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41.
Ruili Zhang Tomonori Maeda Sho Kusaka Kei-ichiro Murai 《Journal of solid state chemistry》2010,183(3):620-623
Host lattice Ba3Si5O13−δNδ oxonitridosilicates have been synthesized by the traditional solid state reaction method. The lattice structure is based on layers of vertex-linked SiO4 tetrahedrons and Ba2+ ions, where each Ba2+ ion is coordinated by eight oxygen atoms forming distorted square antiprisms. Under an excitation wavelength of 365 nm, Ba3Si5O13−δNδ:Eu2+ and Ba3Si5O13−δNδ:Eu2+,Ce3+ show broad emission bands from about 400-620 nm, with maxima at about 480 nm and half-peak width of around 130 nm. The emission intensity is strongly enhanced by co-doping Ce3+ ions into the Ba3Si5O13−δNδ:Eu2+ phosphor, which could be explained by energy transfer. The excitation band from the near UV to the blue light region confirms the possibility that Ba3Si5O13−δNδ:Eu2+, Ce3+ could be used as a phosphor for white LEDs. 相似文献
42.
Toshiyuki Kikuta Sho Takemori 《Abhandlungen aus dem Mathematischen Seminar der Universit?t Hamburg》2014,84(2):257-266
In the case of Siegel modular forms of degree \(n\) , we prove that, for almost all prime ideals \(\mathfrak {p}\) in any ring of algebraic integers, mod \(\mathfrak {p}^m\) cusp forms are congruent to true cusp forms of the same weight. As an application we give congruences for the Klingen-Eisenstein series and cusp forms, which can be regarded as a generalization of Ramanujan’s congruence. We will conclude by giving numerical examples. 相似文献
43.
Let P be a point set on the plane, and consider whether P is quadrangulatable, that is, whether there exists a 2-connected plane graph G with each edge a straight segment such that V(G) = P, that the outer cycle of G coincides with the convex hull Conv(P) of P, and that each finite face of G is quadrilateral. It is easy to see that it is possible if and only if an even number of points of P lie on Conv(P). Hence we give a k-coloring to P, and consider the same problem, avoiding edges joining two vertices of P with the same color. In this case, we always assume that the number of points of P lying on Conv(P) is even and that any two consecutive points on Conv(P) have distinct colors. However, for every k ≥ 2, there is a k-colored non-quadrangulatable point set P. So we introduce Steiner points, which can be put in any position of the interior of Conv(P) and each of which may be colored by any of the k colors. When k = 2, Alvarez et al. proved that if a point set P on the plane consists of \({\frac{n}{2}}\) red and \({\frac{n}{2}}\) blue points in general position, then adding Steiner points Q with \({|Q| \leq \lfloor \frac{n-2}{6} \rfloor + \lfloor \frac{n}{4} \rfloor +1}\) , P ∪ Q is quadrangulatable, but there exists a non-quadrangulatable 3-colored point set for which no matter how many Steiner points are added. In this paper, we define the winding number for a 3-colored point set P, and prove that a 3-colored point set P in general position with a finite set Q of Steiner points added is quadrangulatable if and only if the winding number of P is zero. When P ∪ Q is quadrangulatable, we prove \({|Q| \leq \frac{7n+34m-48}{18}}\) , where |P| = n and the number of points of P in Conv(P) is 2m. 相似文献
44.
Sho Suda 《Discrete Mathematics》2012,312(10):1827-1831
The Erd?s–Ko–Rado theorem is extended to designs in semilattices with certain conditions. As an application, we show the intersection theorems for the Hamming schemes, the Johnson schemes, bilinear forms schemes, Grassmann schemes, signed sets, partial permutations and restricted signed sets. 相似文献
45.
Y Fujii M Teranishi K Nakada M Yamazaki S Kishida S Miyabo 《Chemical & pharmaceutical bulletin》1992,40(2):410-413
A specific assay method has been developed for the determination of 2-methoxyestriol in plasma of pregnant women. The quantitation was achieved by radioimmunoassay after extraction of the plasma with ethyl acetate and purification on a Sephadex LH-20 column. In order to obtain the immunogen for 2-methoxyestriol, 6-oxo-2-methoxyestriol was converted to its 6-(O-carboxymethyl)oxime derivative. The derivative was then coupled to bovine serum albumin by the mixed anhydride method, and rabbits were immunized with this conjugate. The antiserum obtained was partially purified by affinity chromatography on estrone 17-(O-carboxymethyl)oxime-aminohexyl Sepharose conjugate to eliminate the cross-reactive antibodies. Plasma 2-methoxyestriol concentrations in pregnancy were estimated to be mean values of 41.1 pg/ml (12th-14th week), 85.3 pg/ml (27th-29th week), and 97.5 pg/ml (37th-41st week). 相似文献
46.
