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21.
Madhura Marathe Jérôme Lagoute Vincent Repain Sylvie Rousset Shobhana Narasimhan 《Surface science》2012,606(11-12):950-955
We have studied electronic structure of Fe-deposited Au(111) by performing ab initio density functional theory calculations. We find that the magnetic moment on the deposited Fe layer is enhanced as compared to that in bulk iron. We observe a large number of new states on the Fe-deposited surface — one of which is in the majority spin channel having similar dispersion to that on the clean surface, and others in the minority spin channel. The effective mass of electrons in surface states near the Fermi level increases on Fe deposition. The electronic properties are found to be insensitive to the stacking of near-surface layers. We need to use very thick slabs in our calculations to avoid splitting of surface states due to spurious interactions between the two surfaces of the slab. Using the local density of states profiles for different surface states, we conclude that in scanning tunneling microscope experiments one can detect two of the surface states — one in the majority channel below the Fermi level, and another in the minority channel appearing just above the Fermi energy. We compare our results to those from scanning tunneling spectroscopy experiments. 相似文献
22.
In the present investigation, we describe some novel calixarene based heterocyclic compounds (5a-5i) in which 1,3,4-oxadiazole and 1,3,4-thiadiazole derivatives have been coupled with 5,11,17,23-tetra-tert-butyl-25,27-bis(chlorocarbonyl-methoxy)-26,28-dihydroxy calix[4]arene. All the newly synthesized calixarene based heterocyclic compounds have been characterized by elemental analysis and various spectroscopic methods like FTIR, (1)H NMR, (13)C NMR, and FAB-MS. All the final scaffolds have been subjected to antioxidant activity, in vitro antimicrobial screening against two gram (+ve) bacteria (S. aureus, S. pyogenes), two gram (-ve) bacteria (E. coli, P. aeruginosa) and two fungal strains (C. albicans, A. clavatus) and also have been screened for their antitubercular activity against Mycobacterium tuberculosis H(37)Rv. 相似文献
23.
Krishnaswamy R Ghosh SK Lakshmanan S Raghunathan VA Sood AK 《Langmuir : the ACS journal of surfaces and colloids》2005,21(23):10439-10443
We have characterized the phase behavior of mixtures of the cationic surfactant cetyltrimethylammonium bromide (CTAB) and the organic salt 3-sodium-2-hydroxy naphthoate (SHN) over a wide range of surfactant concentrations using polarizing optical microscopy and X-ray diffraction. A variety of liquid crystalline phases, such as hexagonal, lamellar with and without curvature defects, and nematic, are observed in these mixtures. At high temperatures the curvature defects in the lamellar phase are annealed gradually on decreasing the water content. However, at lower temperatures these two lamellar structures are separated by an intermediate phase, where the bilayer defects appear to order into a lattice. The ternary phase diagram shows a high degree of symmetry about the line corresponding to equimolar CTAB/SHN composition, as in the case of mixtures of cationic and anionic surfactants. 相似文献
24.
The title compound is orthorhombic witha = 26·132(6),b = 11·023(2),c = 8·317(5), ?; space group Iba2;Z = 8,D
m
= 1·21(1),D
c
= 1·192 Mg m−3, 1/2(H2O) per molecule in asymmetric unit; λ (MoKα) = 0·7107A; μ = 0·46 cm−1; F(000) = 936. The structure was solved by direct methods and refined to R(F) value of 0·069 using 327 reflections withF ≥ 5σ(F) out of 727 independent reflections for2τ max = 46°. Thetrans fused cyclohexane and cyclohexanone rings form layers along thea-b plane. The axial methyl attached at the bridge-head, interlocks with the translated methylene of the cyclobutane fused across
the cyclohexane ring. The equatorial hydroxyl at the bridge-head adjacent to the methyl junction and the water molecule on
the two-fold form a water bridge along thez axis. The packing is reminiscent of that observed for the cholesterols used in membrane structure studies. 相似文献
25.
