全文获取类型
收费全文 | 2106篇 |
免费 | 422篇 |
国内免费 | 203篇 |
专业分类
化学 | 1386篇 |
晶体学 | 21篇 |
力学 | 109篇 |
综合类 | 12篇 |
数学 | 281篇 |
物理学 | 922篇 |
出版年
2024年 | 6篇 |
2023年 | 56篇 |
2022年 | 78篇 |
2021年 | 110篇 |
2020年 | 107篇 |
2019年 | 95篇 |
2018年 | 79篇 |
2017年 | 81篇 |
2016年 | 129篇 |
2015年 | 115篇 |
2014年 | 135篇 |
2013年 | 167篇 |
2012年 | 207篇 |
2011年 | 210篇 |
2010年 | 138篇 |
2009年 | 142篇 |
2008年 | 118篇 |
2007年 | 102篇 |
2006年 | 92篇 |
2005年 | 83篇 |
2004年 | 68篇 |
2003年 | 55篇 |
2002年 | 49篇 |
2001年 | 46篇 |
2000年 | 31篇 |
1999年 | 26篇 |
1998年 | 21篇 |
1997年 | 25篇 |
1996年 | 25篇 |
1995年 | 21篇 |
1994年 | 19篇 |
1993年 | 11篇 |
1992年 | 14篇 |
1991年 | 15篇 |
1990年 | 19篇 |
1989年 | 9篇 |
1988年 | 5篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 4篇 |
1974年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有2731条查询结果,搜索用时 0 毫秒
91.
92.
93.
用密度泛函B3LYP方法研究了过渡金属钐类卡宾与乙烯的环丙烷化反应的机理。对三种不同的钐的SS试剂CH_3SmCH_2X(其中X=Cl、Br和Ⅰ)分别和CH_2CH_2反应的各反应物、中间体、过渡态和产物构型的全部结构几何参数进行了优化,用内禀反应坐标(IRC)计算和频率分析方法,对过渡态进行了验证。结果表明:CH_3SmCH_2X(其中X=Cl、Br和Ⅰ)与CH_2CH_2环丙烷化反应按亚甲基转移通道(通道A)和卡宾金属化通道(通道B)都可以进行,与锂类卡宾的反应机理相同,只是按亚甲基转移通道(通道A)进行反应较容易一些,而且此反应在较低的温度下就可以发生。 相似文献
94.
Space-Selective Precipitation of Ba2TiSi2O8 Crystals in Sm3^+-Doped BaO-TiO2-SiO2 Glass by Femtosecond Laser Irradiation 下载免费PDF全文
The ferroelectric crystal Ba2TiSi2O8 with high second-order optical nonlinearity is precipitated in Sm^3+-doped BaO-TiO2-SiO2 glass by a focused 800hm, 250 kHz and 150fs femtosecond laser irradiation. No apparent blue and red emissions are observed at the beginning, while strong blue emission due to second harmonic generation and red emission due to the f-f transitions of Sm^3+ are observed near the focal point of the laser beam after irradiation for 25s. Micro-Raman spectra confirm that Ba2 TiSi2O8 crystalline dots and lines are formed after laser irradiation. The mechanism of the phenomenon is discussed. 相似文献
95.
采用甚高频等离子体增强化学气相沉积技术制备了系列微晶硅薄膜太阳电池,指出了气体总流量和背反射电极的类型对电池性能参数的影响.电池的I-V测试结果表明:随反应气体总流量的增加,对应电池的短路电流密度、开路电压和填充因子都有很大程度的提高,结果使得电池的光电转换效率得以提高.另外,ZnO/Ag/Al背反射电极能明显提高电池的短路电流密度,进而也提高了电池的光电转换效率.对气体总流量和背反射电极类型影响电池效率的原因进行了分析.
关键词:
微晶硅薄膜太阳电池
气体流量
ZnO/Ag/Al背反射电极 相似文献
96.
We demonstrate a new approach, i.e., a cw dual-frequency Brillouin fiber laser pumped by two independent single-frequency Er-doped fiber lasers, for the generation of tunable low-noise rf/microwave optical signals. Its inherent features of both linewidth narrowing effect in a Brillouin fiber cavity and common mode noise cancellation between two laser modes sharing a common cavity allow us to achieve high frequency stability without using a supercavity. Beat frequency of the dual-frequency Brillouin fiber laser can be tuned from tens of megahertz up to 100 GHz by thermally tuning the wavelengths of the two pump lasers with tuning sensitivity of approximately 1.4 GHz/ degrees C. Allan variance measurements show the beat signals have the hertz-level frequency stability. 相似文献
97.
We have established a caesium double magneto-optical trap (MOT) system for
cavity-QED experiment, and demonstrated the continuous transfer of cold caesium
atoms from the vapour-cell MOT with a pressure of ~ 1×10-6 Pa to
the ultra-high-vacuum (UHV) MOT with a pressure of ~ 8×10-8 Pa via a
focused continuous-wave transfer laser beam. The effect of frequency detuning as
well as the intensity of the transfer beam is systematically investigated, which
makes the transverse cooling adequate before the atoms leak out of the vapour-cell
MOT to reduce divergence of the cold atomic beam. The typical cold atomic flux got
from vapour-cell MOT is ~2×107 atoms/s. About 5×106
caesium atoms are recaptured in the UHV MOT. 相似文献
98.
Research on Chemical Intermediates - In order to explore the influence of the layers of graphene on the lithium-ion battery composites, to increase the electroconductivity of TiO2 and... 相似文献
99.
100.
Raghida Bou Zerdan Zhishuai Geng Benjaporn Narupai Yvonne J. Diaz Morgan W. Bates David S. Laitar Biswas Souvagya Antony K. Van Dyk Craig J. Hawker 《Journal of polymer science. Part A, Polymer chemistry》2020,58(14):1989-1997
The utility of pentafluorophenyl esters for the selective introduction of functional units and branch points in well-defined poly(acrylic acid) (PAA) derivatives is demonstrated using a combination of controlled radical polymerization and postpolymerization modification. Reversible addition-fragmentation chain transfer enables the synthesis of well-defined copolymers—poly(pentafluorophenyl acrylate-co-tert-butyl acrylate)—with the active ester repeat units serving as attachment points for reaction with primary amines, specifically tris(2-(t-butoxycarbonyl)ethyl)methyl amine (Behera's amine). Deprotection using trifluoroacetic acid removes both the backbone and side chain t-butyl esters to give a series of branched PAA derivatives containing novel tricarboxylic acid side chains that are well suited to complexation and multidentate interactions. Surprisingly, the active ester homopolymer is shown to have the highest reactivity with Behera's amine when compared to copolymers with lower incorporation of pentafluorophenyl esters, suggesting an intriguing interplay of neighboring group effects and steric interactions. The ability to tune the efficiency of postpolymerization modification gives a library of PAA derivatives. 相似文献