全文获取类型
收费全文 | 844篇 |
免费 | 30篇 |
国内免费 | 23篇 |
专业分类
化学 | 640篇 |
晶体学 | 7篇 |
力学 | 6篇 |
数学 | 46篇 |
物理学 | 198篇 |
出版年
2023年 | 5篇 |
2022年 | 6篇 |
2021年 | 7篇 |
2020年 | 12篇 |
2019年 | 6篇 |
2018年 | 7篇 |
2017年 | 8篇 |
2016年 | 15篇 |
2015年 | 18篇 |
2014年 | 16篇 |
2013年 | 56篇 |
2012年 | 41篇 |
2011年 | 47篇 |
2010年 | 19篇 |
2009年 | 15篇 |
2008年 | 62篇 |
2007年 | 58篇 |
2006年 | 64篇 |
2005年 | 51篇 |
2004年 | 45篇 |
2003年 | 39篇 |
2002年 | 34篇 |
2001年 | 17篇 |
2000年 | 16篇 |
1999年 | 19篇 |
1998年 | 10篇 |
1997年 | 9篇 |
1996年 | 12篇 |
1995年 | 10篇 |
1994年 | 6篇 |
1993年 | 4篇 |
1992年 | 11篇 |
1991年 | 6篇 |
1990年 | 10篇 |
1989年 | 6篇 |
1988年 | 8篇 |
1987年 | 5篇 |
1986年 | 7篇 |
1985年 | 15篇 |
1984年 | 13篇 |
1983年 | 9篇 |
1982年 | 9篇 |
1981年 | 9篇 |
1980年 | 6篇 |
1979年 | 12篇 |
1978年 | 6篇 |
1977年 | 4篇 |
1976年 | 4篇 |
1973年 | 3篇 |
1954年 | 2篇 |
排序方式: 共有897条查询结果,搜索用时 93 毫秒
111.
112.
113.
The J = 1 ← 0 and J = 2 ← 1 transitions and the l-doubling transitions of J = 2 – 6 of 12CH3F in the ν2 and ν5 states were analyzed by taking into account the Coriolis interaction between the two modes. The molecular constants which are derived are: ν5 - ν2, 252 412 ± 112; , 25 611.60 ± 0.40; Aζ5, ?38 772 ± 116; , 25 432.52 ± 0.33; D, 21 838.4 ± 8.2; , 39.58 ± 0.30 MHz; in addition to a few other minor constants. The present result is completely consistent with the recent Raman data of Escribano, Mills, and Brodersen, J. Mol. Spectrosc.61, 249 (1976). Molecular constants in the ν3 and ν6 states have also been obtained: B3, 25 197.570 ± 0.020; B6, 25 418.917 ± 0.047; Aζ6ηJ, ?0.562 ± 0.030; |q6|, 8.70 ± 0.13 MHz. Errors are 2.5 times the standard deviations. 相似文献
114.
The cw dye laser excitation spectrum of the
vibronic transition of the HSO radical was observed between 16 420 and 16 520 cm−1 with Doppler-limited resolution, 0.03 cm−1. The HSO radical was produced by reaction of discharged oxygen with H2S or CH3SH. The observed spectra were assigned to 751 transitions of the K′a ← K″a = 2 ← 3, 1 ← 2, 0 ← 1, 1 ← 0, 2 ← 1, and 3 ← 2 subbands, and were analyzed to determine rotational constants, centrifugal distortion constants, and spin-rotation interaction constants with good precision. The signs of the spin-rotation interaction constants were determined for both the upper and the lower state from the observed spectra. The band origin obtained is 16 483.0252 (2.5σ = 0.0013) cm−1. The molecular constants which were determined reproduce the observed transitions with an average deviation of 0.0045 cm−1. 相似文献
115.
116.
Mitsutoshi Tanimoto Shuji Saito Yasuki Endo Eizi Hirota 《Journal of Molecular Spectroscopy》1983,100(1):205-211
The microwave spectrum of the SiF radical was observed in both and of the ground vibronic state. The SiF radical was produced by a dc discharge either in a mixture or in a transient molecule SiF2 generated by the reaction of SiF4 with heated solid silicon. The latter gave twice as intense a spectrum. A least-squares fit to the observed spectrum showed the rotational constant and the centrifugal distortion constant to be 17 350.2752(63) and 0.03188(13) MHz, respectively, with three standard errors in parentheses applying to the last digits of the constants. The lambda-doubling parameter p0 was found to be negative, ?87.67 MHz, indicating that the 2Σ+ excited state contributions dominate over those of 2Σ?. All four hyperfine coupling constants a, b, c, and d were determined and were employed to discuss the unpaired-electron spin and orbital distributions in the SiF radical. 相似文献
117.
118.
Akihiro Fukabori Takayuki Yanagida Federico Moretti Yuui Yokota Rayko Shimura Shuji Maeo Jan Pejchal Kei Kamada Akira Yoshikawa 《Radiation measurements》2010,45(3-6):453-456
Micro-pulling down (μ-PD) method allows to prepare single crystals quickly and relatively inexpensively. Since it is a melt growth and taking into account segregation phenomena, the μ-PD method allows also to obtain single crystals characterized by dopant concentration gradients. Especially, taking the advantage of the grown crystal high aspect ratio, it allows to prepare crystalline samples with variable and wide range concentrations of dopants. These samples can help in understanding the correlation between dopant concentration and luminescence properties. 相似文献
119.
This paper introduces a miniaturized microphone array using the Directionally Constrained Minimization of Power (DCMP) method, which utilizes the transfer functions of microphones located at the same place, namely aggregated microphones. The phased microphone array realizes a noise reduction and direction of arrival (DOA) estimation system according to differences in the arrival time, phase shift, and/or the level of the sound wave for each microphone. Hence it is difficult to miniaturize the microphone array. The objective of our research is to miniaturize the system size using aggregated microphones. In this paper, we first show that the phased microphone array system and the proposed aggregated microphone system can be described within the same framework. We then apply a microphone array under directional constraint to the aggregated microphones and compare the proposed method with the microphone array. We show the directional pattern of the aggregated microphones. We also show the experimental results regarding DOA estimation. 相似文献
120.
Stable 10 W Er:ZBLAN fiber laser operating at 2.71-2.88 μm 总被引:1,自引:0,他引:1
We have developed a diode-pumped tunable 3 μm fiber laser with a cw output power of the order of 10 W with the use of an erbium-doped ZBLAN fiber. A tunability range of 110 nm (2770 to 2880 nm) with an output power between 8 and 11 W was demonstrated. As the pump power was increased, the center of the wavelength range was shifted toward longer wavelengths, but the width of the wavelength range was largely unaffected. The total tunability range for various pump power levels was 170 nm (2710 to 2880 nm). To our knowledge, this is the highest performance (output power and tunability) obtained from a tunable 3 μm fiber laser. 相似文献