全文获取类型
收费全文 | 578篇 |
免费 | 20篇 |
专业分类
化学 | 434篇 |
晶体学 | 4篇 |
力学 | 10篇 |
数学 | 17篇 |
物理学 | 133篇 |
出版年
2021年 | 3篇 |
2020年 | 5篇 |
2019年 | 5篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 17篇 |
2015年 | 8篇 |
2014年 | 16篇 |
2013年 | 13篇 |
2012年 | 19篇 |
2011年 | 24篇 |
2010年 | 14篇 |
2009年 | 9篇 |
2008年 | 28篇 |
2007年 | 23篇 |
2006年 | 31篇 |
2005年 | 25篇 |
2004年 | 42篇 |
2003年 | 30篇 |
2002年 | 30篇 |
2001年 | 11篇 |
2000年 | 8篇 |
1999年 | 10篇 |
1998年 | 4篇 |
1997年 | 14篇 |
1996年 | 8篇 |
1995年 | 4篇 |
1994年 | 13篇 |
1993年 | 12篇 |
1992年 | 4篇 |
1991年 | 12篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1986年 | 8篇 |
1985年 | 15篇 |
1984年 | 12篇 |
1983年 | 2篇 |
1982年 | 8篇 |
1981年 | 16篇 |
1980年 | 9篇 |
1979年 | 10篇 |
1978年 | 13篇 |
1977年 | 4篇 |
1976年 | 5篇 |
1975年 | 4篇 |
1974年 | 5篇 |
1973年 | 2篇 |
1972年 | 4篇 |
1971年 | 5篇 |
1970年 | 3篇 |
排序方式: 共有598条查询结果,搜索用时 46 毫秒
71.
I. Mirebeau M. Hennion M.J.P. Gingras A. Keren K. Kojima M. Larkin G.M. Luke B. Nachumi W.D. Wu Y.J. Uemura I.A. Campbell G.D. Morris 《Hyperfine Interactions》1997,104(1-4):343-348
In the amorphous ( Fe1-x Mn_x)75 P16 B_6 Al_3 alloys, muon and neutron depolarization data, combined with the results of small angle neutron scattering, magnetization and Mössbauer spectroscopy, probe the existence of three distinct magnetic transitions at TC, TK and TF (TF < K < C). 相似文献
72.
R. F. Kiefl J. H. Brewer I. Affleck J. F. Carolan P. Dosanjh W. N. Hardy T. Hsu R. Kadono J. R. Kempton S. R. Kreitzman Q. Li A. H. O'Reilly T. M. Riseman P. Schleger P. C. E. Stamp H. Zhou L. P. Le G. M. Luke B. Sternlieb Y. J. Uemura H. R. Hart K. W. Lay 《Hyperfine Interactions》1991,63(1-4):139-144
We have searched for anomalous internal magnetic fields in highT
c materials which are predicted to occur in anyon and flux phase models of superconductivity. The magnitude, anisotropy and
temperature dependence of the observed fields inc-axis oriented samples of sintered YBa2CuO3O7 and of thick-film Bi2Sr2CaCu2O8 are consistent with a conventional nuclear dipolar origin. An upper limit of ≲0.08 mT is set for any anomalous magnetic fields
along thec-axis atμ
+ sites in bulk CuO2 superconductors. 相似文献
73.
H. Uemura 《Journal of Theoretical Probability》2004,17(2):347-366
We study the Tanaka formula for multidimensional Brownian motions in the framework of generalized Wiener functionals. More precisely, we show that the submartingale U(B
t
–x) is decomposed in the sence of generalized Wiener functionals into the sum of a martingale and the Brownian local time, U being twice of the kernel of Newtonian potential and B
t
the multidimensional Brownian motion. We also discuss on an aspect of the Tanaka formula for multidimensional Brownian motions as the Doob–Meyer decomposition. 相似文献
74.
We give a unified method to obtain the conservativeness of a class of Markov processes associated with lower bounded semi-Dirichlet forms on L 2(X;m), including symmetric diffusion processes, some non-symmetric diffusion processes and jump type Markov processes on X, where X is a locally compact separable metric space and m is a positive Radon measure on X with full topological support. Using the method, we give an example in each section, providing the conservativeness of the processes, that are given by the “increasingness of the volume of some sets(balls)” and “that of the coefficients on the sets” of the Markov processes. 相似文献
75.
