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71.
黑土有机质含量野外高光谱预测模型 总被引:11,自引:0,他引:11
以田间原状黑土野外实测高光谱反射率为研究对象,分析黑土有机质的光谱响应波段,运用光谱分析方法提取光谱指数,建立基于反射光谱特征的黑土有机质高光谱预测模型。得出如下结论:(1)黑土反射光谱特征差异主要在小于1 250 nm的光谱范围,尤其是在小于1 100 nm的范围,随着有机质含量的变化,该波谱范围内黑土反射光谱特征呈现单/双谷现象,有机质是影响黑土反射光谱特征的决定因素。(2)有机质与黑土反射率倒数对数微分的相关系数最高,最高值在1 260 nm,达到-0.77(R2),相关系数高的波谱范围为750~1 260 nm。(3)基于黑土野外光谱反射率的有机质含量高光谱预测模型稳定性强,预测能力较好,能够用于黑土有机质含量野外速测。 相似文献
72.
Ji-Guang Li Yu-Feng Hu Shu-Feng Sun Yan-Sheng Liu Zhi-Chang Liu 《The Journal of chemical thermodynamics》2010,42(7):904-908
Densities and viscosities were measured for pure ionic liquid [C6mim][Br] (1-hexyl-3-methylimidazolium bromide) and the binary system (water + [C6mim][Br]) at 0.1 MPa and in the (293.15 to 333.15) K range. The excess molar volume and viscosity deviation were calculated and correlated by Redlich–Kister polynomial expansions. The fitting parameters and the standard deviations were determined. 相似文献
73.
在高分辨率(ΔE=08?eV,Δp≈01a.u.)高效率的第三代电子动量谱仪上获得了N2价轨道的电离能谱和动量谱.通过对伴线结构的电子动量谱学(EMS)研究,得到了不同伴线结构的电子动量谱,另一方面也得到了伴线结构的强度.由伴线的电子动量分布形状判断出其跃迁的主要来源,并由实验测量的伴线结构强度确定了谱因子(极强度)的大小,通过对谱因子实验值与理论计算结果的比较检验了各种理论模型的精确度.
关键词:
氮分子
价轨道
电子动量谱
电子关联效应 相似文献
74.
在介质阻挡放电中,对放电丝结构从四边形向四边形格子态结构转变中的缺陷进行了研究.实验发现,在四边形向四边形格子态结构的转化中,存在两种缺陷:角缺陷及错位缺陷.为了研究缺陷的形成机理,实验测量了四边形格子态结构中不同放电丝的发光信号,结果发现八边形晶胞的中心放电丝发光强度强于边缘放电丝发光强度.通过引入准势场,研究了放电丝之间的相互作用及其对放电丝结构转变的影响,并由此分析了在转变过程中出现的缺陷,结果与实验符合得很好.
关键词:
介质阻挡放电
角缺陷
错位缺陷
超四边格子态 相似文献
75.
利用新一代高性能(e,2e)电子动量谱仪,在400-2400 eV的大范围入射电子能量条件下,测量了乙烯分子电子密度的动量分布.实验测量的乙烯1b3g轨道电子动量分布与平面波冲量近似的理论计算结果相比,在低动量区和高动量区出现明显的上翘(turn up)效应,并且此上翘效应随着入射电子能量的增加而逐渐减小.进一步的分析证实由于分子的扭曲波效应引起1b3g轨道动量分布在低动量区和高动量区的上翘.实验测量结果将对分子扭曲波理论计算的建立提供实验依据. 相似文献
76.
LI Feng-Ming MENG Fan-Shun FENG Wen-Ke WANG Shu-Feng TIAN He GONG Qi-Huang 《中国物理快报》2010,27(6):246-249
Mono- and dual-branched molecules, { 4-[2-(4-benzothiazol-2-yl-phenyl)-vinyl]-phenyl}-(4-methoxy-phenyl)-phenyl- amine (BS1) and bis-{4-[2- (4-benzothiazol-2-yl-phenyl)-vinyI]-phenyl}-(4-methoxy-phenyI)-phenyl-amine (BS2), are investigated with one- and two-photon static spectroscopy, and the femtosecond fluorescence up-conversion technique. The molecules show branch-based fluorescence emission at low quantum yield. U1trafast non-radiative decay on a picosecond time scale is found and is attributed to intramolecular charge-transfer bridged by the central triphenylamine. The two-photon absorption cross-sections of BS1 and BS2 are 19.1 and 19.4 GM, respectively. 相似文献
77.
从陆西凹陷的实际资料出发,分析了裂缝在油气勘探中的作用及不同类型裂缝的特征,研究了影响构造裂缝发育的因素,认为构造裂缝的发育受构造部位,孔隙度断层等多种因素的影响,探讨了裂缝发育程度与相关影响因素之间的定量关系,给出了拟合求曲率的方法,与最近断层距离的计算方法,建立了裂缝密度的定量化预测方法-拟合曲率综合预测裂缝方法和相应的评价标准,并对陆西凹陷的裂缝分布进行预测。 相似文献
78.
Wu Ya-Hang Huang Kun Chen Shu-Feng Chen Yu-Zhe Tung Chen-Ho Wu Li-Zhu 《中国科学:化学(英文版)》2019,62(9):1194-1197
Stiff-stilbene derivatives have been widely explored as molecular rotors, molecular force probes and optical switches with excellent performance. However, their function as fluorophores is poorly understood. In the present work, we design three stiffstilbene derivatives and study their photophysical properties. These compounds exhibit very weak emission in solution but significantly enhanced monomer emission in viscous solvent, bright excimer emission in aggregates and at solid state. Detailed spectroscopic studies, single crystal structural analysis, powder X-ray diffraction(XRD) as well as effects of substituents have been carefully examined. They provide direct evidence that intermolecular interactions and molecular packing, which can restrict bond vibration and rotation, are responsible for the bright aggregation-induced emission. 相似文献
79.
Shu-FengLi Xin-LinYang Wen-QiangHuang 《高分子科学》2005,(2):197-202
Monodisperse crosslinked poly(chloromethylstyrene-co-divinylbenzene) (poly(CMSt-co-DVB)) microspheres were prepared by distillation-precipitation copolymerization of chloromethylstyrene (CMSt) and divinylbenzene (DVB) in neat acetonitrile. The polymer particles had clean surfaces due to the absence of any added stabilizer. The size of the particles ranges from 2.59 μm to 3.19 μm and with mono-dispersity around 1.002-1.014. The effects of monomer feed in copolymerization on the microsphere formation were described. The polymer microspheres were characterized by SEM and chlorinity elemental analysis. 相似文献
80.