"Proteo-dendrimers" in which polyanionic hepta(glutamic acids), fluorescent zinc porphyrinate cores, hydrophilic polyether surfaces, and nonpeptide hydrophobic dendrons are combined, were developed as a new series of synthetic receptors for protein recognition. They have polyanionic "patch" structures on their surfaces and undergo complementary electrostatic interactions with a positively charged cytochrome c patch, as observed in biological protein-protein recognition systems. Stability constants of the resulting supramolecular complexes were determined in phosphate buffer (pH 7) by monitoring the fluorescence quenching of the zinc porphyrinates. These proteo-dendrimer receptors exhibited higher affinities with cytochrome c proteins in aqueous solutions than with biological cytochrome b5. Furthermore, they effectively blocked complexation of biological cytochrome b5 with cytochrome c, indicating that the proteo-dendrimers and cytochrome b5 similarly occupy the polycationic patch of cytochrome c. 相似文献
Mix and match : The pentagonal [Mo6O21]n? polyoxomolybdate building block assembles with other sources of Mo, V, and Sb ions to form an orthorhombic Mo‐V‐Sb oxide. The first single‐crystal X‐ray analysis of an orthorhombic Mo–V‐based oxide, a promising catalyst for light alkane selective oxidation known as the “M1 phase”, revealed the structure of the compound.
Let H be a real Hilbert space and let C be a nonempty closed convex subset of H. Let ?? >?0 and let A be an ??-inverse-strongly monotone mapping of C into H and let B be a maximal monotone operator on H. Let F be a maximal monotone operator on H such that the domain of F is included in C. Let 0?< k?<?1 and let g be a k-contraction of H into itself. Let V be a ${\overline{\gamma}}$-strongly monotone and L-Lipschitzian continuous operator with ${\overline{\gamma} >0 }$ and L >?0. Take ${\mu, \gamma \in \mathbb R}$ as follows:$${0 < \mu < \frac{2\overline{\gamma}}{L^2}, \quad 0 < \gamma < \frac{\overline{\gamma}-\frac{L^2 \mu}{2}}{k}.}$$In this paper, under the assumption ${(A+B)^{-1}0 \cap F^{-1}0 \neq \emptyset}$, we prove a strong convergence theorem for finding a point ${z_0\in (A+B)^{-1}0\cap F^{-1}0}$ which is a unique solution of the hierarchical variational inequality $${\langle (V-\gamma g)z_0, q-z_0 \rangle \geq 0, \quad \forall q\in (A+B)^{-1}0 \cap F^{-1}0.}$$Using this result, we obtain new and well-known strong convergence theorems in a Hilbert space which are useful in nonlinear analysis and optimization. 相似文献
We measured the temperature dependence of 57Fe M?ssbauer spectra obtained after 57Mn implantation into polycrystalline LiH with an extremely low implantation dose. Density functional calculations suggested that the Fe atoms were predominantly implanted into both Li and H substitutional sites of the LiH crystal. 相似文献
Light-induced refractive index change in photopolymer is quantified by a digital holographic microscope. The refractive index change is induced as the dark reaction which proceeds inside the photopolymer after a writing beam is stopped. Time-lapse phase distribution across the photopolymer is measured by the off-axis digital holographic microscope which enables us to retrieve the 2-D phase map from a single hologram. It is found that the initial phase profile does not coincide with the illumination intensity distribution. This observation suggests that the rate of the refractive index change in dark reaction is not proportional to the illumination intensity in case the exposure energy becomes high. 相似文献
Thermal reactions of alkali salts of 4-(1-bromoethyl)benzoic acid in bulk were investigated. These reactions were found to produce unexpectedly the graft copolymer, poly(4-vinylbenzoate)-graft-oligo(oxycarbonyl-1,4-phenylenethylidene) ( 1 ). The relative reactivity of the oligocondensation as well as the vinyl polymerization of the salts decreased in the following order: K > Na > Li. The reaction polymerization rate proceeded rapidly during the initial 15 min, and then slowed down. 相似文献
Partial charge fluctuations in the charge-ordered state of a material, often triggered by structural disorders and/or defects, can significantly alter its physical characteristics, such as magnetic long-range ordering. However, it is difficult to post-chemically fix such accidental partial fluctuations to reconstruct a uniform charge-ordered state. Herein, we report CO2-aided charge ordering demonstrated in a CO2-post-captured layered magnet, [{Ru2(o-ClPhCO2)4}2{TCNQ(OMe)2}] ⋅ CO2 ( 1⊃CO2 ; o-ClPhCO2−=ortho-chlorobenzoate; TNCQ(OMe)2=2,5-dimethoxy-7,7,8,8-tetracyanoquinodimethane). Pristine porous layered magnet 1 had a partially charge-fluctuated ordered state, which provided ferrimagnetic ordering at TC=65 K. Upon loading CO2, 1 adsorbed one mole of CO2, forming 1⊃CO2 , and raising TC to 100 K. This was because of the vanishing charge fluctuations without significantly changing the framework structure. This research illustrates the post-accessible host–guest chemistry delicately combined with charge, spin, and lattice ordering in a spongy magnet. Furthermore, it highlights how this innovative approach opens up new possibilities for technology and nanoscale magnetism manipulation. 相似文献