全文获取类型
收费全文 | 264篇 |
免费 | 17篇 |
国内免费 | 2篇 |
专业分类
化学 | 220篇 |
晶体学 | 1篇 |
数学 | 3篇 |
物理学 | 59篇 |
出版年
2023年 | 4篇 |
2022年 | 6篇 |
2021年 | 12篇 |
2020年 | 10篇 |
2019年 | 12篇 |
2018年 | 8篇 |
2017年 | 8篇 |
2016年 | 11篇 |
2015年 | 11篇 |
2014年 | 8篇 |
2013年 | 19篇 |
2012年 | 17篇 |
2011年 | 26篇 |
2010年 | 7篇 |
2009年 | 9篇 |
2008年 | 17篇 |
2007年 | 11篇 |
2006年 | 11篇 |
2005年 | 11篇 |
2004年 | 4篇 |
2003年 | 7篇 |
2002年 | 4篇 |
2001年 | 4篇 |
1999年 | 1篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1980年 | 4篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1975年 | 4篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1969年 | 1篇 |
1968年 | 2篇 |
1966年 | 1篇 |
1963年 | 1篇 |
排序方式: 共有283条查询结果,搜索用时 203 毫秒
61.
A copper‐catalyzed migratory oxidative‐coupling reaction between nitrones and various ethers/amines exhibited high functional‐group tolerance. Even in aqueous media, the reaction proceeded efficiently. For practical use of this catalysis, a unique sequential Huisgen cycloaddition was demonstrated. Mechanistic investigations revealed that the reaction proceeded through oxidative catalytic activation of ethers/amines to afford iminium/oxonium intermediates by concurrent dual one‐electron abstractions by copper(II) and oxyl radicals. 相似文献
62.
63.
The combination method between asymmetric Kekulé structures (CMAK) was expanded to the structure prediction of a series of acenes and phenylenes. The structures predicted by the CMAK correspond to those calculated by the ab initio molecular orbital (MO) and B3LYP density functional methods. The CMAK can characterize the structures. The aromaticity for the whole ring and each ring in the treated compounds was estimated by the index of deviation from aromaticity (IDA). The estimated aromaticity corresponds fairly well to the characterization of the structure predicted by the CMAK. The predicted structures of linear acenes reveal the aromaticity of the central ring and also explain its reactivity. The side ring in [n]phenacene shows high aromaticity. The critical difference in the structure and aromaticity for the central six‐membered ring of the isomers benzo[1,2:4,5]dicyclobutene and benzo[1,2:5,6]dicyclobutene was explained. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
64.
Yousuke Ooyama Naoya Yamaguchi Shogo Inoue Tomoya Nagano Eigo Miyazaki Hiroshi Fukuoka Ichiro Imae Kenji Komaguchi Joji Ohshita Yutaka Harima 《Tetrahedron》2012,68(2):529-533
We have newly designed and synthesized unsymmetrical carbazole-type D–π–A fluorescent dyes. The dyes show a bathochromic shift-type mechanofluorochromism (MFC): grinding of as-recrystallized dyes induces a bathochromic shift of fluorescent color and the fluorescent color is recovered by heating or exposure to solvent vapor. In order to clarify the MFC mechanism for the carbazole-type D–π–A fluorescent dyes, time-resolved fluorescence spectroscopy, X-ray powder diffractometry, single-crystal X-ray structural analysis, IR spectroscopy, and differential scanning calorimetry are performed before and after grinding of the solids. On the basis of experimental results and semi-empirical molecular orbital calculations (AM1 and INDO/S), we have revealed that the MFC is attributed to a reversible switching between crystalline and amorphous states with changes of intermolecular hydrogen bonding and π–π interaction. 相似文献
65.
Enantioselective direct aldol reaction of α-substituted nitroacetates with aqueous formaldehyde for the synthesis of α-alkyl serines has been achieved under base-free neutral phase-transfer conditions with a bifunctional chiral phase-transfer catalyst. 相似文献
66.
Prof. Hidemitsu Uno Kota Muramatsu Shogo Hiraoka Hiroyuki Tahara Mako Hirose Eidai Tamura Tatsumi Shiraishi Dr. John Mack Prof. Nagao Kobayashi Dr. Shigeki Mori Dr. Tetsuo Okujima Dr. Masayoshi Takase 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(25):5701-5708
A bicyclo[2.2.2]octadiene(BCOD)-fused bis(dipyrromethane) derivative was reacted with methylal in the presence of trifluoroacetic acid followed by oxidation with chloranil to give a doubly N-confused phlorin derivative, which did not undergo the retro-Diels–Alder reaction extruding an ethylene molecule on heating. In contrast, a 7-tert-butoxybicyclo[2.2.1]heptadiene(7-BuOBCHD)-fused bis(dipyrromethane) yielded benzene-ring-fused doubly N-confused porphyrins by following similar reaction sequences. 相似文献
67.
Shuntaro Mataka Kazufumi Takahashi Masashi Tashiro Wei-Hua Lin Shin-Ichi Iwasaki Tetsuo Tsutsui Shogo Saito Shinji Akiyama Tadashi Yonemitsu 《Journal of heterocyclic chemistry》1989,26(1):215-219
Reversible color change of 4,6,7-tri(alkoxy-substituted phenyl)-1,2,5-thiadiazolo[3,4-c]pyridines 5 in the solid state was observed: on grinding, yellow crystals of 5 became an orange amorphous solid which, on heating or washing with an appropriate solvent, gave the original yellow crystals. 相似文献
68.
The synthesis of marine dolabellane diterpenoids claenone, palominol and dolabellatrienone was conducted from d-mannitol. In each case, formation of the bicyclo[2.2.1]heptane derivative by sequential Michael reaction, preparation of the tetrasubstituted cyclopentane derivative by retro-aldol reaction and cyclization of sulfone were involved as key steps. 相似文献
69.
Makoto Ohki Haruo Sakurai Shogo Kozaki 《International Journal of Infrared and Millimeter Waves》1997,18(10):2031-2045
This paper is described for T-matrix analysis of the electromagnetic wave diffraction from a Fourier grating that the boundary
value problem is treated by applying the extended boundary condition. The rigorous form of the expression of matrix elements
is presented in the term of Bessel functions of the first kind. The error of power conservation versus the truncated number
has been examined for mode number. Diffraction efficiencies versus groove depth and wavelength for a second or third harmonic
wave of Fourier grating have been discussed. Numerical results are in good agreement with those obtained from other method
and experimental values. Reasonable numerical results are presented for a groove depth per period of the Fourier grating less
than 0.25. 相似文献
70.
Masahiro Hayashi Shogo Tawada Yoshihiro Kubota Yoshihiro Sugi Jong Ho Kim 《Reaction Kinetics and Catalysis Letters》2004,83(2):329-335
Although extensive isomerization of 4,4'-diisopropylbiphenyl (4,4'-DIPB) occurred at 300oC over H-mordenite, high selectivity for 4,4'-DIPB among DIPB isomers was observed over silica-modified H-mordenite. This
is due to the prevention of the isomerization of 4,4'-DIPB by the deactivation of external acid sites.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献