The energy exchange and the optimum length of the sample tube of opfirl

The energy exchange between the pumping laser and FIR signal in the optically pumped FIR laser (OPFIRL) system was studied. The iteration method has been used to calculate the power density of the pumping and FIR signals at any point along the optical axis of the sample tube. It was found that the power density of the FIR signal did not always increase along the length of the laser tube. There was a maximum FIR power density at the appropriate point in the sample tube. If the distance of maximum power point from the entrance of the OPFIRL tube was taken as the length of sample tube Z_opt, the maximum FIR laser output should be obtained. This was the optimum length of OPFIRL tube. The value of Z_opt was closely related to the parameter of OPFIRL such as the pumping power density, the pumping detuning and the frequency of the FIR laser. The energy-exchange and the maximum output of the fir laser were calculated under the ideal condition.     

甲基二氯硅烷—甲苯等压汽液平衡研究

用泵式沸点仪测定了甲基二氯硅烷—甲苯二元系在常压下的汽液平衡数据,并用间接法由ＴＰＸ 推算了与之平衡的汽相组成,用最小二乘法求出了该系统的液相活度系数模型参数,由模型参数推算的泡点温度与实验值符合良好,所得数据通过了热力学一致性检验。     

圆薄板非对称大变形弯曲问题

本文首先导出圆薄板非轴对称大变形问题的位移基本方程及边界条件.利用变换和摄动法将非线性位移方程线性化,得到了近似边值问题.作为算例,文中研究了圆薄板在较复杂载荷作用下的非线性弯曲问题.     

直流溅射法制备电致变色WO_3膜

采用ＷＯ３陶瓷靶直流溅射制作了电致变色膜．介绍了制膜工艺．分析测试表明，膜有无定形结构；除有正常成分ＷＯ３外，还含有来自衬底及反应室内的微量杂质．电致变色谱响应特性和电化学特性的测量证明，膜的电色活性良好．还对实验结果作了理论分析．     

A NEW FORMULA WITHOUT BOUNDARY INTEGRALS ON A STEIN MANIFOLD

A new Koppelman-Leray-Norguet formula of (p-1,q) differential forms for a strictly pseudoconvex polyhedron with not necessarily smooth boundary on a Stein manifold is obtained, and an integral representation for the solution of (?)-equation on this domain which does not involve integrals on boundary is given, so one can avoid complex estimates of boundary integrals.     

关于猝灭问题的一些结果及其应用

本文研究一类含奇异项的半线性抛物方程的初边值问题,给出了该问题的古典解整体存在或发生猝灭现象的判据以及猝灭解的生命跨度估计。同时,还用上述结果研究了一类含超Sobolev临界指标的半线性椭圆方程的Dirichlet边值问题,获得了正解的存在性结果。     

沿高阶单调曲线的Hilbert变换和极大算子的L^p估计

设γ:[-1,1]→R~n是R~n中的曲线,沿曲线的γ的Hilbert变换是如下定义的主值积分: Hf(x)=P.V.integral -1 to 1 f(x-γ(t))dt/t,相应的极大算子定义为: Mf(x)=sup 1/h| integral O to h f(x-γ(t))dt|. 对高阶单调曲线本文证明了相应的算子M和H都是L~p(R~n)有界的,从而改进了Nestlerode的结果。     

光泵分子气体远红外光谱的AC Stark效应

本文应用图论法研究光泵激光气体分子的波谱特性。假定了:1.分子与外来信号场相互作用输运过程中只涉及到六个能级;2.泵场强远大于探测场强。在这些假定下求解密度矩阵方程,获得一套反映受激分子波谱特性的解析表达式。应用这些表达式,可求得不同频率的泵场作用下分子气体的远红外波谱特性。本文特别叙述分子振动基态远红外光谱的AC aStark效应。结果表明:在谐振点AC aStark分裂的值与C.H.Townes所得结果基本相同,在受激发射和吸收共存的情况下,特性曲线的总趋向与他的结果基本一致。调谐曲线有些部份反映发射特性,有些部份反映吸收特性,在发射和吸收的过渡部份,吸收和发射都很小,而且具有特殊的过渡特性。     

杂多阴离子的NMR和ESR研究——P-V-W Keggin阴离子的31P、51V、17O-NMR谱

本文合成了六种含有P-V-W和V-V-W Keggin结构的杂多阴离子,并研究了它们的³¹P、⁵¹V、¹⁷O-NMR谱,对于PV_xW_12-xO₄₀^(x+3)-(x=1~4)阴离子,当x=1时,³¹P和⁵¹V-NMR谱只有一条线,并且此线化学位移和pH无关。当x ≥ 2时,谱线数目随着x迅速增加,其原因是几何异构体的数目和类型迅速增加。它们的化学位移δ_p,和δ_v。依赖于溶液的酸性和x,即δ_p,随pH值和x增加而减少,而δ_v,却随pH和x的增加而增加。最后简短讨论了桥氧上质子化的影响。