全文获取类型
收费全文 | 474篇 |
免费 | 15篇 |
国内免费 | 1篇 |
专业分类
化学 | 400篇 |
晶体学 | 5篇 |
力学 | 1篇 |
数学 | 32篇 |
物理学 | 52篇 |
出版年
2023年 | 3篇 |
2022年 | 6篇 |
2021年 | 11篇 |
2020年 | 11篇 |
2019年 | 8篇 |
2018年 | 6篇 |
2017年 | 5篇 |
2016年 | 17篇 |
2015年 | 7篇 |
2014年 | 10篇 |
2013年 | 25篇 |
2012年 | 34篇 |
2011年 | 36篇 |
2010年 | 8篇 |
2009年 | 6篇 |
2008年 | 26篇 |
2007年 | 18篇 |
2006年 | 21篇 |
2005年 | 23篇 |
2004年 | 15篇 |
2003年 | 12篇 |
2002年 | 13篇 |
2001年 | 14篇 |
2000年 | 11篇 |
1999年 | 7篇 |
1998年 | 4篇 |
1994年 | 6篇 |
1992年 | 7篇 |
1991年 | 3篇 |
1988年 | 4篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 9篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 7篇 |
1980年 | 3篇 |
1979年 | 7篇 |
1978年 | 9篇 |
1977年 | 4篇 |
1976年 | 7篇 |
1975年 | 4篇 |
1974年 | 8篇 |
1973年 | 10篇 |
1970年 | 2篇 |
1968年 | 2篇 |
1963年 | 2篇 |
1961年 | 2篇 |
1959年 | 2篇 |
排序方式: 共有490条查询结果,搜索用时 7 毫秒
31.
Yoshikazu Shizuri Yoshishige Okuno Hideyuki Shigemori Shosuke Yamamura 《Tetrahedron letters》1987,28(52):6661-6664
(±)-8,14-Cedranoxide has been synthesized starting from 3,4-dimethoxyphenol, wherein 6-acetoxymethyl-2,6-dimethyl-9-methoxytricyclo[5.3.1.01,5]undec-9-en-8,11-dione as a key intermediate has been produced efficiently by means of electrochemical methods. 相似文献
32.
Extraction chromatography using macroreticular ethylstyrene-divinylbenzene beads impregnated with monothiodibenzoylmethane (SBB) solution has been investigated. Of the solvents used as the stationary phase, heptan-1-ol showed the highest rate of metal extraction, and loading with 0.5 ml of the solvent per g of resin was found to be the optimum. A column packed with such loaded beads can be used for the separation of nickel(II), iron(III) and cobalt(II). 相似文献
33.
Motoko S. Asano Sho Hashimoto Takuya Shinozuka Yasutaka Fushimi 《Molecular physics》2019,117(19):2664-2672
ABSTRACTInteraction between a zinc porphyrin (ZnPor) as the end-group and poly(9,9-di-n-octylfluorene-2,7-vinylene) (PFV) as the main chain in a porphyrin end-modified fluorescent conjugated polymer, ZnPFV, was studied by time-resolved electron paramagnetic resonance (EPR) and fluorescence spectroscopy. While fluorescence from the PFV part of ZnPFV showed a spectral profile almost identical to that of a PFV oligomer without end-modification, the emission spectrum of the ZnPor part exhibited a much broader profile compared to that of the reference zinc porphyrin monomer. Based on the analysis of lifetimes and quantum yields, it was found that radiative rate constant of the ZnPor part was enhanced by nearly three times. The observed unusual enhancement in the radiative rate constant was rationalised in terms of a partial π-conjugation between the end group and the main chain, as a result of co-planarisation in fluid solution. On the other hand, the time-resolved EPR spectrum of ZnPFV at 100?K basically showed a similar spectral pattern to that of the reference zinc porphyrin, but with significant differences in zero-field spitting parameters and initial population ratios. The π-system of the excited triplet state is deduced to deviate from D4h symmetry in the end zinc porphyrin groups. The obtained results show that interaction of the porphyrin end group with the main chain of the polymer significantly influences the excited singlet state properties of the porphyrin, while its triplet state properties were affected to a lesser extent. 相似文献
34.
35.
36.
37.
Katsuyoshi Kakinuma Hiroshi Yamamura Hajime Haneda Tooru Atake 《Solid State Ionics》2001,140(3-4):301-306
(Ba1−xLax)2In2O5+x, whose end member is Ba2In2O5, is an oxygen-deficient perovskite oxide showing high oxide-ion conductivity. In order to clarify the reason why the high oxide ion conductivity appeared in this system, the electrical conductivity was measured as a function of temperature and La content. With an increasing La content, the discontinuous jump of ion conductivity in the Arrhenius plot, which is related to the disordering of the oxygen vacancies, disappeared for the sample with x0.2. Above x=0.12, the ion conductivity linearly increased with La content, while the activation energy remained constant with respect to the La content. Moreover, the conductivity for x=0.6 was 0.042 (S/cm) at 1073 K, which exceeded that of 8 mol% yttria-stabilized zirconia. The higher oxide-ion conductivity of this system could be dominated by the amount of mobile oxygen ions. 相似文献
38.
Sho Inagaki Akari Sato Haruka Sato Satoru Tamura Tomikazu Kawano 《Tetrahedron letters》2017,58(52):4872-4875
A simple and efficient synthesis of 4,5-dihydro-4-oxo-3-furancarboxylates using an acylative intramolecular cyclization of sulfonium salts is described. The reaction involved the efficient formation of a mixed anhydride between a linear carboxylic acid and trifluoroacetic anhydride in the presence of N-methylimidazole, followed by the sequential conversion into a highly reactive acylammonium species in situ. This procedure is easily handled, uses readily available inexpensive reagents, and provides a variety of 2-substituted 4,5-dihydro-4-oxo-3-furancarboxylates. 相似文献
39.
A ring-closing metathesis reaction of allenynes occurred at room temperature in the presence of a molybdenum alkylidene complex to give ring-closed vinylallenes. The vinylallene skeletons were constructed by a metathesis-type reaction between the alkyne moiety and the proximal carbon-carbon double bond of the allene moiety. [reaction: see text] 相似文献
40.
Sakamoto N Ikeda C Yamamura M Nabeshima T 《Journal of the American Chemical Society》2011,133(13):4726-4729
Novel pentacoordinate dipyrrin-silicon complexes showed efficient red or near-IR fluorescence, and the structural interconversion between silanol and siloxane derivatives resulted in significant changes in the optical properties. 相似文献