全文获取类型
收费全文 | 1189篇 |
免费 | 17篇 |
国内免费 | 8篇 |
专业分类
化学 | 908篇 |
晶体学 | 11篇 |
力学 | 5篇 |
数学 | 26篇 |
物理学 | 264篇 |
出版年
2023年 | 4篇 |
2022年 | 3篇 |
2021年 | 3篇 |
2020年 | 5篇 |
2018年 | 3篇 |
2016年 | 6篇 |
2015年 | 9篇 |
2014年 | 33篇 |
2013年 | 61篇 |
2012年 | 48篇 |
2011年 | 61篇 |
2010年 | 44篇 |
2009年 | 22篇 |
2008年 | 64篇 |
2007年 | 80篇 |
2006年 | 92篇 |
2005年 | 87篇 |
2004年 | 61篇 |
2003年 | 73篇 |
2002年 | 69篇 |
2001年 | 32篇 |
2000年 | 24篇 |
1999年 | 24篇 |
1998年 | 12篇 |
1997年 | 13篇 |
1996年 | 16篇 |
1995年 | 14篇 |
1994年 | 13篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1991年 | 8篇 |
1990年 | 12篇 |
1989年 | 6篇 |
1988年 | 10篇 |
1987年 | 19篇 |
1986年 | 7篇 |
1985年 | 16篇 |
1984年 | 15篇 |
1983年 | 6篇 |
1982年 | 18篇 |
1981年 | 8篇 |
1980年 | 11篇 |
1979年 | 11篇 |
1978年 | 16篇 |
1977年 | 10篇 |
1976年 | 7篇 |
1975年 | 4篇 |
1974年 | 12篇 |
1973年 | 12篇 |
1965年 | 3篇 |
排序方式: 共有1214条查询结果,搜索用时 15 毫秒
31.
Shiro Komba 《Tetrahedron letters》2004,45(13):2759-2762
A new hydroxy protecting group for convenient preparation of oligosaccharide was developed using uni-chemo protection (UCP) concept. The UCP group was comprised of polymerized amino acid derivatives and protecting each hydroxyl groups by ester linkage. Depending on the polymerization degree, the hydroxyl groups were characterized and controlled. Using this protecting group, two kinds of sialyl-T analogues were successfully synthesized from same sugar parts merely by repeating Edman degradation and coupling. 相似文献
32.
Some organogermanium oligomers with different side groups were synthesized via li-gand substitution polymerization from 1, 4-dioxane complex of germanium dichloride withdifferent organolithitum compounds. The oligomers were isolated through either precipi-tation from methanol or extraction using toluene with a yield of no less than 50%. Theweiglit average molecular weight (M_w) of the oligomers is ranging from 1.4×10~3 to 5.9×10~3depending on the type and alkyl length of the organolithium compounds used. 相似文献
33.
Bengu E Plass R Marks LD Ichihashi T Ajayan PM Iijima S 《Physical review letters》1996,77(20):4226-4228
34.
For simple depth selective conversion electron Mössbauer spectroscopy (CEMS) by using a He+CH4 proportional counter, a flexible and versatile CAMAC data acquisition system (KODAQ) which works on a popular Japanese personal computer PC9801VX (NEC) was applied. It is demonstrated that CEM spectra of the oxidized Fe thin film which is composed of Fe3O4, Fe1–xO and -Fe metal are successfully obtained. 相似文献
35.
Two-step preparation for catalyst-free biodiesel fuel production 总被引:10,自引:0,他引:10
Biodiesel fuel was prepared by a two-step reaction: hydrolysis and methyl esterification. Hydrolysis was carried out at a
subcritical state of water to obtain fatty acids from triglycerides of rapeseed oil, while the methyl esterification of the
hydrolyzed products of triglycerides was treated near the supercritical methanol condition to achieve fatty acid methyl esters.
Consequently, the two-step preparation was found to convert rapessed oil to fatty acid methyl esters in considerably shorter
reaction time and milder reaction condition than the direct supercritical methanol treatment. The optimum reaction condition
in this two-step preparation was 270°C and 20 min for hydrolysis and methyl esterification, respectively. Variables affecting
the yields in hydrolysis and methyl esterification are discussed. 相似文献
36.
37.
Raman spectra of stilbene mono- and di-negative ions in tetrahydrofuran solution were obtained by Ar+ laser exciting lines. A considerable frequency shift was observed for several vibrations in the successive steps: stilbene → (stilbene)? → (stilbene)2?. The observed shift is discussed in a simple VB scheme, particularly in comparison with the results on anthracene negative ions. The resonance Raman effect was striking for both ions with intensity maxima at the exciting wavelengths close to the absorption maxima. 相似文献
38.
The spectrum of magnetic resonance is typically affected by a modulated structure in an incommensurate phase, resulting in the broadened spectrum characterized by ‘edge singularities’. We demonstrate that the modulated structure in the crystal where molecular motion exists is responsible for the narrowing of the spectrum in the fast motional region by means of the simulation of 2H NMR spectrum of [Mg(H2O)6][SiF6]. The program developed by combining the theories of phase solitons in the incommensurate phase and motional change of 2H NMR spectrum was used for the simulation. We obtained a good agreement between the theoretical 2H NMR spectrum and experimental one for [Mg(H2O)6][SiF6]. 相似文献
39.
Takao Iijima Nobuyuki Sashida Hiroshi Kakiuchi 《Journal of polymer science. Part A, Polymer chemistry》1989,27(11):3651-3658
α-Methoxyphenylmethylium hexachloroantimonate was used as a novel initiator for the polymerization of α,β-disubstituted oxiranes such as cyclohexene oxide (CHO) and 2-butene oxide (trans and cis) (2-BO) at ?78°C with dichloromethane or dichloromethane-toluene mixtures as solvents. The CHO polymerization mixture became turbid and the polymer precipitated in dichloromethane. The CHO polymerization proceed quantitatively in dichloromethane–toluene mixtures. The molecular weight distribution of polyCHO obtained was bimodal regardless of the solvent used. The polymerization of trans-2-BO was heterogeneous in both dichloromethane and dichloromethane–toluene mixture. The polymerization mixtures of cis-2-BO were transparent but reached a limit yield which was less than the polymer yield of trans-2-BO. Furthermore, the microstructure of the poly2-BOs were analyzed by Vandenberg's method and the results confirmed Vandenberg's finding that inversion of configuration occurs in the propagation step. 相似文献
40.
Nakanishi I Miyazaki K Shimada T Iizuka Y Inami K Mochizuki M Urano S Okuda H Ozawa T Fukuzumi S Ikota N Fukuhara K 《Organic & biomolecular chemistry》2003,1(22):4085-4088
Electron-transfer reduction of molecular oxygen (O2) by the phenolate anion (1-) of a vitamin E model, 2,2,5,7,8-pentamethylchroman-6-ol (1H), occurred to produce superoxide anion, which could be directly detected by a low-temperature EPR measurement. The rate of electron transfer from 1- to O2 was relatively slow, since this process is energetically unfavourable. The one-electron oxidation potential of 1- determined by cyclic voltammetric measurements is sufficiently negative to reduce 2,2-bis(4-tert-octylphenyl)-1-picrylhydrazyl radical (DOPPH*) to the corresponding one-electron reduced anion, DOPPH-, suggesting that 1- can also act as an efficient radical scavenger. 相似文献