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101.
Anion photoelectron spectroscopy of acetonitrile cluster anions, (CH3CN)(-)(n) (n=10-100), successfully demonstrates the competitive coexistence of two different anionic species: a solvated electron and a solvent-bound valence anion. The distinctly different nature of these anions is revealed by hole-burning-type photoelectron spectroscopy and relative photodetachment cross section measurements. This unusual coexistence is attributed to the closely lying nature of their anionic states at just the number of solvent molecules sufficient to almost complete the first solvation layer. 相似文献
102.
Kawai K Takada T Nagai T Cai X Sugimoto A Fujitsuka M Majima T 《Journal of the American Chemical Society》2003,125(52):16198-16199
The hole transfer causes the long-lived charge-separated state in DNA during the photosensitized one-electron oxidation of DNA. The combination of the transient absorption measurement and DNA damage quantification by HPLC clearly demonstrated that the yield of the DNA damage correlates well with the lifetime of the charge-separated state. 相似文献
103.
104.
Hisatoyo Morinaga Yusuke Ujihara Naho Yuto Daisuke Nagai Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》2011,49(24):5210-5216
Metal‐free controlled ring‐opening polymerization of glycidyl phenyl ether (GPE) was achieved using tetra‐n‐butylammonium fluoride (Bu4NF) as an initiator in the presence of water and ethanol as chain transfer agents (CTAs). Number‐averaged molecular weight of poly(GPE) increased with an increase of [GPE]0/([Bu4NF]0 + [CTA]0) values, showing relatively narrow molecular weight distributions. NMR spectroscopic analysis exhibited a formation of ethoxy groups as well as FCH2 at the initiating polymer chain‐end when ethanol was used as the CTA in the polymerization. These results indicate that Bu4NF acts as a catalyst as well as the initiator for this polymerization system. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
105.
106.
Effect of refraction index and thickness of the light guide in the position-sensitive gamma-ray detector using compact PS-PMTs 总被引:1,自引:0,他引:1
Koji Inoue Haruo Saito Yasuyuki Nagashima Toshio Hyodo Yasuyoshi Nagai Shinichi Muramatsu Shota Nagai 《Radiation Physics and Chemistry》2000,58(5-6):763-766
We constructed a position-sensitive gamma-ray detector consisting of an array of BGO scintillators, a light guide and compact PS-PMTs. The effects of refractive index and thickness of the light guide of a glass plate on the detector performance were investigated. A light guide with higher refractive index and smaller thickness is found better for a good spatial resolution. 相似文献
107.
Daisuke Nagai Asuka Fujii Masayoshi Tanaka Bungo Ochiai Atsushi Sudo Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》2009,47(6):1510-1521
Anionic polymerization of methacrylates under sterically confined environment in a spherical beads‐shaped networked polystyrene (NwPS) matrix is described. The initiator used herein is a samarium (Sm) (III) enolate, which was formed by treatment of 2‐bromoisobutylate immobilized in the side chain of NwPS with Sm (II) iodide. By using this NwPS‐bound initiator, polymerization of a series of methacrylates (=solid‐supported polymerization) was studied to find its two aspects: (1) In the early stages, the rate constant for each methacrylate was comparable to that for its conventional solution‐phase polymerization using a Sm (III) enolate, suggesting that methacrylate can be efficiently supplied to the propagating end by its free permeation without any interference by the networked structure of the matrix. (2) After the early stages, the rate constant decreased remarkably, implying that permeation of methacrylate was sterically interfered by the formed poly(methacrylate) that filled the confined space in NwPS, as supported by a SEM image of the resulting beads, of which pores were filled with the formed polymers. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1510–1521, 2009 相似文献
108.
H. Nagai N. Oyama H. Yoshie A. Tsujimura 《Journal of magnetism and magnetic materials》1987,70(1-3):171-172
The educed Gd atoms in the X-structure (Th6Mn23-type) of Gd(Fe1−xMnx)2 were magnetically investigated by comparing with Gd6(Fe1−yMny)23 whose structure is Th6Mn23-type. The magnetic properties of Gd(Fe1−xMnx)2 (0.4≤x≤0.7) were observed to be quite similar to those of Gd6(Fe1−yMny)23 (0.4≤y≤0.7). 相似文献
109.
Akira Tanaka Mitsuhiro Fukuda Hiroyuki Nagai Masayuki Shinohara Shigeharu Onogi 《Journal of Polymer Science.Polymer Physics》1989,27(11):2283-2293
A new apparatus was designed to investigate the dynamic viscoelastic properties of solid polymer materials in the nonlinear viscoelastic region. The apparatus was combined with a birefringence apparatus in such a way that birefringence could be measured simultaneously with stress under oscillatory deformation. The nonlinear viscoelastic behavior of bulk-crystallized high-density polyethylene films was examined. Nonlinearity of mechanical properties became evident around 30°C, while optical properties became markedly nonlinear around 50°C. The nonlinearity of viscoelastic properties changes very little when the films are swollen with tetrachloroethane. It is proposed that disruption of lamellae to crystallites in the drawing process is one of the most important causes of the nonlinear behavior of high-density polyethylene films. 相似文献
110.
Inagi S Koseki K Hayashi S Fuchigami T 《Langmuir : the ACS journal of surfaces and colloids》2010,26(24):18631-18633
The electrochemical reduction of a fluorene-based conjugated polymer, poly(9-fluorenone-alt-9,9-dioctylfluorene), was investigated for the first time. The carbonyl group in the fluorenone unit was selectively and quantitatively converted to the methylene group, as determined by (1)H NMR, IR, and energy-dispersive X-ray (EDX) analysis. The optical and electrochemical properties of the polymers were studied by UV-vis, photoluminescence (PL), and cyclic voltammetry (CV) measurements and were found to be tunable by varying the reduction level. 相似文献