1, 2 ← 0, 0 ← 2, and 1 ← 3. They are analyzed to determine rotational constants, centrifugal distortion constants, and spin-rotation constants for both the ground and the excited electronic states. The band origin obtained is 16 413.874 (2.5σ = 0.002) cm?1. The rotational constants determined are combined with the previous result on HSO (M. Kakimoto et al., J. Mol. Spectrosc.80, 334–350 (1980)) to calculate the structural parameters for this radical in both the states: , , and ∠HSO = 106.6(5)° for the state, and , , and ∠HSO = 95.7(21)° for the state, where values in parentheses denote 2.5σ. 相似文献
804.
A multi-quantum-well (MQW) active layer has been introduced to 1.3-μm GaInAsP/InP surface-emitting (SE) lasers. Room temperature pulsed operation of a 1.3-μm MQW SE laser was obtained for the first time and its threshold current was 15 mA. CW (continuous wave) operation up to 7°C (threshold current 1th=7.6 mA at 7°C) was achieved. 相似文献
805.
H. Ninomiya H. F. Weinberger 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2003,262(1):869-873
We present an example of a predator-prey-like system
with a prey-only state as a global attractor, and with the
additional property that an attempt to control the prey by
harvesting or poisoning both species produces solutions in which
both populations blow up in finite time. 相似文献
806.
Glutathione sulfhydryl oxidase is immobilized on oxirane-acrylic beads (Eupegit-C) and packed in a small column. The simple system for glutathione comprises the immobilized enzyme column and a flow-through membrane-covered platinum/silver/silver chloride electrode pair for detection of hydrogen peroxide. The calibration graph for glutathione was linear from 0.05 to 1.0 mM for 200-μl samples. The assay took 3 min. The relative standard deviation for 0.5 mM glutathione was 2% (n=10). 相似文献
807.
808.
Kazuo Yamaura Kohsei Hirata Satoko Tamura Shuji Matsuzawa 《Journal of Polymer Science.Polymer Physics》1985,23(8):1703-1712
The dilute-solution behavior of poly(vinyl alcohol) (PVAVTFA), derived from vinyl trifluoroacetate, in water-dimethylsulfoxide (DMSO) mixtures was investigated. With solvent mixtures ranging from 10 to 20 vol % DMSO, the relation between the reduced viscosity ηsp/C and the polymer concentration C was linear for polymer concentrations above 0.2 g/dL, whereas in solutions in mixed solvents of other compositions the dependence was linear for polymer concentrations above 0.1 g/dL. The relation between the intrinsic viscosity [η] obtained for aqueous solutions of PVAVTFA and the molecular weight M estimated from viscosity measurements in solutions of poly(vinyl acetate) (PVAVTFA), obtained by acetylation of PVAVTFA, was given by [η] = 7.34 × 10?4 M0.63. The value of [η] was greatest for the solvent mixture with 10 vol % DMSO and smallest for about 50 vol % DMSO, and Huggins constants k were smallest and greatest for these two cases, respectively. The turbidity of the solutions of low-molecular-weight PVAVTFA, was higher than that of high-molecular-weight PVAVTFA up to 30 vol % DMSO, and the reverse relation held for 40-70 vol % DMSO. 相似文献
809.
810.