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991.
A mesogenic crosslinking agent M-1 was synthesized to minimize the perturbations of non-mesogenic crosslinking agents in liquid crystalline elastomers. The synthesis of new side chain liquid crystalline elastomers containing the rigid mesogenic crosslinking agent M-1 and nematic monomer M-2 by a one-step hydrosilylation reaction is described. The chemical structures of the monomers and network polymers obtained were confirmed by FTIR and 1H NMR spectroscopy. The mesomorphic properties and phase behaviour were investigated by differential scanning calorimetry, polarizing optical microscopy, and X-ray diffraction. The influence of the crosslinking units on phase behaviour is discussed. Liquid crystalline elastomers containing less than 15 mol % of the crosslinking units showed elasticity, reversible phase transitions and a threaded texture. The experimental results demonstrated that the glass transition temperature of polymers P-1-7 increased with increasing concentration of crosslinking agent M-1; but the isotropic temperature and liquid crystalline range decreased slightly. 相似文献
992.
Ying Gao Honglian Huang Zhanhai Yao Dean Shi Zhuo Ke Jinghua Yin 《Journal of Polymer Science.Polymer Physics》2003,41(15):1837-1849
Blends of linear low‐density polyethylene (LLDPE) with polystyrene (PS) and blends of LLDPE with high‐impact polystyrene (HIPS) were prepared through a reactive extrusion method. For increased compatibility of the two blending components, a Lewis acid catalyst, aluminum chloride (AlCl3), was adopted to initiate the Friedel–Crafts alkylation reaction between the blending components. Spectra data from Raman spectra of the LLDPE/PS/AlCl3 blends extracted with tetrahydrofuran verified that LLDPE segments were grafted to the para position of the benzene rings of PS, and this confirmed the graft structure of the Friedel–Crafts reaction between the polyolefin and PS. Because the in situ generated LLDPE‐g‐PS and LLDPE‐g‐HIPS copolymers acted as compatibilizers in the relative blending systems, the mechanical properties of the LLDPE/PS and LLDPE/HIPS blending systems were greatly improved. For example, after compatibilization, the Izod impact strength of an LLDPE/PS blend (80/20 w/w) was increased from 88.5 to 401.6 J/m, and its elongation at break increased from 370 to 790%. For an LLDPE/HIPS (60/40 w/w) blend, its Charpy impact strength was increased from 284.2 to 495.8 kJ/m2. Scanning electron microscopy micrographs showed that the size of the domains decreased from 4–5 to less than 1 μm, depending on the content of added AlCl3. The crystallization behavior of the LLDPE/PS blend was investigated with differential scanning calorimetry. Fractionated crystallization phenomena were noticed because of the reduction in the size of the LLDPE droplets. The melt‐flow rate of the blending system depended on the competition of the grafting reaction of LLDPE with PS and the degradation of the blending components. The degradation of PS only happened during the alkylation reaction between LLDPE and PS. Gel permeation chromatography showed that the alkylation reaction increased the molecular weight of the blend polymer. The low molecular weight part disappeared with reactive blending. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1837–1849, 2003 相似文献
993.
The structure of {[Zn2(1,2,4,5‐btc)(pz)(H2O)4]·2(H2O)}n (1,2,4,5‐btc = 1, 2, 4, 5‐benzenetetracarboxylate, pz = pyrazine) is a two‐dimensional coordination network. The zinc(II) center is in a distorted octahedral NO5 coordination environment that is defined by one nitrogen atom of pyrazine, three oxygen atoms of carboxyl groups from 1,2,4,5‐benzenetetracarboxylate tetraanions and two water molecules. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
994.
在空间Lp(Rn),1≤p<∞中,Poison算子半群e--△z是右半平面Rez>0上的解析半群.本文考虑它的边界值,证明了闭稠定算子-i-△对某个α≥0生成了一个指数有界(I+-△)-α 半群. 相似文献
995.
Liying Zhou Yingming Yao Yong Zhang Hongting Sheng Mingqiang Xue Qi Shen 《应用有机金属化学》2005,19(3):398-399
The title complex, [Ph2NC(NCy)2]3Yb·2PhCH3 is a monomer with a six‐coordinate ytterbium center ligated by six nitrogen atoms of three chelating bidentate guanidinate ligands. The coordination geometry around the lanthanide ion is best described as a distorted trigonal prism. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
996.
Justin T. Russell Yao Lin Alexander Bker Long Su Philippe Carl Heiko Zettl Jinbo He Kevin Sill Ravisubhash Tangirala Todd Emrick Kenneth Littrell Pappannan Thiyagarajan David Cookson Andreas Fery Qian Wang Thomas P. Russell 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2005,117(16):2472-2478
997.
Yao Zhijian 《Annals of Differential Equations》2008,(3):367-378
In this paper, a predator-prey chain system with impulsive effects and Beddington-DeAngelis functional response is studied. We investigate the existence of periodic solu-tion by coincidence degree theory. Sufficient conditions are obtained for the existence of periodic solution. 相似文献
998.
Yao Fengping Zhou Shulin 《偏微分方程(英文版)》2008,21(4):315-334
In this paper similarly to the second-order case, we give an elementary and straightforward proof of global Lp estimates for the initial-value parabolic problem of the bi-harmonic type. Moreover, we obtain the existence and uniqueness of the solutions in the suitable space using the potential theory, Marcinkiewicz interpolation theorem and approximation argument. Meanwhile, by the same approach we can deal with the general polyharmonic cases. 相似文献
999.
I. J. Jang Y. D. Yao I. Klik H. E. Horng H. C. Yang 《Czechoslovak Journal of Physics》1996,46(Z4):2021-2022
Thermomagnetic curves for water based ferrofluid with large magnetic latex particles are analyzed. The particles are found
to have extremely low barrier height of thermal relaxation (≤1200 K at temperatures below 100 K) whose field dependence is
deduced.
Work sponsored by the National Science Council of the R.O.C. under Grant No. NSC85-2112-M-001-020. 相似文献
1000.
σ-根与σ-半单类的构造 总被引:1,自引:0,他引:1
继[1~3]分别给出σ-根及其半单类的两个特征性质,研究了对于已知环类M,含于M的最大σ-根及σ-半单类和包含M的最小σ-半单类的构造,同时得到σ-半单闭包σ-遗传的一个充分条件. 相似文献