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11.
Kumar VG Gokavarapu SD Rajeswari A Dhas TS Karthick V Kapadia Z Shrestha T Barathy IA Roy A Sinha S 《Colloids and surfaces. B, Biointerfaces》2011,87(1):159-163
A simple biological method for the synthesis of gold nanoparticles (AuNPs) using Cassia auriculata aqueous leaf extract has been carried out in the present study. The reduction of auric chloride led to the formation of AuNPs within 10 min at room temperature (28°C), suggesting a higher reaction rate than chemical methods involved in the synthesis. The size, shape and elemental analysis were carried out using X-ray diffraction, TEM, SEM-EDAX, FT-IR and visible absorption spectroscopy. Stable, triangular and spherical crystalline AuNPs with well-defined dimensions of average size of 15-25 nm were synthesized using C. auriculata. Effect of pH was also studied to check the stability of AuNPs. The main aim of the investigation is to synthesize AuNPs using antidiabetic potent medicinal plant. The stabilizing and reducing molecules of nanoparticles may promote anti-hyperglycemic if tested further. 相似文献
12.
Bruch’s membrane is a layer composed of collagen fibers located just beneath the retina. This study validates a strategy used
to map the morphological and adhesion characteristics of collagen fibers in Bruch’s membrane. Atomic force microscopy tips
were functionalized with different chemical groups and used to map the hydrophilic and hydrophobic regions on the surface
of the eye tissue. The largest adhesion forces were observed when tips functionalized with NH2 groups were used. The trend in the adhesion forces was rationalized based on the distribution of different functional groups
in the triple-helical structure of the collagen fibers. The results of this study can be used to design more effective strategies
to treat eye diseases such as age-related macular degeneration. 相似文献
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We find numerically that in the limit of weak atom-atom interactions a Bose-Einstein condensate in an optical lattice may develop a pulsating dynamical instability in which the atoms nearly periodically form a peak in the occupation numbers of the lattice sites, and then return to the unstable initial state. Multiple peaks behaving similarly are also found. Simple arguments show that the pulsating instability is a remnant of integrability, and give a handle on the relevant physical scales. 相似文献
15.
Jones B Deeney C McKenney JL Ampleford DJ Coverdale CA Lepell PD Shelton KP Safronova AS Kantsyrev VL Osborne G Sotnikov VI Ivanov VV Fedin D Nalajala V Yilmaz F Shrestha I 《Physical review letters》2008,100(10):105003
Axially localized NaF dopants are coated onto Al cylindrical wire arrays in order to act as spectroscopic tracers in the stagnated z-pinch plasma. Non-local-thermodynamic-equilibrium kinetic models fit to Na K-shell lines provide an independent measurement of the density and temperature that is consistent with spectroscopic analysis of K-shell emissions from Al and an alloyed Mg dopant. Axial transport of the Na dopant is observed, enabling quantitative study of instabilities in dense z-pinch plasmas. 相似文献
16.
We study a soliton in an optical lattice holding bosonic atoms quantum mechanically using both an exact numerical solution and quantum Monte Carlo simulations. The computation of the state is combined with an explicit account of the measurements of the numbers of the atoms at the lattice sites. In particular, importance sampling in the quantum Monte Carlo method arguably produces faithful simulations of individual experiments. Even though the quantum state is invariant under lattice translations, an experiment may show a noisy version of the localized classical soliton. 相似文献
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Phase behavior and microstructures of nonionic fluorocarbon surfactant in aqueous systems 总被引:1,自引:0,他引:1
Shrestha RG Shrestha LK Sharma SC Aramaki K 《The journal of physical chemistry. B》2008,112(34):10520-10527
The phase behavior and self-assembled structures of perfluoroalkyl sulfonamide ethoxylate, C8F17SO2N(C3H7)(CH2CH2O)20H (abbreviated as C8F 17EO20), a nonionic fluorocarbon surfactant in an aqueous system, has been investigated by the small-angle X-ray scattering (SAXS) technique. The C8F17EO20 forms micelles and different liquid crystal phases depending on the temperature and composition. The fluorocarbon micellar structure induced by temperature or composition change and added fluorocarbon cosurfactant has been systematically studied. The SAXS data were analyzed by the indirect Fourier transformation (IFT) and the generalized indirect Fourier transformation (GIFT) depending on the volume fraction of the surfactant and complemented by plausible model calculations. The C8F17EO20 forms spherical type micelles above critical micelle concentration (cmc) in the dilute region. The micelle tends to grow with temperature; however, the growth is not significant on changing temperature from 15-75 degrees C, which is attributed to the higher clouding temperature of the surfactant (>100 degrees C). On the other hand, the micellar structure (shape and size) is apparently unaffected by composition (1-25 wt %) at 25 degrees C. Nevertheless, addition of fluorocarbon cosurfactant of structure C8F17SO2N(C3H7)(CH2CH2O)H (abbreviated as C8F17EO1) to the semidilute solution of C8F17EO20 (25 wt %) favors micellar growth, which finally leads to the formation of viscoelastic wormlike micelles, as confirmed by rheometry and supported by SAXS. The onset sphere-to-wormlike transition in the structure of micelles in the C8F17EO20/water/C8F17EO1 system is due to the fact that the C8F17EO1 tends to go to the surfactant palisade layer so that the critical packing parameter increases due to a decrease in the effective cross-sectional area of the headgroup. As a result, spherical micelles grow into a cylinder, which after a certain concentration entangle to form a rigid network structure of wormlike micelles. 相似文献
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Yousef A Shrestha S Viehland LA Lee EP Gray BR Ayles VL Wright TG Breckenridge WH 《The Journal of chemical physics》2007,127(15):154309
High-level ab initio calculations are performed on the coinage metal cations (Cu+, Ag+, and Au+) interacting with each of the rare gases [Rg (Rg=He to Rn)]. The RCCSD(T) procedure is employed, with basis sets being of approximately quintuple-zeta quality, but with the heavier species using relativistic effective core potentials. The interaction potentials are compared to experimental and theoretical data where they exist. In addition, transport coefficients for the mobility and diffusion of the cations in the rare gases are calculated. The latter have involved a rewriting of some of the programs used, and the required modifications are discussed. The mobility results indicate that, rather than being a rare occurrence, mobility minima may be common phenomena. Finally, a new estimate is put forward for the validity of zero-field mobilities in ion mobility spectrometry. 相似文献