全文获取类型
收费全文 | 707篇 |
免费 | 16篇 |
专业分类
化学 | 564篇 |
晶体学 | 18篇 |
力学 | 10篇 |
数学 | 33篇 |
物理学 | 98篇 |
出版年
2023年 | 2篇 |
2021年 | 8篇 |
2020年 | 9篇 |
2019年 | 12篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 14篇 |
2015年 | 10篇 |
2014年 | 10篇 |
2013年 | 33篇 |
2012年 | 37篇 |
2011年 | 32篇 |
2010年 | 35篇 |
2009年 | 36篇 |
2008年 | 54篇 |
2007年 | 46篇 |
2006年 | 38篇 |
2005年 | 51篇 |
2004年 | 36篇 |
2003年 | 42篇 |
2002年 | 28篇 |
2001年 | 7篇 |
2000年 | 11篇 |
1999年 | 6篇 |
1998年 | 8篇 |
1997年 | 4篇 |
1996年 | 6篇 |
1995年 | 6篇 |
1994年 | 3篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 10篇 |
1982年 | 8篇 |
1981年 | 11篇 |
1980年 | 11篇 |
1979年 | 10篇 |
1978年 | 5篇 |
1977年 | 8篇 |
1976年 | 9篇 |
1975年 | 2篇 |
1974年 | 6篇 |
1973年 | 3篇 |
排序方式: 共有723条查询结果,搜索用时 15 毫秒
61.
Yoshiaki Nakamoto Isao Karube Seikichi Terawaki Shuichi Suzuki 《Applied biochemistry and biotechnology》1976,1(2):143-149
Collagen fibrils were modified with β-l-[3,3-dimethyl-6′-nitrospiro-(indoline-2,2′-2H-benzopyran)] propionic anhydride. The spiropyran collagen membrane showed reverse photochromism. Lactate dehydrogenase (LDH, E.C. 1.1.1.27) was entrapped in the spiropyran collagen membrane. The activity of the LDH-spiropyran collagen membrane decreased under visible-light irradiation, and then increased again after incubation in the dark. The optimum pH of the LDH-spiropyran collagen membrane was displaced toward lower pH values under visible-light irradiation. The activity change of the LDH-spiropyran collagen membrane under visible-light irradiation depended on the LDH content. 相似文献
62.
Kaihara S Osanai Y Nishikawa K Toshima K Doi Y Matsumura S 《Macromolecular bioscience》2005,5(7):644-652
The enzymatic transformation into an oligomer was carried out with the objective of developing the chemical recycling of bacterial polyesters. Poly(R-3-hydroxyalkanoate)s (PHAs), such as poly[(R-3-hydroxybutyrate)-co-12%(R-3-hydroxyhexanoate)] and poly[(R-3-hydroxybutyrate)-co-12%(R-3-hydroxyvalerate)], were degraded by granulated Candida antarctica lipase B immobilized on hydrophilic silica (lipase GCA) in a diluted organic solvent at 70 degrees C. The degradation products were cyclic oligomers having a molecular weight of a few hundreds. The obtained cyclic oligomer was readily repolymerized by the same lipase (lipase GCA) to produce the corresponding polyester in a concentrated solution. The cyclic oligomer was copolymerized with epsilon-caprolactone using lipase to produce the corresponding terpolymers having an Mw of 21,000. This is the first example of the enzymatic chemical recycling of bacterial PHAs using lipase. Poly(R-3-hydroxybutyrate) [P(3HB)] was also degraded into the linear-type R-3HB monomer to trimer by P(3HB)-depolymerase (PHBDP) in phosphate buffer at 37 degrees C. The degradation using PHBDP required a longer reaction time compared with the lipase-catalyzed degradation in organic solvent. The monomer composition of the oligomer depended on the origin of the PHBDP. The R-3HB monomer was predominately produced by PHBDP from Pseudomonas stutzeri, while the R-3HB dimer was produced by PHBDP from Alcaligenes faecalis T1. Repolymerization of these oligomers by lipase in concentrated organic solvent produced a relatively low-molecular-weight P(3HB) (e.g., Mw=2,000). Degradation of P(3HB) by lipase in organic solvent into repolymerizable cyclic oligomer and degradation of P(3HB) by PHBDP in buffer into hydroxy acid type R-3HB dimer. 相似文献
63.
Yusuke Arai Tetsuji Yano Shuichi Shibata 《Journal of Sol-Gel Science and Technology》2004,32(1-3):189-194
Microspheres of refractive index of nD > 2.0 have been investigated. The organic-inorganic hybrid microspheres of nD = 1.72 were prepared by the vibrating orifice technique using titanium-tetra-n-butoxide (TTBu) and diphenyldimethoxysilane (DPhDMS). For lasing demonstration, Eu3+-doped microspheres were prepared using europium (III) thenoyltrifluoroacetonate [Eu(TTFA)3] as the dopant. The particles have good spherical shape, smooth surface and high optical transparency. The diameters of the particles could be controlled to within 0.1 m. Subsequent heating of the microspheres at 550°C under oxygen atmosphere resulted in an increase in the refractive index up to nD = 2.6 with retention of the spherical shape. Resonant emission was confirmed from Eu3 +-doped microspheres after heating at 400–550°C, by pumping with the 514.5 nm line of a CW- Ar+laser. 相似文献
64.
