首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   19259篇
  免费   3228篇
  国内免费   2493篇
化学   14599篇
晶体学   259篇
力学   1089篇
综合类   190篇
数学   2201篇
物理学   6642篇
  2024年   47篇
  2023年   369篇
  2022年   545篇
  2021年   612篇
  2020年   712篇
  2019年   778篇
  2018年   627篇
  2017年   603篇
  2016年   890篇
  2015年   884篇
  2014年   1140篇
  2013年   1531篇
  2012年   1760篇
  2011年   1873篇
  2010年   1338篇
  2009年   1265篇
  2008年   1268篇
  2007年   1221篇
  2006年   1037篇
  2005年   877篇
  2004年   759篇
  2003年   625篇
  2002年   703篇
  2001年   595篇
  2000年   459篇
  1999年   369篇
  1998年   298篇
  1997年   218篇
  1996年   230篇
  1995年   184篇
  1994年   199篇
  1993年   128篇
  1992年   132篇
  1991年   120篇
  1990年   112篇
  1989年   93篇
  1988年   59篇
  1987年   56篇
  1986年   53篇
  1985年   50篇
  1984年   37篇
  1983年   17篇
  1982年   11篇
  1981年   14篇
  1980年   10篇
  1979年   14篇
  1977年   9篇
  1976年   8篇
  1975年   7篇
  1957年   5篇
排序方式: 共有10000条查询结果,搜索用时 250 毫秒
41.
MC模式下顾客需求与厂商供应的纳什均衡   总被引:3,自引:0,他引:3  
在大规模定制(MC,Mass Customization)模式下,基于市场需求的复杂化,厂商对个性化的顾客需求很难做出及时准确的反应,而且由于其自身生产能力的限制,不可能对所有的个性化用户进行一一地满足,只可能对已经存在的个性化需求,根据自身的生产能力和规模,以利润最大化及顾客对产品的满意度为目标,对个性化需求进行较准确地预测,从而正确指导生产。本通过博弈论的方法,提出了一个基于顾客对产品的满意度及企业的利润的一个非合作博弈模型,并给出求解纳什均衡的方法。  相似文献   
42.
A low cost, coolerless 980nm diode pumped, gain flattened L band EDFA with fast transient control, high pump efficiency and gain clamping effect was realized by using FBGs as C band seed generators.  相似文献   
43.
The atom transfer radical copolymerization of N‐substituted maleimides such as N‐phenylmaleimide (PhMI), N‐cyclohexylmaleimide (ChMI), and N‐butylmaleimide (NBMI) with styrene initiated with dendritic polyarylether 2‐bromoisobutyrates in an ionic liquid, 1‐butyl‐3‐methylimidazolium hexafluorophosphate ([bmim][PF6]), at room temperature and anisole at 110 °C was investigated. The dendritic‐linear block copolymers obtained in ionic liquid possessed well‐defined molecular weight and low polydispersity (1.05 < Mw/Mn < 1.32) and could be used as a macroinitiator for chain‐extension polymerization, suggesting the living nature of the reaction system. The ionic liquids containing catalyst could be recycled in the atom transfer radical polymerization systems without further treatment. Compared with polymerization conducted in anisole, the polymerization in ionic liquid had a stronger tendency for alternation. The tendency for alternation decreased in the order PhMI > NBMI > ChMI in [bmim][PF6] and PhMI > ChMI > NBMI in anisole. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2156–2165, 2003  相似文献   
44.
A soluble cyano‐substituted poly[(1,3‐phenylene vinylene)‐alt‐(1,4‐phenylene vinylene)] derivative ( 9 ) was synthesized and characterized. Comparison between 9 and its model compound ( 10 ) showed that the chromophore in 9 remained to be well defined as a result of a π‐conjugation interruption at adjacent m‐phenylene units. The attachment of a cyano substituent only at the β position of the vinylene allowed the maximum electronic impact of the cyano group on the optical properties of the poly(p‐phenylene vinylene) material. At a low temperature (?108 or ?198 °C), the vibronic structures of 9 and 10 were partially resolved. The absorption and emission spectra of a film of 9 were less temperature‐dependent than those of a film of 10 , indicating that the former had a lower tendency to aggregate. A light‐emitting diode (LED) based on 9 emitted yellow light (λmax ≈ 578 nm) with an external quantum efficiency of 0.03%. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3149–3158, 2003  相似文献   
45.
