Free convection heat transfer from a horizontal fin attached cylinder between confined nearly adiabatic walls

Steady state two-dimensional free convection heat transfer from a horizontal, isothermal fin attached cylinder, located between nearly two adiabatic walls is studied experimentally using a Mach–Zehnder interferometer. Effects of the walls inclination angel (θ) on heat transfer from the cylinder is investigated for Rayleigh number ranging from 1000 to 15,500. Two cylinders with different diameters of D = 10 and 20 mm are used to cover wide Rayleigh range. Results indicate that, heat transfer phenomena differ for different Rayleigh number. For Rayleigh numbers lower than 5500, heat transfer rate from cylinder surface is lower than the heat transfer from a single cylinder. In this range by the use of walls, heat transfer from the cylinder decreases slightly and walls’ inclination does not change heat transfer rate from the cylinder surface. For Rayleigh number ranging from 5500 to 15,500, amount of heat transfer from the cylinder surface is less than that of a single cylinder. However, by adding nearly adiabatic walls to experimental model heat transfer mechanism differs and chimney effect between fin and walls increases the heat transfer rate from the cylinder surface. By increasing the walls inclination angel from 0° to 20°, the chimney effect between walls and fin diminishes and heat transfer rate from the cylinder surface is approaching to the heat transfer rate of fin attached cylinder without adiabatic walls.     

NMR‐Solution Structures in Methanol of an α‐Heptapeptide,of a β3/β2‐Nonapeptide,and of an all‐β3‐Icosapeptide Carrying the 20 Proteinogenic Side Chains

The NMR‐solution structure of an α‐heptapeptide with a central Aib residue was investigated in order to verify that, in contrast to β‐peptides, short α‐peptides do not form a helical structures in MeOH. Although the central Aib residue was found to induce a bend in the experimentally determined structure, no secondary structure typical for longer α‐peptides or proteins was found. A β²/β³‐nonapeptide with polar, positively charged side chains was subjected to NMR analysis in MeOH and H₂O. Whereas, in MeOH, it folds into a 10/12‐helix very similar to the structure determined for a corresponding β²/β³‐nonapeptide with only aliphatic side chains, no dominant conformation could be determined in H₂O. Finally, the NMR analysis of a β³‐icosapeptide containing the side chains of all 20 proteinogenic amino acids in MeOH is described. It revealed that this 20mer folds into a 3₁₄‐helix over its whole length forming six full turns, the longest 3₁₄‐helix found so far. Together, our findings confirm that, in contrast to α‐peptides, β‐peptides not only form helices with just six residues, but also form helices that are longer than helical sections usually observed in proteins or natural peptides. The higher helix‐forming propensity of long β‐peptides is attributed to the conformation‐stabilizing effect of the staggered ethane sections in β‐peptides which outweighs the detrimental effect of the increasing macrodipole.     

Formation of uniform self-assembly monolayers by choosing the right solvent: OTS on silicon wafer, a case study

The main purpose of this research is to show the effects of solvent nature, partial charge distribution and polarity index, on the preparation of uniform silane self-assembly monolayers. Octadecyltrichlorosilane (OTS) on silicon wafers was chosen as a case study. Contrary to what was thought before, dipole moment data are not enough and one needs accompanying data on partial charge distribution and polarity index to predict the best solvent for a uniform self-assembled monolayer (SAM). Results can be applied to other monolayer-solvent systems.     

Nonlinear optical characterization of phosphate glasses based on ZnO using the Z-scan technique

The nonlinear optical properties of a phosphate vitreous system [(ZnO)_x-(MgO)_30-x-(P₂ O₅)₇₀], where x=8, 10, 15, 18, and 20 mol% synthesized through the melt-quenching technique have been investigated by using the Z-scan technique. In the experiment, a continuous-wave laser with a wavelength of 405 nm was utilized to determine the sign and value of the nonlinear refractive (NLR) index and the absorption coefficient with closed and opened apertures of the Z-scan setup. The NLR index was found to increase with the ZnO concentration in the glass samples by an order of 10^-10 cm²·W^-1. The real and imaginary parts of the third-order nonlinear susceptibility were calculated by referring to the NLR index (n₂) and absorption coefficient (β) of the samples. The value of the third-order nonlinear susceptibility was presented by nonlinear refractive or absorptive behavior of phosphate glasses for proper utilization in nonlinear optical devices. Based on the measurement, the positive sign of the NLR index shows a self-focusing phenomenon. The figures of merit for each sample were calculated to judge the potential of phosphate glasses for application in optical switching.     

Octadecyltrichlorosilane (OTS): a resist for OMCVD gold nanoparticle growth

One application of octadecyltrichlorosilane (OTS) self‐assembled monolayers (SAMs) is its use as thin film resists. In this work, we demonstrated that OTS SAMs can be reliable resists for organo‐metallic chemical vapor deposition (OMCVD) grown gold nanoparticles (Au NPs). In optical sensing applications based on Au NPs, one candidate system consists of patterned OTS SAMs and precisely grown OMCVD Au NPs for achieving a high sensitivity. As an initial step, the OTS SAMs need to perfectly resist the OMCVD Au NP growth. Hence the optimized formation of the OTS SAMs affected by different assembly times and baking temperatures was studied by contact angle, ellipsometry, XPS, SEM, and atomic force microscopy (AFM). To demonstrate the ability of the OTS SAMs to resist OMCVD Au NP growth, the OMCVD process was carried out on two sets of samples: OTS SAMs fabricated under optimized conditions on one set and the other set without OTS SAMs. High‐resolution XPS, RBS, SEM, and ultraviolet‐visible (UV‐Vis) spectroscopy were applied to study the growth of Au NPs on the samples with and without OTS SAM resists. Copyright © 2009 John Wiley & Sons, Ltd.     

On the convergence of nonstationary column-oriented version of algebraic iterative methods

Recently, Elfving, Hansen, and Nikazad introduced a successful nonstationary block-column iterative method for solving linear system of equations based on flagging idea (called BCI-F). Their numerical tests show that the column-action method provides a basis for saving computational work using flagging technique in BCI algorithm. However, they did not present a general convergence analysis. In this paper, we give a convergence analysis of BCI-F. Furthermore, we consider a fully flexible version of block-column iterative method (FBCI), in which the relaxation parameters and weight matrices can be updated in each iteration and the column partitioning of coefficient matrix is allowed to update in each cycle. We also provide the convergence analysis of algorithm FBCI under mild conditions.     

Regio- and stereoselective synthesis of functionalized oxazolidin-2-ones from the reaction of α-epoxyketones with urea

A regio- and stereoselective synthesis of functionalized 4,5-disubstituted oxazolidin-2-ones is reported with moderate to good yields from the reaction of α-epoxyketones with urea in the presence of p-toluenesulfonic acid as the catalyst.