Axisymmetrical snap buckling of a clamped shallow spherical shell with initial deformation and subject to uniform pressure is analysed based on the finite-deformation theory. As a refinement to analyses given in the author's previous papers, a variable term in the deformation pattern is introduced and Galerkin's method is applied to the non-linear simultaneous differential equations, so that upper buckling pressures are obtained as a function of the geometrical parameter α. Non-uniqueness of solution is shown in the region of larger values of α, where the higher order of deformation mode takes place. Stability of a number of possible equilibrium states is checked by use of the second variation of total potential energy to clarify the actual buckling process. The remark- able decrease of buckling pressure is reasonably explained by introducing a small initial deflection, which explains the discrepancy between the classical buckling pressure and experimental results. 相似文献
76.
Uemura S Aono M Komatsu T Kunitake M 《Langmuir : the ACS journal of surfaces and colloids》2011,27(4):1336-1340
Self-assembled structures of melamine and the condensed melamine derivative melem were investigated at aqueous solution-Au(111) interfaces by cyclic voltammetry and in situ scanning tunneling microscopy (STM) observation. The adsorption/desorption behaviors of both molecules on Au(111) surfaces could be controlled by varying the electrochemical potential and solution concentration. In the negative potential region, self-assembled structures of melem and melamine were constructed by double hydrogen bonding systems between nitrogen atoms of triazine rings and amine groups. In addition, melem formed a closely packed structure at potentials of between -0.3 and -0.15 V or in solutions at higher concentrations. 相似文献
77.
Kourist R Miyauchi Y Uemura D Miyamoto K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(2):557-563
Variant G74C of arylmalonate decarboxylase (AMDase) from Bordatella bronchoseptica has a unique racemising activity towards profens. By protein engineering, variant G74C/V43A with a 20-fold shift towards promiscuous racemisation was obtained, based on a reduced activity in the decarboxylation reaction and a two-fold increase in the racemisation activity. The mutant showed an extended substrate range, with a 30-fold increase in the reaction rate towards ketoprofen. Molecular dynamics simulations and the substrate profile of the racemase indicate that the steric and polar effects of the substrate structure play a more dominant role on catalysis than mere kinetic α-proton acidity. The observation that the conversion of β,γ-unsaturated carboxylic acids does not lead to a rearrangement to form their α,β isomers indicates a concerted rather than a stepwise mechanism. Interestingly, a substrate bearing a nitro group instead of the carboxylic acid group on the α-carbon atom was also converted by the racemase. 相似文献
78.
Kawai Y Tsukamoto S Ito J Akimoto K Takahashi M 《Chemical & pharmaceutical bulletin》2011,59(9):1110-1116
The blockade of human ether-a-go-go-related gene (hERG) potassium channels is widely regarded as the predominant cause of drug-induced QT prolongation. The correlation analysis between the inhibition of the hERG channel (hERG inhibition) and physicochemical properties was investigated by use of in-house quinolone antibiotics as model compounds. In order to establish a simple prediction model of hERG inhibition, we focused on the comprehensible physicochemical parameters such as lipophilicity (log P) and basicity (pK(a)). At first, the risk associated with increasing log P and pK(a) was examined by statistical analysis. It was demonstrated that the risk associated with increasing log P and pK(a) by one unit, respectively, almost identically increased. Consequently, equal attention should be paid to both parameters on hERG inhibition. Next, a prediction model of hERG inhibition which was represented by log P and pK(a) was investigated. As a result, we built the stepwise discriminant prediction model which took advantage of the risk judgment by zone classification. In conclusion, the impact of log P and pK(a) on hERG inhibition was clarified relatively and quantitatively. The quantitative risk assessment established based on both parameters, was considered to be a practical and useful tool in avoiding hERG inhibition and in the rational drug design for drug discovery, especially in lead optimization. Moreover, we also carried out a trend analysis using a different derivative and demonstrated that both parameters were equally significant for hERG inhibition. 相似文献
79.
Ohno O Chiba T Todoroki S Yoshimura H Maru N Maekawa K Imagawa H Yamada K Wakamiya A Suenaga K Uemura D 《Chemical communications (Cambridge, England)》2011,47(46):12453-12455
Novel sesquiterpene alkaloids, halichonines A (1), B (2), and C (3), were identified from the marine sponge Halichondria okadai Kadota. By spectroscopic analyses and synthesis, their structures were revealed to include a 6,6-bicyclic ring system and two prenylated amine moieties. In addition, 2 induced apoptosis in HL60 human leukemia cells. 相似文献
80.
Journal of Theoretical Probability - We consider symmetric stable-type processes with degenerate/singular Lévy densities via Dirichlet form theory. We give conditions of some global path... 相似文献