全文获取类型
收费全文 | 2866篇 |
免费 | 73篇 |
国内免费 | 12篇 |
专业分类
化学 | 2238篇 |
晶体学 | 38篇 |
力学 | 24篇 |
数学 | 50篇 |
物理学 | 601篇 |
出版年
2022年 | 15篇 |
2021年 | 24篇 |
2020年 | 20篇 |
2019年 | 30篇 |
2018年 | 16篇 |
2017年 | 22篇 |
2016年 | 46篇 |
2015年 | 45篇 |
2014年 | 48篇 |
2013年 | 97篇 |
2012年 | 153篇 |
2011年 | 181篇 |
2010年 | 92篇 |
2009年 | 97篇 |
2008年 | 161篇 |
2007年 | 170篇 |
2006年 | 149篇 |
2005年 | 165篇 |
2004年 | 142篇 |
2003年 | 128篇 |
2002年 | 98篇 |
2001年 | 102篇 |
2000年 | 75篇 |
1999年 | 67篇 |
1998年 | 33篇 |
1997年 | 38篇 |
1996年 | 32篇 |
1995年 | 30篇 |
1994年 | 25篇 |
1993年 | 27篇 |
1992年 | 40篇 |
1991年 | 31篇 |
1990年 | 37篇 |
1989年 | 27篇 |
1988年 | 17篇 |
1987年 | 35篇 |
1986年 | 18篇 |
1985年 | 32篇 |
1984年 | 33篇 |
1983年 | 19篇 |
1982年 | 34篇 |
1981年 | 31篇 |
1980年 | 22篇 |
1979年 | 41篇 |
1978年 | 23篇 |
1977年 | 20篇 |
1976年 | 15篇 |
1975年 | 17篇 |
1974年 | 19篇 |
1973年 | 15篇 |
排序方式: 共有2951条查询结果,搜索用时 0 毫秒
21.
Toyoda M Ishihara M Yamaguchi S Ito H Matsuo T Roll R Rosenbauer H 《Journal of mass spectrometry : JMS》2000,35(2):163-167
A new type of multi-turn time-of-flight mass spectrometer was constructed, consisting of four cylindrical electric sectors and 28 electric quadrupole lenses, the size of the vacuum chamber being 60 x 70 x 20 cm. It was demonstrated that the mass resolution can be increased according to the number of cycles of the ions through the ion optical system. 相似文献
22.
23.
24.
Ohwada T Miura M Tanaka H Sakamoto S Yamaguchi K Ikeda H Inagaki S 《Journal of the American Chemical Society》2001,123(42):10164-10172
N-Nitrosamines can be considered as potential nitric oxide (NO)/nitrosonium ion (NO(+)) donors. However, the relation of the structures of N-nitrosamines, in particular of aliphatic N-nitrosamines, to the characteristics of release of NO or NO(+) remains unclear. Here we show that aliphatic N-nitrosoamines of 7-azabicyclo[2.2.1]heptanes can undergo heterolytic N-NO bond cleavage. On the basis of the observation of reduced rotational barriers of the N-NO bonds in solution and nitrogen-pyramidal structures of the N-nitroso group in the solid state, we postulate that N-NO bond cleavage of N-nitrosamines is enhanced by a reduction of the resonance in the N-NO group. Computational studies suggest that these structural features of the N-nitrosamines of 7-azabicyclo[2.2.1]heptane are derived from angle strain imposed on the CNC angles. 相似文献
25.
26.
27.
Abe K Ahrens LA Amako K Aronson SH Beier EW Callas JL Cutts D Diwan M Durkin LS Gibbard BG Heagy SM Hedin D Hoftun JS Hurley M Kabe S Kurihara Y Lanou RE Mann AK Marx MD Murtagh MJ Nagashima Y Newcomer FM Shinkawa T Stern E Suzuki Y Terada S White DH Williams HH Yamaguchi Y 《Physical review letters》1987,58(7):636-639
28.
Nishimiya N Yamaguchi Y Ohrui Y Suzuki M 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2004,60(3):493-504
The mirror gap of a Fabry-Perot interferometer was stabilized with two laser diodes; one locked to the line frequency 385,243,555.14445 MHz of the F=3<--1 in 5D(3/2)<--5S(1/2) (87Rb) and the other to the 385,284,566.3663 MHz of the F=4<--2 in 5D(5/2)<--5S(1/2) (87Rb) [Opt. Commun. 102 (1993) 432]. The length of the mirror gap was adjusted to generate the zero-cross points simultaneously at both of the two line positions. The fringe signals obtained from an interferometer thus stabilized can be used as frequency markers having accuracies of the order of 10(10) depending on the finesse of the interferometer used. Based on measurement using Cs D1 hyperfine lines reported by Udem et al. [Phys. Rev. Lett. 82 (1999) 3568], the uncertainty of markers in the region 50 THz apart from the reference lines is +/- 5 MHz. 相似文献
29.
[structure: see text]. All stereoisomers of a cyclic alkyne containing three helicene units, 1,12-dimethylbenzo[c]phenanthrene, are synthesized using a building block. Isomeric [3 + 3]cycloalkynes aggregate in organic solvents. Vapor pressure osmometry reveals dimer formation of (M,M,M)-[3 + 3]cycloalkynes in chloroform and benzene at concentrations above 2 mM. No higher aggregation is observed. The chirality of helicenes plays an important role in self-aggregation, and diastereomeric (M,P,M)-[3 + 3]cycloalkyne forms a dimer only above 15 mM. Aggregation of racemic (M,M,M)-[3 + 3]cycloalkyne or (M,P,M)-[3 + 3]cycloalkyne is much weaker than that of a single enantiomer. 相似文献
30.
S. Tamai J. Kamada T. Ono T. Kuroki K. Goto A. Yamaguchi 《Journal of polymer science. Part A, Polymer chemistry》2002,40(3):423-428
Polyimide containing an indan unit and alkyl moiety with a high molecular weight was prepared from 5,7‐diamino‐1,1,4,6‐tetramethylindan and 3,3′,4,4′‐benzophenone tetracarboxylic dianhydride. This polyimide was amorphous and soluble in common organic solvents, such as tetrahydrofuran, chloroform, and cyclopentanone. Thermogravimetry of the polyimide showed good thermal stability, indicating that a 10% weight loss of the polyimide was observed at 500 °C in nitrogen. The glass‐transition temperature of the polyimide was not observed by DSC measurement between room temperature and 400 °C at a heating rate of 10 °C/min (Apparatus: DSC3100 MAC Science Co., Ltd.). Transparency of the polyimide at 365 nm was 80%. The polyimide acted as a photosensitive resist of negative type by UV radiation. The resist had a sensitivity of 31 mJ/cm2 and a contrast of 2.3 when it was developed with cyclopentanone at room temperature. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 40: 423–428, 2002 相似文献