N,O-羧甲基壳聚糖的合成和性质研究

采用多段升温法将壳聚糖改性 ,合成了取代度为 1.84、平均分子量为 3.0 8× 10 5、等电点为 7.2 8的N ,O 羧甲基壳聚糖 (CMC) ,分别用紫外光谱、红外光谱、荧光光谱对其结构进行了表征 ,并对其水溶液的Zeta电位、电导率、表面张力以及水分散体系中羧甲基壳聚糖微粒的粒径分布进行了研究 .结果表明 ,N ,O 羧甲基壳聚糖具有表面活性 ;介质的pH值和浓度对羧甲基壳聚糖溶液的稳定性有很大的影响     

Controlling the gain shape of Er^3＋—doped fluorozirconate fibre amplifier by a coherent field

We proposed a four-level system to explore the quantum interference effects on optical amplification.We found that the gain of the probe.including positions and values of gain peaks,can be adjusted by changing the coherent field and the incoherent pumping.At the same time,we can also modify the absorption profile of electromagnetically induced transparency by the incoherent pump.The results provide a method to flatten the gain of Erbium-doped fibre amplifiers.     

Study of the stability of polarization mode dispersion in fibre

Polarization mode dispersion (PMD) is the ultimate limitation to high bit-rate fibre communication system. The stability of PMD is very important to its measurement and compensation. This paper puts forward a method to measure the stability of PMD by measuring the stability of the state of polarization (SOP) and introduces the conception of time evolution vector (TEV) of SOP. We observe the fact that the regularity of the principal state of polarization changing with time is the same as other SOPs‘‘, if we neglect the dependence of TEV on wavelength. We also measure the SOP‘‘s stability of some fibres with different lengths, and obtain results of PMD changing with time.     

Electric field-induced stress birefringence in layered composites PbZr1-xTixO3/Polycarbonate

Electro-optical composites based on the product of electro-strictive and elasto-optical effects are developed.Layered composites of PbZr 1 x Ti x O 3 and polycarbonate are synthesised.Their electro-optical properties are studied.The nominal transverse electro-optical coefficient of the composite is observed to be about 3.6 times larger than that of LiNbO 3.Experiments and theoretical analyses show that the electro-optical effect of the composite has a strong ’size effect’.With the ratio of thickness/length decreasing or the width of elasto-optical phase increasing,the half-wave electric field intensity increases but the transverse electro-optical coefficient decreases for the layered composite.     

一类不确定离散混沌系统的自抗扰控制器与小脑神经网络并行优化控制

针对一类受扰不确定离散非线性混沌系统,提出了基于免疫动态微粒群优化策略的ADRC与CMAC神经网络并行控制方法(ADRC-CMAC).ADRC控制器抑制系统扰动,保证系统的稳定性;CMAC神经网络控制器实现前馈控制保证系统的控制精度和响应速度.利用动态免疫微粒群算法对ADRC-CMAC并行控制器参数进行全局优化.实验结果表明该控制方法具有较快系统的响应速度,较好的抗干扰能力,控制精度高. 关键词： 自抗扰控制器 小脑神经网络 并行控制 混沌系统     

钚气溶胶环境中惰性气体氪迁移过程研究

放射性气体的安全性问题是涉及反应堆运行中必需研究的重要问题.因此在钚气溶胶环境中,对钚材料裂变产生的放射性气体裂变产物,需要研究其在钚气溶胶环境中的迁移过程.对放射性惰性气体Kr87,Kr88的实验测量数据进行了具体分析.依据它们具有钚材料直接裂变和作为固体裂变产物子体两种来源这一物理特性,在不同的制样时间对Kr87/Kr88比值变化规律进行分析.确立了这两种来源的在钚气溶胶环境中的物理图像和迁移过程的物理模型,并与实验数据进行比较以验证模型的正确性. 关键词： 钚气溶胶 气体裂变产物 放射性Kr87/Kr88 迁移过程     

全谱拟合法研究聚丙烯腈基碳纤维形成过程中晶态结构演变

通过全谱拟合法对碳纤维制备过程中不同阶段纤维的XRD谱图进行处理,得到不同阶段纤维的微观结构参数,研究了聚丙烯腈(PAN)基碳纤维制备过程中晶态结构的演变.全谱拟合法基于晶体衍射的严格物理理论,拟合目标为整个衍射谱,并不是个别衍射峰,所得结果具有更高的可信度.研究结果表明:PAN原丝中的高分子链沿纤维轴高度取向,表观晶粒尺寸为6.5 nm左右;经过预氧化处理,纤维中的有序结构遭到破坏,表观晶粒尺寸锐减.纤维中逐渐形成梯形结构并沿纤维轴取向,从而形成新的有序结构;经过碳化处理后,环状梯形结构转变为碳的层状结 关键词： 碳纤维 晶体结构 XRD 全谱拟合法     

Structural and bonding properties of ScSi_n~-(n=2～6) clusters:photoelectron spectroscopy and density functional calculations

Anion ion photoelectron spectroscopy and density functional theory (DFT) are used to investigate the electronic and structural properties of ScSi_n^- (n=2sim6) clusters and their neutrals. We find that the structures of ScSi_n^- are similar to those of Si_n+1^-. The most stable isomers of ScSi_n^- cluster anions and their neutrals are similar for n=2, 3 and 5 but different for n=4 and 6, indicating that the charge effect on geometry is size dependent for small scandium-silicon clusters. The low electron binding energy (EBE) tails observed in the spectra of ScSi_4,6^- can be explained by the existence of less stable isomers. A comparison between ScSi_n^- and VSi_n^- clusters shows the effects of metal size and electron configuration on cluster geometries.     

基于无基底焦平面阵列红外热像仪的理论模型分析

基于双材料微悬臂梁热变形原理的光学读出非制冷红外探测阵列经历了从有基底结构向无基底结构的发展过渡,无基底阵列的红外成像结果和有限元模型分析均表明无基底阵列不满足恒温基底条件.本文结合电学比拟的方法,提出了一种新的基于无基底焦平面阵列(focal plane Array,FPA)的热传递分析的理论模型.分析采用整体考虑的思路,避开了无基底FPA阵列各单元热传递互相影响所产生的复杂热分布分析,并考虑了框架对热量的吸收与传递.理论模型采用外边框与环境等温的边界条件,虽不及有限元方法对边界条件的处理灵活,但也已取 关键词： 光学读出 无基底 非制冷红外成像 焦平面阵列     

Cluster synchronization in a network of non-identical dynamic systems

Cluster synchronization in a network of non-identical dynamic systems is studied in this paper, using two-cluster synchronization for detailed analysis and discussion. The results show that the common intercluster coupling condition is not always needed for the diffusively coupled network. Several sufficient conditions are obtained by using the Schur unitary triangularization theorem, which extends previous results. Some numerical examples are presented for illustration.