Electric polarization in insulators is represented by the transferred charge through a shift of the Bloch wave functions induced by an adiabatic change of external parameters Q-->. It is found that this covalent/quantum contribution is determined nonlocally by the topological structure in the Q--> space. The condition for the charge pumping for a cyclic change of Q--> is also obtained. Applications of this picture to various organic ferroelectrics and BaTiO3 are discussed. 相似文献
65.
Kato S Matsumoto T Ishi-i T Thiemann T Shigeiwa M Gorohmaru H Maeda S Yamashita Y Mataka S 《Chemical communications (Cambridge, England)》2004,(20):2342-2343
Novel donor-pi-bridge-acceptor-pi-bridge-donor (D-pi-A-pi-D) type 2,1,3-benzothiadiazole fluorescent dyes connected to the N,N-diarylamino terminus via various type pi-conjugate spacers exhibits large two-photon absorption cross-sections and high fluorescent quantum yields in orange-red color. 相似文献
66.
Chiba JY Tanaka K Ohshiro Y Miyake R Hiraoka S Shiro M Shionoya M 《The Journal of organic chemistry》2003,68(2):331-338
This paper describes a convenient synthetic procedure for nucleoside mimics, 1-6, in which the 3',5'-hydroxy groups of natural 2'-deoxythymidine or 2'-deoxyadenosine are replaced by thiol, amine, or alkylthiol groups. Such nucleosides would be built up into a single DNA strand with cooperative participation of metal coordination, where internucleoside linkages are replaced by metal complexation motifs. The X-ray crystal structure and complexation behaviors of 3',5'-dithiothymidine, 1, with Au(I) are also reported. 相似文献
67.
Huh D Tkaczyk AH Bahng JH Chang Y Wei HH Grotberg JB Kim CJ Kurabayashi K Takayama S 《Journal of the American Chemical Society》2003,125(48):14678-14679
This work is the first demonstration of electrical modulation of surface energy to reversibly switch dynamic high-speed gas-liquid two-phase microfluidic flow patterns. Manipulation of dynamic two-phase systems with continuous high-speed flows is complex and interesting due to the multiple types of forces that need to be considered. Here, distinct stable flow patterns are formed through a multipronged approach: both surface tension forces generated by surface chemistry modulation as well as viscous and inertial forces produced by fluid flows are employed. The novel fluidic actuation mechanism provides insights into better understanding microscale two-phase flow dynamics and offers new opportunities for the development of two-phase biochemical microsystems that are mechanically simple and operational at high speeds. 相似文献
68.
Shuichi Kawashima 《Journal of Differential Equations》2008,244(12):3151-3179
In the present paper, we investigate the large-time behavior of the solution to an initial-boundary value problem for the isentropic compressible Navier-Stokes equations in the Eulerian coordinate in the half space. This is one of the series of papers by the authors on the stability of nonlinear waves for the outflow problem of the compressible Navier-Stokes equations. Some suitable assumptions are made to guarantee that the time-asymptotic state is a nonlinear wave which is the superposition of a stationary solution and a rarefaction wave. Employing the L2-energy method and making use of the techniques from the paper [S. Kawashima, Y. Nikkuni, Stability of rarefaction waves for the discrete Boltzmann equations, Adv. Math. Sci. Appl. 12 (1) (2002) 327-353], we prove that this nonlinear wave is nonlinearly stable under a small perturbation. The complexity of nonlinear wave leads to many complicated terms in the course of establishing the a priori estimates, however those terms are of two basic types, and the terms of each type are “good” and can be evaluated suitably by using the decay (in both time and space variables) estimates of each component of nonlinear wave. 相似文献
69.
The synergic extraction of lanthanoids has been investigated using mixtures of high molecular weight beta-diketone, LIX 54 (HA; major component, 1-phenyl-3-isoheptyl-1,3-propanedion) and bidentate neutral ligands (S) in toluene. The distribution behavior of bidentate amines (2,2'-bipyridine (bpy), 1,10-phenanthroline (phen) and 2,9-dimethyl-1,10-phenanthroline (dmp)) was investigated and their related equilibrium constants were evaluated. The synergic effect is produced by the formation of such adduct complexes as MA3 x S. The extraction constants with LIX 54 alone and those in the presence of bidentate ligands were determined for lanthanoid-series elements. 相似文献
70.
Shuichi Nakamura Masashi Hayashi Yasutoshi Kamada Ryosuke Sasaki Yuichi Hiramatsu Norio Shibata Takeshi Toru 《Tetrahedron letters》2010,51(29):3820-3823
A catalytic enantioselective desymmetrization of meso-N-(heteroarenesulfonyl)aziridines with TMSN3 using chiral Lewis acids afforded products with high enantioselectivity. As proof of the utility of this procedure, the precursor of selective κ-opioid agonist (1S,2S)-(−)-U-50,488 was synthesized. 相似文献