Synthesis of 9α,11α-thiathromboxane A2 methyl ester

The synthesis of thromboxane A₂ (TXA) analogue, 9α,11α-thia-TXA₂ methyl ester $\text{2}$, in which the oxygen atom in the oxetane ring of TXA₂ was replaced by a sulfur atom, is described.     

A matroid generalization of theorems of Lewin and Gallai

This paper presents a theorem concerning a matroid with the parity condition. The theorem provides matroid generalizations of graph-theoretic results of Lewin and Gallai.     

Counting the number of distinct real roots of certain polynomials by Bezoutian and the Galois groups over the rational number field

In this article, we count the number of distinct real roots of certain polynomials in terms of Bezoutian form. As an application, we construct certain irreducible polynomials over the rational number field which have given number of real roots and by the result of Oz Ben-Shimol [On Galois groups of prime degree polynomials with complex roots, Algebra Disc. Math. 2 (2009), pp. 99–107], we obtain an algorithm to construct irreducible polynomials of prime degree p whose Galois groups are isomorphic to S _p or A _p .     

Lipase‐Catalyzed transformation of Poly(trimethylene carbonate) into Cyclic Monomer,Trimethylene Carbonate: A New Strategy for Sustainable Polymer Recycling Using an Enzyme

The enzymatic degradation and polymerization using an enzyme were carried out with respect to the establishment of a sustainable chemical recycling system for poly(trimethylene carbonate) [P(TMC)] which is a potentially biodegradable synthetic plastic. The enzymatic transformation of P(TMC)s having an M_n of 3000~48000 using Candida antarctica lipase (lipase CA) in acetonitrile at 70 °C afforded the corresponding cyclic monomer, trimethylene carbonate (TMC: 1,3‐dioxan‐2‐one), in a yield of up to 80%. Thus obtained TMC readily polymerized again using both fresh lipase CA and recovered lipase CA.     

Chain-growth polycondensation of potassium 3-cyano-4-fluorophenolate derivatives for well-defined poly(arylene ether)s

Polycondensation normally proceeds in a step-growth reaction manner to give polymers with a wide range of molecular weights. However, the polycondensation of potassium 2-alkyl-5-cyano-4-fluorophenolate ( 1 ) proceeded at 150°C in a chain polymerization manner from initiator, 4-fluoro-4′-trifluoromethyl benzophenone ( 2 ), to give aromatic polyethers having controlled molecular weights and low polydispersities (M_w/M_n ⩽ 1.2). The resulting polycondensation of 1 had all of the characteristics of living polymerization and displayed a linear correlation between molecular weight and monomer conversion, maintaining low polydispersities. Sulfolane was a better solvent for chain-growth polycondensation of 1 than other aprotic solvents. The polyether from 1 with a low polydispersity showed higher crystallinity than that with a broad molecular weight distribution, obtained by the conventional polycondensation of 1 without 2 .