火灾烟雾颗粒凝并分形特性研究

火灾烟雾颗粒因布朗运动由初期的主粒子凝并形成大颗粒的凝团结构，其外形呈现出分形特征，根据分形理论对火灾烟雾颗粒凝团结构进行分析研究，采用场发射扫描电镜对多种材料的烟雾颗粒图像进行测试，通过对烟雾凝团图像进行处理，获得了火灾探测中常见的多种材料的分形维数和分形系数，给出了烟雾颗粒的主粒子粒径，并对其影响因素进行了对比分析，为火灾烟雾探测中颗粒凝并分形特性研究提供有益的探索. 关键词： 火灾 烟雾 颗粒 凝并 分形     

A kind of new algebraic Rossby solitary waves generated by periodic external source

In the article, by employing multiple-scale, perturbation method, a new model is derived to describe the algebraic Rossby solitary waves generated by periodic external source in stratified fluid. The local conservation laws and analytic solutions of the model are obtained, and the breakup properties are discussed. By numeric simulation, some problems on the generation and evolution of the algebraic solitary waves under the influence of periodic external source are theoretically investigated. The results show that besides the solitary waves, an additional harmonic wave appears in the region of the external source forcing. Furthermore, the periodic variation of the external source forcing can prevent solitary waves from breaking. Meanwhile, the detuning parameter has an important effect on the breakup of the algebraic Rossby solitary waves.     

Facile synthesis of biphenyl-fused BODIPY and its property

A biphenyl-fused BODIPY was synthesized through a facile oxidative cyclization of peripheral aryl-substituents at the β-position of the BODIPY unit. The extended π-system of the fused BODIPY induces near-infrared (NIR) absorption and strong π-π interactions in the solid state. These features are beneficial for the application of the dye as a functional material. The biphenyl-fused BODIPY dye was demonstrated to exhibit photocurrent conversion ability on the basis of its n-type semiconducting property.     

Multifunctional Non‐Viral Delivery Systems Based on Conjugated Polymers

Multifunctional nanomaterials with simultaneous therapeutic and imaging functions explore new strategies for the treatment of various diseases. Conjugated polymers (CPs) are considered as novel candidates to serve as multifunctional delivery systems due to their high fluorescence quantum yield, good photostability, and low cytotoxicity. Highly sensitive sensing and imaging properties of CPs are well reviewed, while the applications of CPs as delivery systems are rarely covered. This feature article mainly focuses on CP‐based multifunctional non‐viral delivery systems for drug, protein, gene, and cell delivery. Promising directions for the further development of CP‐based delivery systems are also discussed.

     

Controllable synthesis of well-ordered TiO2 nanotubes in a mixed organic electrolyte for high-efficiency photocatalysis

Well-ordered TiO 2 nanotube arrays (TNAs) were fabricated by electrochemical anodization in a mixed organic electrolyte consisting of ethylene glycol and glycerol. The morphology, structure, crystalline phase, and photocatalytic properties of TNAs were characterized by using TEM, SEM, XRD and photodegradation of methylene blue. It was found that the morphology and structure of TNAs could be significantly influenced by the anodization time and applied voltage. The obtained tube length was found to be proportional to anodization time, and the calculated growth rate of nanotubes was 0.6 m/h. The microstructure analysis demonstrated that the diameter and thickness of the nanotubes increased with the increase of anodization voltage. The growth mechanism of TNAs was also proposed according to the observed relationship between current density and time during anodization. As expected, the obtained TNAs showed a higher photocatalytic activity than the commercial TiO 2 P25 nanoparticles.     

Bridged polyhedral oligomeric silsesquioxane (POSS): A potential member of silsequioxanes

Two novel and well-defined polyhedral oligomeric silsesquioxanes（POSS） with two same Si₈O₁₂ cores and a reactive NH group, namely bridged-POSS（2a and 2b）,have been prepared by the traditional ’corner-capping’ reaction.X-ray diffraction demonstrates that those two POSS have the similar T₈ structure.From the thermo-gravimetric analysis,bridged-POSS shows the belter thermal degradation stability than the contrastive POSS.     

Novel organosoluble polyimide based on an asymmetric bis(ether amine): 3, 4′-Bis(4-aminophenoxy)-benzophenone

A new kind of asymmetrical ether diamine,3,4’-bis（4-aminophenoxy）benzophenone（BABP）,was synthesized from the nucleophilic substitution reaction of 4-chloronitrobenzene and 3,4’-dihydroxybenzophenone in the presence of potassium carbonate,followed by catalytic reduction with SnCl₂-6H₂O and concentrated hydrochloric acid.The prepared diamine was employed in the preparation of a novel polyimide containing asymmetrical diaryl ether segments via the polycondensation of it with BTDA by a two-step method.The resulting polyimide exhibits excellent solubility,film-forming capability and high thermal resistance.     

Catalytic Asymmetric Dearomatization Reactions

This Review summarizes the development of catalytic asymmetric dearomatization (CADA) reactions. The CADA reactions discussed herein include oxidative dearomatization reactions, dearomatization by Diels–Alder and related reactions, the alkylative dearomatization of electron‐rich arenes, transition‐metal‐catalyzed dearomatization reactions, cascade sequences involving asymmetric dearomatization as the key step, and nucleophilic dearomatization reactions of pyridinium derivatives. Asymmetric dearomatization reactions with chiral auxiliaries and catalytic asymmetric reactions of dearomatized substrates are also briefly introduced. This Review intends to provide a concept for catalytic asymmetric dearomatization.