Fujii S Mochizuki M Aono K Hamasaki S Murakami R Nakamura Y 《Langmuir : the ACS journal of surfaces and colloids》2011,27(21):12902-12909
Polystyrene (PS) latex particles carrying pH-responsive poly[2-(diethylamino)ethyl methacrylate] (PDEA) hair (PDEA-PS particles) were synthesized by dispersion polymerization and characterized in terms of diameter, diameter distribution, morphology, chemical composition, surface chemistry, and pH-response using scanning electron microscopy (SEM), elemental microanalysis, (1)H nuclear magnetic resonance spectroscopy, the laser diffraction method, and zeta potential measurements. The hairy particles can act as pH-responsive stabilizers of aqueous foams by adsorption at the air-water surface. Above pH 8.0, where particles have nonprotonated PDEA hair, which is relatively hydrophobic, particle-stabilized foams are stable for at least 1 month. Optical microscopy and SEM confirmed that flocculated PDEA-PS latex particles were adsorbed at the air-water interface and stabilized the aqueous foams. At pH 6.1 and 7.1, relatively stable foams can be prepared that remain stable for at least 24 h. SEM studies indicated that the PDEA-PS particles were adsorbed at the air-water interface as a monolayer at pH 6.1. At pH 5.1 and 3.1, where the particles have cationic water-soluble PDEA hairs with hydrophilic character, no foam was formed. Rapid defoamation can be induced by lowering the solution pH; the addition of acid caused the in situ protonation of 2-(diethylamino)ethyl methacrylate residues, which impart water-soluble hydrophilic character to the PDEA hair, and the PDEA-PS particles desorbed from the air-water interface. The foaming and defoaming cycles could be repeated at least five times. 相似文献
47.
Nakamura Y Inomata S Ebine M Manabe Y Iwakura I Ueda M 《Organic & biomolecular chemistry》2011,9(1):83-85
We report on the design, synthesis and assessment of a novel biaryl-linked (BArL) molecular probe for the exploration of low-abundant target proteins for bioactive compounds based on the activity based protein profiling (ABPP) approach. Surprisingly, the performance of the BArL probe was better than that of the stepwise tagging approach that is considered to be the most effective method used in ABPP study. 相似文献
48.
Ginet P Montagne K Akiyama S Rajabpour A Taniguchi A Fujii T Sakai Y Kim B Fourmy D Volz S 《Lab on a chip》2011,11(8):1513-1520
Metal electrodes with micron scale width enable the heating of less than a dozen cells in a confluent layer at predictable temperatures up to 85 °C with an accuracy of ±2 °C. Those performances were obtained by a preliminary robust temperature calibration based on biotin-rhodamine fluorescence and by controlling the temperature map on the substrate through thermal modeling. The temperature accuracy was proved by inducing the expression of heat shock proteins (HSP) in a few NIH-3T3 cells through a confined and precise temperature rise. Our device is therefore effective to locally induce a heat shock response with almost single-cell resolution. Furthermore, we show that cells heated at a higher temperature than the one of heat shock remain alive without producing HSP. Electrode deposition being one of the most common engineering processes, the fabrication of electrode arrays with a simple control circuit is clearly within reach for parallel testing. This should enable the study of several key mechanisms such as cell heat shock, death or signaling. In nanomedicine, controlled drug release by external stimuli such as for example temperature has attracted much attention. Our device could allow fast and efficient testing of thermoactivable drug delivery systems. 相似文献
49.
Eiichi Masumoto Hiroshi Maruoka Fumi Okabe Sho Nishida Yuki Yoshimura Toshihiro Fujioka Kenji Yamagata 《Journal of heterocyclic chemistry》2011,48(1):96-104
Dihydropyridazinones 4a , 4b , N‐substituted dihydropyrazoles 5b , 5c , 5d , and O‐substituted pyrazoles 6a , 6b , 6c , 6d have been synthesized starting from spirocyclopropanepyrazole derivative 2 . Treatment of 2 with α‐chloro esters, e.g., methyl chloroacetate, ethyl chloroacetate, isopropyl chloroacetate, and tert‐butyl chloroacetate, in potassium carbonate/sodium iodide system caused ring opening and subsequent C‐ or N‐attack nucleophilic substitution to give the corresponding dihydropyridazinones 4a , 4b and N‐substituted dihydropyrazoles 5b , 5c , 5d . On the other hand, in the absence of sodium iodide, O‐substituted pyrazoles 6a , 6b , 6c , 6d were obtained from 2 via an O‐attack nucleophilic substitution. J. Heterocyclic Chem., 2011. 相似文献
50.