Stabilization of enhanced chirality from pyrene-containing l-glutamide lipid in methyl methacrylate by photo-induced polymerization

Enhanced CD spectra based on chirally-oriented structures of pyrene-containing L-glutamic acid-derived lipid were observed in polymerizable monomers and CD strength was maintained after photo-induced polymerization of the monomer solvents.     

NMR and MO Studies on the Molecular Structure of a Fluoranthene-Benzene Complex

Fluoranthene (FA) forms a 1:1 van der Waals complex with benzene in cyclohexane. The ¹H NMR spectrum of this complex shows that the FA moiety in the complex state has five kinds of hydrogen atoms and that the ¹H NMR peaks assigned to the protons attached to the naphthalene skeleton are largely shifted to higher magnetic field on complex formation with benzene. These observations indicate that the complex takes the structure of C_S symmetry, in which the benzene molecule mainly interacts with the electronic system localized on the naphthalene moiety of FA. The present ab initio calculations reproduce well the ¹H NMR spectral shifts mentioned above and the experimentally predicted C_S structure of the complex. According to the PPP calculations for the electronic absorption spectral changes on the complex formation, the FA-benzene complex is considered to take a sandwich type structure.     

High-energy quasi-phase-matched optical parametric oscillation in a 3-mm-thick periodically poled MgO:LiNbO3 device

We have demonstrated high-energy quasi-phase-matched optical parametric oscillation in a 3-mm-thick periodically poled 5-mol. % MgO-doped LiNbO3 device with a 32.1-microm grating period and a 30-mm length. With a large-spot-size pump laser of 2.2-mm diameter, we obtained a total output pulse energy of 22 mJ for both the signal (wavelength 1.82 microm) and the idler (2.56 microm) waves at an input pump energy of 46 mJ.     

Laser terahertz-emission microscope for inspecting electrical faults in integrated circuits

A laser terahertz-emission microscope (LTEM) system is proposed and developed for inspecting electrical faults in integrated circuits (IC). We test a commercial operational amplifier while the system is operating. Two-dimensional terahertz-emission images of the IC chip are clearly observed while the chip is scanned with a femtosecond laser. When one of the interconnection lines is cut, the damaged chip has a LTEM image different from that of normal chips. The results indicate that the LTEM system is a potential tool for IC inspection.     

Time-resolved Auger decay in CsBr using high harmonics

The temperature-dependent decay dynamics of innershell holes in CsBr was measured by using high harmonics. The measured lifetime was as short as 1.5 ps at 340 K due to increasing the Auger-allowed final state density in the Urbach exciton tail, whereas it is 1.1 ns at 10 K, determined by radiative recombination. The temperature-dependent Auger lifetime extrapolated to a high temperature corresponds to the fully energy-allowed Auger decay. In the model to be presented, this yields an interatomic Auger decay lifetime of 2.4+3.8/-1.5 fs, in line with a theoretical calculation for NaF.     

Plasma production by helicon and slow waves

The observation of slow-wave sustained (SW) discharge in a whistler- or helicon-wave range of frequency is made using high-frequency and very-high-frequency bands of rf. The SW discharge occurs at an extremely low rf power and plasma density, which are lower than a capacitive-coupling discharge region.     

Detection and evaluation of the depth of surface cracks in conductive materials by using a loop antenna

A new method is developed for detection and evaluation of the depth of surface cracks in conductive materials. The main components of the measurement equipment are a conductive wire and a loop antenna, both of which are located as close as possible to the surface of the investigated material, while the antenna loop is perpendicular to the surface and parallel to the wire. Supplying of electrical potential with microwave frequency f and amplitude |_s| to the wire results in spreading of induced current close beneath the surface of the material. The induced current redistributes in the vicinity of surface cracks, and some of the current paths flow along the crack walls. This leads to generation of a time-variable magnetic field mostly within the volume of the crack, which is detected by the loop antenna. A theoretical analysis is presented of the contributions of the different types of generated magnetic fields to the potential drop with amplitude |U_s| measured by the antenna. The distribution of the ratio R(dB)=|U|/|U_s| is measured for specimens of paramagnetic and ferromagnetic steel which contain three artificial cracks with depths of 0.5 mm, 1 mm, and 2 mm, and frequency f=300 MHz of the supplied electrical potential. It turns out that artificial cracks with a depth of d 0.5 mm, located at distances from x=3 mm to x=15 mm from the wire, can be detected. The largest sensitivity of crack detection is achieved for x4 mm when the long axis of a crack is perpendicular to the wire. The crack response of the measured ratio R is proportional to the crack depth when the loop of the antenna is located above or slightly outside an artificial crack, and at least 4 mm from the wire. This relation could be used for evaluation of the depth of real surface cracks. The notable decrement of the crack response outside the crack can indicate the location of the crack tips on the surface of the specimen. It is shown that a loop antenna with a diameter of 7 mm provides the largest crack response, as well as that the developed method can be applied to both paramagnetic and ferromagnetic materials. An example of the detection of a real crack by an antenna is reported for the first time. PACS 81.70.Ex; 84.40.Ba; 84.32.Ff     

Application of high pressure induced by water-freezing to the direct catalytic asymmetric three-component List-Barbas-Mannich reaction

High pressure induced by water-freezing has been successfully applied to the direct catalytic asymmetric-three component List-Barbas-Mannich reaction, in which higher yield and better enantioselectivity can be realized than those from the reaction at room temperature under 0.1 MPa.