Die Wechselwirkung zwischen synthetischen Polymeren und Netzmitteln

Zusammenfassung Die Polyelektrolyten (Polyakryls?ure, Carboxymethylzellulose, K-Polyvinylsulfat) verhalten sich bei Zusatz gleichnamig geladener Netzmittel anders als bei Zusatz des einfachen Salzes, was durch die Analogie der Wechselwirkung zwischen Netzmittel und nichtionischen Polymeren wie Polyvinylalkohol zu erkl?ren ist.     

Determination of beta-carbolines in foodstuffs by high-performance liquid chromatography and high-performance liquid chromatography-mass spectrometry

A high-performance liquid chromatographic method combined with fluorimetric detection is described for the determination of beta-carboline (norharman) and 1-methyl-beta-carboline (harman). The analysis of foodstuffs for the identification of beta-carbolines is facilitated by clean-up samples using Bond Elut PRS cartridges. Recoveries were excellent. Further, a high-performance liquid chromatographic-mass spectrometric method was also developed for their identification. The concentration of beta-carboline among the foodstuffs and alcoholic beverages varied greatly. Also, norharman and harman were observed in uncooked foodstuffs, whereas acetaldehyde was found in most fermented food. The toxicological implication of beta-carbolines in foodstuffs is discussed.     

On interior regularity criteria for weak solutions of the navier-stokes equations

We are concerned with the behavior of weak solutions of the Navier-Stokes equations near possible singularities. We shall show that if a weak solution is in some Lebesgue space or small in some Lorentz space locally, it does not blowup there. Our basic idea is to estimate integral formulas for vorticity which satisfies parabolic equations.     

The intermediate weak boson and weak interactions at high energy

The high-energy pire-leptonic weak interaction is investigated based on the assumption of the existence of a charged vector boson which mediates the weak processes. With the aid of the fixed-t dispersion relation the following relation is obtained: The weak boson mass m_W should satisfy $\text{m}{}_{\mathrm{<mtext>W</mtext>}}\text{? G}{}^{\mathrm{<mtext>?</mtext><mtext>1</mtext><mtext>2</mtext>}}$, with G the Fermi coupling constant, if the asymptotic value of the cross section becomes of the order of the strong interaction in the energy region observable in cosmic rays, etc.The scattering processes $\text{e}\text{+ν→}\text{e}\text{+ν}\text{and}\text{e}\text{+}\text{ν}\text{→}\text{e}\text{+}\text{ν}$ are examined by the aid of the N/D method. For a large vector-boson mass $\text{m}{}_{\mathrm{<mtext>W</mtext>}}\text{?100}\text{GeV}$, an S-wave resonance should exist for the process e+ν→e+ν while for $\text{e}\text{+}\text{ν}\text{→}\text{e}\text{+}\text{ν}$ there should exist a P-wave resonance which corresponds to the intermediate weak boson. The neutral current is then estimated. It is shown that the neutral current produced as a higher-order effect is not inconsistent with the present experiments on the pure-leptonic weak interaction if m_W?1 TeV.     

Magic number 7+/-2 in networks of threshold dynamics

Information processing by random feed-forward networks consisting of units with a sigmoidal input-output response is studied by focusing on the dependence of its outputs on the number of parallel paths M. It is found that the system leads to a combination of on-off outputs when M less or similar to 7, while for M greater or similar to 7, chaotic dynamics arises, resulting in a continuous distribution of outputs. This universality of the critical number M approximately 7 is explained by a combinatorial explosion, i.e., the dominance of factorial over exponential increase. The relevance of the result to biological problems is briefly discussed.     

Structural analysis of sonochemically prepared Au/Pd nanoparticles dispersed in porous silica matrix

Bimetallic Au/Pd nanoparticles supported on a silica matrix were prepared by an ultrasonic technique. The samples heat-treated at 100, 200, 300 and 400 degrees C were examined with techniques of XRD (X-ray diffraction), TEM and XAS (X-ray absorption spectrometry) for studying correlation between their structure and the catalytic activity of hydrogenation of cyclohexene. Even after the heat treatment at 400 degrees C, the particles were smaller than 20 nm and well dispersed in the matrix without agglomeration nor sintering. Results of the XRD, TEM and XAS indicated that the as-prepared particles have a core/shell structure of Au/Pd and transform into a random alloy at 300 degrees C. The catalysis seemed to be deactivated by alloying.     

The SAAP force field. A simple approach to a new all-atom protein force field by using single amino acid potential (SAAP) functions in various solvents

A simple strategy to compose a new all-atom protein force field (named as the SAAP force field), which utilizes the single amino acid potential (SAAP) functions obtained in various solvents by ab initio molecular orbital calculation applying the isodensity polarizable continuum model (IPCM), is presented. We considered that the total energy function of a protein force field (E(TOTAL)) is divided into three components; a single amino acid potential term (E(SAAP)), an interamino acid nonbonded interaction term (E(INTER)), and a miscellaneous term (E(OTHERS)), which is ignored (or considered to be constant) at the current version of the force field. The E(INTER) term consists of electrostatic interactions (E(ES')) and van der Waals interactions (E(LJ')). Despite simplicity, the SAAP force field implicitly involves the correlation among individual terms of the Lifson's potential function within a single amino acid unit and can treat solvent effects unambiguously by choosing the SAAP function in an appropriate solvent and the dielectric constant (D) of medium. Application of the SAAP force field to the Monte Carlo simulation of For-Ala(2)-NH(2) in vacuo reasonably reproduced the results of the extensive conformational search by ab initio molecular orbital calculation. In addition, the preliminary Monte Carlo simulations for For-Gly(10)-NH(2) and For-Ala(10)-NH(2) showed reversible transitions from the extended to the pseudosecondary structures in water (D = 78.39) as well as in ether (D = 4.335). The result suggested that the new approach is efficient for fast modeling of protein structures in various environments. Decomposition analysis of the total energy function (E(TOTAL)) by using the SAAP force field suggested that conformational propensities of single amino acids (i.e., the E(SAAP) term) may play definitive roles on the topologies of protein secondary structures.