The development of devices made of micro- and nano-structured thin film materials has resulted in the need for advanced measurement techniques to characterize their mechanical properties. Photoacoustic techniques, which use pulsed laser irradiation to nondestructively induce very high frequency ultrasound in a test object via rapid thermal expansion, are suitable for nondestructive and non-contact evaluation of thin films. In this paper, we compare two photoacoustic techniques to characterize the mechanical parameters of edge-supported aluminum and silicon nitride double-layer thin films. The elastic properties and residual stresses in such films affect their mechanical performance. In a first set of experiments, a femtosecond transient pump–probe technique is used to investigate the Young’s moduli of the aluminum and silicon nitride layers by launching ultra-high frequency bulk acoustic waves in the films. The measured transient signals are compared with simulated transient thermoelastic signals in multi-layer structures, and the elastic moduli are determined. Independent pump–probe tests on silicon substrate-supported region and unsupported region are in good agreement. In a second set of experiments, dispersion curves of the A0 mode of the Lamb waves that propagate along the unsupported films are measured using a broadband photoacoustic guided-wave method. The residual stresses and flexural rigidities for the same set of double-layer membranes are determined from these dispersion curves. Comparisons of the results obtained by the two photoacoustic techniques are made and discussed. 相似文献
26.
Srisailam S Kumar TK Srimathi T Yu C 《Journal of the American Chemical Society》2002,124(9):1884-1888
Effect(s) of organic solvents on an all beta-sheet protein are investigated to understand the influence of backbone conformation on protein aggregation. Results obtained in the present study reveal that protein aggregation is accompanied by the formation of non-native beta-sheet conformation. In contrast, induction of non-native helical segments in the protein is found to inhibit aggregation. The differential effects of the secondary structures on protein aggregation are proposed to stem from the disparity in the nature of the hydrogen bonds and packing of the side chains of hydrophobic residues in the beta-sheet and alpha-helix conformation. In our opinion, the results of the present study provide useful hints to develop methods to alleviate the problems of both in vitro and in vivo protein aggregation. 相似文献
27.
Rema Krishnaswamy Hynd Remita Marianne Impéror-Clerc Catherine Even Patrick Davidson Brigitte Pansu 《Chemphyschem》2006,7(7):1510-1513
Single-crystalline platinum nanorods, monodisperse in diameter, are synthesized through a simple process at room temperature, in cetyltrimethyl ammonium bromide (CTAB) solution. The complexation of the CTA+ surfactant ion with tetrachloroplatinate in the presence of hexanol leads to the formation of a precipitate with a lamellar crystalline structure. The reduction of Pt(II) metal ions to Pt(0) is carried out using gamma radiolysis. Transmission electron microscopy (TEM) observations of the nanoparticles extracted from the solution, three weeks after radiolysis, revealed single-crystalline Pt nanorods, monodisperse in diameter (3-4 nm) and 20-60 nm long. By following the shape of the nanorods at various stages of the growth, it was found that the single-crystalline nanorods grow by coalescence of spherical seeds 3-4 nm in diameter. This suggests an aggregative mechanism similar to that recently observed for silver particles in solution. 相似文献
28.
Structures of complexes formed in aqueous solutions by some anionic polyelectrolytes (double and single stranded (ds and ss)
DNA, poly(vinyl sulfonate) (PVS), and poly(styrene sulfonate) (PSS)) with a cationic surfactant system consisting of cetyltrimethylammonium
bromide (CTAB) and sodium 3-hydroxy-2-naphthoate (SHN) have been determined using small angle X-ray diffraction. All complexes
are found to have a two-dimensional (2-D) hexagonal structure at low SHN concentrations. Analysis of the diffraction data
shows that the ds DNA—CTAB complex has an intercalated structure, with each DNA strand surrounded by three cylindrical micelles.
On increasing SHN concentration, DNA—CTAB—SHN complexes exhibit a hexagonal-to-lamellar transition, whereas PVS complexes
show a hexagonal → centered rectangular → lamellar transition. PSS complexes show yet another sequence of structures. These
results indicate the significant influence of the chemical nature of the polyelectrolyte on the structure of the complexes. 相似文献
29.
30.
Energy deficit spectra of field ions coming from above a single atomic site are measured by using an atom-probe FIM modified with a Möllenstedt energy analyzer. This device offers a resolution of 5 × 10?5 and is inherently more efficient and less noisy than a retarder. The energy spectra made up of 10 to 100 ions/sec are displayed on the screen of an assembly of two microchannel plates and are photographically recorded within a few seconds. Jason peaks for H2+ and Ne+ are confirmed, and are also found for He+. High-order multiple peaks appear when ions are taken from the flat, closely packed net planes of W and Ir field ion emitters. The results are in quantitative agreement with a resonance model similar to one by Alferieff and Duke and by Jason. Noble gas ions are also observed from the forbidden zone near the surface, and interpreted as apex-adsorbed atoms ionized by or after excitation by the electron shower coming from farther-out field ionization of other gas atoms. Energy from excited metastable apex-adsorbed atoms may account for artifact vacancies observed particularly when field evaporation is performed in neon. 相似文献