Azimuthal anisotropy in low-energy ion scattering from SmB6 (001)

A remarkable azimuthal anisotropy has been observed in the scattering of He⁺ ions of an incident energy of 1 KeV from the SmB₆(001) surface. The anisotropy can be interpreted on the basis of “shadowing” effects and clearly reflects the structure of the surface.     

Photoelectron spectroscopic study of simple hydrogen-bonded dimers. I. Supersonic nozzle beam photoelectron spectrometer and the formic-acid dimer

In this paper we describe several characteristics of our supersonic nozzle beam photoelectron spectrometer recently constructed for studying hydrogen-bonded dimers in the gas phase by HeI (58.4 nm) radiation. Using this photoelectron apparatus, we have reinvestigated the HeI photoelectron spectrum of the formic-acid dimer (HCOOH)₂ which is well known as a fairly strong doubly hydrogen-bonded dimer. It was found that the (HCOOH)₂ spectrum deduced here from the spectrum of the monomer—dimer mixture considerably differs from that reported by Carnovale et al. in the region beyond 16.5 eV. New spectral assignments are given for four ionization bands beyond 16.5 eV. It is also indicated that the lower bound of the dissociation energy of (HCOOH)₂⁺ is estimated to be 1.0 ± 0.1 eV from the threshold of the dimer band (11.0 eV) obtained in this experiment. This value is considerably smaller than the value of 1.7 ± 0.2 eV recently reported for the water dimer cation (H₂O)₂⁺.     

Aerosol Generation Method for Measuring Particles Suspended in Water – Detection of Particulate Impurities in Ultrapure Water and Sizing of Fine Powders –

The method described is based on the fact that the measurement of particles in the gaseous phase is generally easier than that in the liquid phase for fine particles smaller than 1 μm in diameter. The system consists of a liquid nebulizing unit, evaporator, condenser, mixing diluter and two different aerosol sizing instruments. It has been found that this method can continuously detect particulate impurities in ultrapure water in situ and can measure the size distribution of fine powders in the submicron particle size range down to about 0.05 μm.     

A trifluoromethanesulfonic acid-catalyzed reaction of arylhydrazines with benzene

Arylhydrazines reacted with benzene in the presence of trifluoromethanesulfonic acid (TFSA) to give aminobiphenyls. This is a general method for the synthesis of aminobiphenyls.     

Structures of novel antibiotics, furaquinocins A and B

Structures of novel citocydal antibiotics furaquinocins A and B, isolated from the fermentation broth of Streptomyces sp. KO-3988, was elucidated on the basis of spectroscopic analyses.     

Synthetic studies on β-lactam antibiotics. VII. Mild removal of the benzyl ester protecting group with aluminum trichloride

The benzyl ester protecting group in β-lactam derivatives can be cleanly removed by treatment with aluminum trichloride under mild conditions, preferably in the presence of anisole, to give the corresponding free acids in high yields.     

Laser diode integrated with a low radiation loss thickness-tapered beam expander for highly efficient fiber coupling

The optimal structure of a laser diode monolithically integrated with a thickness-tapered beam expander waveguide is demonstrated by analyzing the relationship between fiber coupling efficiencies and radiation losses. It is also found that mode conversion loss is lowered in a ridge waveguide structure than in a buried hetero structure under equivalent fiber coupling. A fabricated ridge waveguide device based on this design shows threshold current as low as 16 mA and narrow beam divergences of 13° and 12°.