大口径光束波前采样器(孔栅)的研制   总被引:2,自引:0,他引:2  
应用平面波角谱理论,分析了采样器对光波场采样和分光的基本原理以及对空间采样频率的选择规则,描述了实际研制的大口径采样器的结构设计,并通过数值方法和高能激光大气传输实验研究了高能激光经采样器前/后的远场光斑分布关系。结果表明:利用光束波前采样器能高保真地实现对高能激光束的分光。  相似文献   
46.
采用高温热解法,以乙二胺为前驱液,在沉积有铁催化剂的p型硅(111)基底上制备出了定向生长的CNx纳米管.利用扫描电子显微镜、高分辨率透射电子显微镜和拉曼光谱对CNx纳米管进行了形貌观察和表征.CNx纳米管的高度在20?μm左右,直径在50—100nm之间,具有明显的“竹节状”结构,结晶有序度较差.对CNx纳米管薄膜进行低场致发射性能测试:外加电场为1.4V/μm,观察到20?μA /cm2发射电流,外电场升至2.54V/μm时发射电流达到1.280mA/cm2,在较高外电场下,没有发现电流“饱和”.这比 关键词: CNx纳米管 高温热解 “竹节状”结构 场致发射  相似文献   
47.
线性均衡约束最优化的一个广义投影强次可行方向法   总被引:1,自引:0,他引:1  
本文讨论带线性均衡约束最优化问题,首先利用摄动技术和一个互补函数将问题等价转化为一般约束最优化问题,然后结合广义投影技术和强次可行方向法思想,建立了问题的一个新算法.算法在迭代过程中保证搜索方向不为零,从而使得每次迭代只需计算一次广义投影.在适当的条件下,证明了算法的全局收敛性,并对算法进行了初步的数值试验.  相似文献   
48.
Two quantities ηrel and are applied to study the nonideal acetone–water association mixture. An all-atom acetone model and a TIP5P water model have been adopted for molecular dynamics simulation. We study the transport properties of the system comparing the 's of strong hydrogen bond and weak contact based on transport properties, MD simulations together with NMR experimental data and find good agreement of concentration dependence, which exhibits the cooperation effect.  相似文献   
49.
A gas-filled type of recoil separator for heavy element research was installed at an experimental hall of RIKEN Linear Accelerator facility to realize getting higher intensity of primary beam and long beam time. Performance of the separator was studied using target recoils and various nuclear reactions. The results show the high performance of the separator for heave element research. As an application of the GARIS, production and identification of an isotope of the 110th element 271[110] have been performed using the 208Pb(64Ni,1n)271[110] reaction. Three decay chains coincide well both in decay times and energies with the ones reported by the group of SHIP experiment at GSI, Germany. Our results provide a confirmation of the synthesis of an isotope 271[110] of element 110.  相似文献   
50.
The tetramethoxysilane (TMOS)/2‐hydroxylethyl methacrylate (HEMA) hybrid gels were synthesized with acid and base catalysts, via the in situ polymerization of HEMA, with and without the cosolvent methanol. With methanol in the TMOS/HEMA sol, the enhanced esterification and depolymerization reactions of the silanols resulted in a slower growth of silica particles. The silica particles that were synthesized with an acid catalyst were less than 40 nm. The thermal resistance of the poly(2‐hydroxyethyl methacrylate) (PHEMA) chains was enhanced by the addition of colloidal silica. The Fourier transform infrared characterizations and the exothermal peaks on the differential scanning calorimetry traces of these hybrid gels indicated chemical hybridization occurring as a result of condensation of the colloid silica and PHEMA at higher temperatures. Hence, the residual weight content of the hybrid gel after its synthesis with the base catalyst was even higher than the content of TMOS in the hybrid sol. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3476–3486, 2004  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号